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http://dx.doi.org/10.5012/bkcs.2004.25.7.1009

Spectrophotometric Determination of Nitrite Based on Its Reaction with p-Nitroaniline in the Presence of Diphenylamine in Micellar Media  

Afkhami, Abbas (Department of Chemistry, Faculty of Sciences, Bu-Ali Sina University)
Masahi, Shokofeh (Department of Chemistry, Faculty of Sciences, Bu-Ali Sina University)
Bahram, Morteza (Department of Chemistry, Faculty of Sciences, Bu-Ali Sina University)
Publication Information
Bulletin of the Korean Chemical Society / v.25, no.7, 2004 , pp. 1009-1011 More about this Journal
Abstract
In the present work a very simple, sensitive and selective spectrophotometric method for the determination of nitrite in micellar media is described. The method is based on the color reaction of nitrite with p-nitroaniline in the presence of diphenylamine in acid media. In order to remove the extraction step, Triton X-100, a non-ionic surfactant was used as micellar media. The optimum reaction conditions such as acid concentration, reagents concentration and effect of time have been studied and the analytical characteristics of the method such as limit of detection, linear range and molar absorptivity have been obtained. The interference of some anions and cations was also tested. The method was applied to the determination of nitrite in real samples.
Keywords
Spectrophotometric determination; Nitrite; p-Nitroaniline; Diphenylamine; Micellar media;
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