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http://dx.doi.org/10.5012/bkcs.2004.25.1.063

Novel Silica Nanotubes Using a Library of Carbohydrate Gel Assemblies as Templates for Sol-Gel Transcription in Binary Systems  

Jung, Jong-Hwa (Nano Material Team, Korea Basic Science Institute (KBSI), CREST, Japan Science and Technology Corporation (JST), Nanoarchitectonics Research Center (NARC), National Institute of Advanced Industrial Science and Technology(AIST))
Lee, Shim-Sung (Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University)
Shinkai, Seiji (Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University)
Iwaura, Rika (Naoarchitectonics Research Center (NARC), National Institute of Advanced Industrial Science and Technology (AIST))
Shimizu, Toshimi (Naoarchitectonics Research Center (NARC), National Institute of Advanced Industrial Science and Technology (AIST), CREST, Japan Science and Technology Corporation (JST))
Publication Information
Bulletin of the Korean Chemical Society / v.25, no.1, 2004 , pp. 63-68 More about this Journal
Abstract
Sugar-based gelator p-dodecanoyl-aminophenyl- ${\beta}$-D-aldopyranosides (1-3) have been shown to self-assemble in the presence of p-aminophenyl aldopyranosides. The hydrogel 1+4 showed the double-helical structure with 3-25 nm outer diameters, which is quite different from that of 1. The gel 2+5 revealed twisted ribbon structure with 30-50 nm in widths and a few micrometers of length whereas the gel 3+4 revealed the single and the bundled fiber structures. The difference in these gel supramolecular structures has successfully been transcribed into silica structures by sol-gel polymerization of tetraethoxysilane (TEOS), resulting in the doublehelical, the twisted-ribbon, the single and the multiple (lotus-shaped) hollow fiber structures. These results indicate that novel silica structures can be created by transcription of various superstructures formed in binary gels through the hydrogen-bonding interaction, and the amino group of the p-aminophenyl aldopyranosides acts as an efficient driving force to create novel silica nanotubes. Furthermore, electron energy-loss spectroscopy (ELLS) provided strong evidence for the inner hollow structure of the double-helical silica nanotube. This is a novel and successful example that a variety of new silica structures can be created using a library of carbohydrate gel fibers as their templates.
Keywords
Double-helical; Gelator; Nanotube; Silica; Sol-gel transcription;
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