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http://dx.doi.org/10.5012/bkcs.2004.25.10.1471

Lipase/Ruthenium-Catalyzed Dynamic Kinetic Resolution of β-Hydroxyalkylferrocene Derivatives  

Lee, Han-Ki (National Research Laboratory of Chirotechnology, Department of Chemistry, Division of Molecular and Life Sciences, Pohang University of Science and Technology)
Ahn, Yang-Soo (National Research Laboratory of Chirotechnology, Department of Chemistry, Division of Molecular and Life Sciences, Pohang University of Science and Technology)
Publication Information
Bulletin of the Korean Chemical Society / v.25, no.10, 2004 , pp. 1471-1473 More about this Journal
Abstract
An efficient dynamic kinetic resolution of racemic ${\beta}$-hydroxyalkylferrocene and 1,1'-bis( ${\beta}$-hydroxyalkyl)-ferrocene derivatives was achieved using lipase/ruthenium-catalyzed transesterification in the presence of an acyl donor. The racemic ${\beta}$-hydroxyalkylferrocene derivatives were successfully transformed to the corresponding chiral acetates of high optical purities in high yields.
Keywords
Dynamic kinetic resolution (DKR); Enzyme/metal bicatalysis; Lipase; ${\beta}$-Hydroxyalkylferrocene;
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