Browse > Article
http://dx.doi.org/10.5012/bkcs.2003.24.8.1119

Experimental Determinations of Coherent Multidimensional Vibrational Spectroscopy  

Besemann, Daniel (Department of Chemistry, University of Wisconsin-Madison)
Condon, Nicholas (Department of Chemistry, University of Wisconsin-Madison)
Meyer, Kent (Department of Chemistry, University of Wisconsin-Madison)
Zhao, Wei (Department of Chemistry, University of Wisconsin-Madison)
Wright, John C. (Department of Chemistry, University of Wisconsin-Madison)
Publication Information
Bulletin of the Korean Chemical Society / v.24, no.8, 2003 , pp. 1119-1125 More about this Journal
Abstract
Coherent multidimensional vibrational spectroscopy is a new technique for establishing correlations between features in vibrational spectra that are caused by intra- and intermolecular interactions. These interactions cause cross-peaks between vibrational transitions that reflect the coupling. In this paper, we use Doubly Vibrationally Enhanced Infrared Spectroscopy (DOVE-IR) and DOVE-Raman processes to obtain coherent two dimensional vibrational spectra. The spectra are fitted to obtain the dephasing rates and third order susceptibilities $(χ^{(3)})$ for the nonlinear processes. We show that the DOVE $χ^{(3)}$ values are directly related to the molar absorptivities and Raman $χ^{(3)}$. We then use these relationships to obtain estimates for the $χ^{(3)}$ of the stimulated photon echo and $χ^{(5)}$ of the six wave mixing spectroscopies, respectively. We also predict the ratio of the cascaded four wave mixing signal to the six wave mixing signal.
Keywords
Nonlinear; Vibrational; Two dimensional; Coherent; Infrared;
Citations & Related Records

Times Cited By Web Of Science : 4  (Related Records In Web of Science)
Times Cited By SCOPUS : 4
연도 인용수 순위
1 Zhao, W.; Wright, J. C. J. Am. Chem. Soc 1999, 121, 10994-10998.   DOI   ScienceOn
2 LaBuda, M. J.; Wright, J. C. J. Chem. Phys. 1998, 108, 4112-4122.   DOI   ScienceOn
3 Besemann, D. M.; Condon, N. J.; Murdoch, K. M.; Meyer, K. A.;Zhao, W.; Wright, J. C. Chem. Phys. 2001, 266, 177.   DOI   ScienceOn
4 Levenson, M. D.; Bloembergen, N. J. Chem. Phys. 1974, 60,1323-1327.   DOI
5 Levenson, M. D.; Bloembergen, N. Phys. Rev. B 1974, 10, 4447-4463.   DOI
6 Hamm, P.; Lim, M.; DeGrado, W. F.; Hochstrasser, R. M. J. Chem.Phys. 2000, 112, 1907-1916.   DOI   ScienceOn
7 Asplund, M. C.; Zanni, M. T.; Hochstrasser, R. M. Proc. Natl.Acad. Sci. 2000, 97, 8219-8224.   DOI   ScienceOn
8 Zanni, M. T.; Asplund, M. C.; Hochstrasser, R. M. J. Chem. Phys.2001, 114, 4579-4590.   DOI   ScienceOn
9 Lim, M.; Hamm, P.; Hochstrasser, R. M. Proc. Natl. Acad. Sci.1998, 95, 15215-15320.
10 Golonzka, O.; Khalil, M.; Demirdoven, N.; Tokmakoff, A. Phys.Rev. Letters 2001, 86, 2154-2157.   DOI   ScienceOn
11 Khalil, M.; Tokmakoff, A. Chem. Phys. 2001, 266, 213-230.   DOI   ScienceOn
12 Tominaga, K.; Yoshihara, K. Phys. Rev. A 1997, 55, 831.   DOI   ScienceOn
13 Tokmakoff, A.; Fleming, G. R. J. Chem. Phys. 1997, 106, 2569-2582.   DOI   ScienceOn
14 Blank, D. A.; Kaufman, L. J.; Fleming, G. R. J. Chem. Phys.2000, 113, 771-778.   DOI   ScienceOn
15 Murdoch, K. M.; Condon, N. J.; Zhao, W.; Besemann, D. M.;Meyer, K. A.; Wright, J. C. Chem. Phys. Letters 2001, 335, 349.   DOI   ScienceOn
16 Kaufman, L. J.; Heo, J.; Ziegler, L. D.; Fleming, G. R. Phys. Rev.Letters 2002, 88, 207402-207406.   DOI   ScienceOn
17 Kaufman, L. J.; Blank, D. A.; Fleming, G. R. J. Chem. Phys.2001, 114, 2312-2332.   DOI   ScienceOn
18 Wright, J. C. Int. Rev. Phys. Chem. 2002, 21, 185-255.   DOI   ScienceOn
19 Steffen, T.; Fourkas, J. T.; Duppen, K. J. Chem. Phys. 1996, 105,7364-7382.   DOI   ScienceOn
20 Wright, J. C. In Applications of Lasers to Chemical Problems, 1st ed.; Evans, T. R., Ed.; John Wiley&Sons: New York, 1982; p 35.
21 Hamm, P.; Lim, M.; Hochstrasser, R. M. J. Phys. Chem. B 1998,102, 6123-6138.   DOI   ScienceOn
22 Tominaga, K.; Yoshihara, K. J. Chem. Phys. 1996, 104, 4419-4426.   DOI
23 Tokmakoff, A. J. Phys. Chem. A 2000, 104, 4247-4255.   DOI   ScienceOn
24 Khalil, M.; Demirdoven, N.; Golonzka, O.; Fecko, C. J.; Tokmakoff,A. J. Phys. Chem. A 2000, 104, 5711-5715.   DOI   ScienceOn
25 Kwak, K.; Cha, S.; Cho, M.; Wright, J. C. J. Chem. Phys. 2002,117, 5675-5687.   DOI   ScienceOn
26 Tokmakoff, A.; Lang, M. J.; Larsen, D. S.; Fleming, G. R.;Chernyak, V.; Mukamel, S. Phys. Rev. Letters 1997, 79, 2702-2705.   DOI   ScienceOn
27 Richmond, G. L. Annu. Rev. Phys. Chem. 2001, 52, 257-265.
28 Blank, D. A.; Kaufman, L. J.; Fleming, G. R. J. Chem. Phys.1999, 111, 3105-3114.   DOI
29 Zhao, W.; Wright, J. C. Phys. Rev. Letters 1999, 83, 1950-1953.   DOI
30 Kirkwood, J. C.; Ulness, D. J.; Albrecht, A. C.; Stimson, M. J.Chem. Phys. Letters 1998, 293, 417-422.   DOI   ScienceOn
31 Carlson, R. J.; Wright, J. C. Anal. Chem. 1991, 63, 1449-1451.   DOI
32 Wright, J. C.; Condon, N. J.; Murdoch, K. M.; Besemann, D.;Meyer, K. A. J. Phys. Chem. to be published.
33 Shen, Y. R. The Principles of Nonlinear Optics; Wiley Interscience:New York, 1984.
34 Richmond, G. L.; Robinson, J. M.; Shannon, V. L. Prog. Surf. Sci.1988, 28, 1.   DOI   ScienceOn
35 Carlson, R. J.; Wright, J. C. J. Chem. Phys. 1990, 92, 5186-5195.   DOI
36 Ulness, D. J.; Kirkwood, J. C.; Albrecht, A. C. J. Chem. Phys.1998, 108, 3897-3902.   DOI   ScienceOn
37 Ivanecky, J. E.; Wright, J. C. Chem. Phys. Letters 1993, 206, 437-444.   DOI   ScienceOn
38 Kubarych, K. J.; Milne, C. J.; Lin, S.; Astinov, V.; Miller, R. J. D.J. Chem. Phys. 2002, 116, 2016-2042.   DOI   ScienceOn
39 Chen, P. C.; Hamilton, J. P.; Zilian, A.; LaBuda, M. J.; Wright, J.C. Appl. Spectrosc. 1998, 52, 380-392.   DOI   ScienceOn
40 Astinov, V.; Kubarych, K. J.; Milne, C. J.; Miller, R. J. D. Chem.Phys. Letters 2000, 327, 334-342.   DOI   ScienceOn
41 Lee, D.; Albrecht, A. C. Advances in Infrared and Raman Spectroscopy,1st ed.; Wiley-Heyden: Chichester, 1985; Vol. 12.
42 Khalil, M.; Golonzka, O.; Demirdoven, N.; Fecko, C. J.; Tokmakoff,A. Chem. Phys. Letters 2000, 321, 231-237.   DOI   ScienceOn
43 Cho, M. In Advances in Mult-Photon Processes and Spectroscopy;1st ed.; Lin, S. H., Villaeys, A. A., Fujimura, Y., Eds.; WorldScientific: Singapore, 1999; Vol. 12, pp 1-72.
44 Tominaga, K.; Keogh, G. P.; Naitoh, Y.; Yoshihara, K. J. RamanSpectr. 1995, 26, 495-501.   DOI   ScienceOn
45 Tominaga, K.; Yoshihara, K. Phys. Rev. Letters 1995, 74, 3061-3064.   DOI   ScienceOn
46 Corn, R. M.; Higgins, D. A. Chem. Rev. 1994, 94, 107-125.   DOI   ScienceOn
47 Levenson, M. D.; Kano, S. S. Introduction to Nonlinear Spectroscopy;Academic Press: New York, 1988.
48 Steffen, T.; Duppen, K. J. Chem. Phys. 1997, 106, 3854-3864.   DOI   ScienceOn
49 Hamilton, J. P.; LaBuda, M. J.; Wright, J. C. Chem. Phys. Letters1997, 277, 175-182.   DOI   ScienceOn
50 Asplund, M. C.; Lim, M.; Hochstrasser, R. M. Chem. Phys.Letters 2000, 323, 269-277.   DOI   ScienceOn
51 Carlson, R. J.; Nguyen, D. C.; Wright, J. C. J. Chem. Phys. 1990,92, 1538-1546.   DOI
52 Hamm, P.; Lim, M.; Hochstrasser, R. M. Phys. Rev. Letters 1998,81, 5326-5329.   DOI   ScienceOn
53 Mukamel, S. Principles of Nonlinear Optical Spectroscopy, 1sted.; Oxford University Press: New York, 1995.
54 Zhao, W.; Wright, J. C. Phys. Rev. Letters 2000, 84, 1411-1414.   DOI   ScienceOn
55 Wright, J. C.; Carlson, R. J.; Hurst, G. B.; Steehler, J. K.; Riebe,M. T.; Price, B. B.; Nguyen, D. C.; Lee, S. H. Int. Rev. Phys.Chem. 1991, 10, 349-390.   DOI   ScienceOn
56 Zanni, M. T.; Cnanakaran, S.; Stenger, J.; Hochstrasser, R. M. J.Phys. Chem. B 2001, ASAP, May 8, 2001.
57 Steffen, T.; Duppen, K. Phys. Rev. Letters 1996, 76, 1224-1227.   DOI   ScienceOn
58 Richmond, G. L. Anal. Chem. 1997, 69, 537A.
59 Hamm, P.; Lim, M.; DeGrado, W. F.; Hochstrasser, R. M. J. Phys.Chem. A 1999, 103, 10049-10053.   DOI   ScienceOn
60 Hamm, P.; Lim, M.; DeGrado, W. F.; Hochstrasser, R. M. Proc.Natl. Acad. Sci. 1999, 96, 2036-2041.   DOI   ScienceOn
61 Duppen, K.; Molenkamp, L. W.; Morsink, J. B. W.; Wiersma, D.A.; Trommsdorff, H. P. Chem. Phys. Letters 1981, 84, 421-424.   DOI   ScienceOn
62 Wright, J. C.; Carlson, R. J.; Riebe, M. T.; Steehler, J. K.; Nguyen,D. C.; Lee, S. H.; Price, B. B.; Hurst, G. B. In VibrationalSpectroscopy and Structure, 1st ed.; Bist, H. D., Durig, J. R.,Sullivan, J. F., Eds.; Elsevier Science Publishers: Amsterdam,1989; Vol. 17B, pp 123-158.
63 Carlson, R. J.; Wright, J. C. J. Chem. Phys. 1990, 93, 2205-2216.   DOI
64 LaBuda, M. J.; Wright, J. C. Chem. Phys. Letters 1998, 290, 29-35.   DOI   ScienceOn
65 Tokmakoff, A.; Lang, M. J.; Larsen, D. S.; Fleming, G. R. Chem.Phys. Letters 1997, 272, 48-54.   DOI   ScienceOn
66 Wright, J. C.; Chen, P. C.; Hamilton, J. P.; Zilian, A.; LaBuda, M.J. Appl. Spectrosc. 1997, 51, 949-958.   DOI   ScienceOn
67 Steffen, T.; Duppen, K. Chem. Phys. Letters 1997, 273, 47-54.   DOI   ScienceOn