Browse > Article
http://dx.doi.org/10.5012/bkcs.2003.24.2.173

Sorption Preconcentration and Determination of Nickel in Wastes of Heat Power Industry by Diffuse Reflection Spectroscopy  

Kalyakina, O.P. (Krasnoyarsk State University, Dept. of Chemistry)
Kononova, O.N. (Krasnoyarsk State University, Dept. of Chemistry)
Kachin, S.V. (Krasnoyarsk State University, Dept. of Chemistry)
Kholmogorov, A.G. (Institute of Chemistry and Chemical Technology, Siberian Dept. of the Academy of Science)
Publication Information
Bulletin of the Korean Chemical Society / v.24, no.2, 2003 , pp. 173-177 More about this Journal
Abstract
The present work is focused on the preconcentration of nickel and its determination by means of diffuse reflection spectroscopy. The preconcentration of nickel was carried out by sorption on macroporous aminocarboxylic amphoteric resin ANKB-35. Based on this collector, a method to determine nickel in wastes of heat power industry was worked out using solid-phase spectroscopy. The colored surface compound to be determined was obtained by a preceding nickel sorption on the resin and by subsequent treatment of the concentrate obtained with definite amounts of 1-(2-pyridilazo)-2-naphtol (PAN). The Ni calibration curve is linear in the concentration range of 0.5-20.0 mg/L (sample volume is 200.0 mL) and the detection limit is 0.05 mg/L. The presence of $Cu^{2+},\;Fe^{3+},\;Co^{2+}$ ions as well as macrocomponents of natural water $(Na^+,\;K^+,\;Ca^{2+},\;Mg^{2+})$ do not hinder the solid-phase spectroscopy determination of nickel. The nickel determination by diffuse reflection spectroscopy was carried out in model solutions as well as in solutions obtained after the dissolution of wastes of heat power industry.
Keywords
Nickel; Sorption preconcentration; Wastes of heat power industry; Diffuse reflection spectroscopy;
Citations & Related Records

Times Cited By Web Of Science : 11  (Related Records In Web of Science)
Times Cited By SCOPUS : 11
연도 인용수 순위
1 Kalyakina, O. P.; Kononova, O. N.; Kachin, S. V.; Kholmogorov, A. G. Acta Hydrochim. Hydrobiol. 2000, 28, 272.   DOI   ScienceOn
2 Burger, K. Organic Reagents in Metal Analysis; Mir: Moscow, 1975; p 148.
3 Runov, V. L.; Tropina, V. V. J. Anal. Chem. 1996, 51, 64.
4 Grebenuk, V. D.; Sobolevskaya, T. T.; Makhno, A. G. Chimiya i Technologiya Vody 1989, 11, 407.
5 Me Millen, T. NLGI Spokesman 1991, 54, 24.
6 Yoshimura, K.; Waki, H.; Ohashi, S. Talanta 1976, 23, 449.   DOI   ScienceOn
7 Kononova, O. N.; Kholmogorov, A. G.; Kachin, S. V.; Mytykh, O. V.; Kononov, Y. S.; Kalyakina, O. P.; Pashkov, G. L. Hydrometallurgy 2000, 54, 107.   DOI   ScienceOn
8 Kubelka, P.; Munk, F. Z. Techn. Phys. 1931, 12, 593 (cited from [21]).
9 Terlezkaya, A. V.; Bogoslovskaya, T. A. Chimiya i Technologiya Vody 1994, 16, 338.
10 Zhabo, V. V. Ohrana Okrushaushchey Sredy na TES i AES; Energoatomisdat: Moscow, Russia, 1992; p 240. (Environmental Control in Heat Power Stations and Nuclear Power Stations, in Russian)
11 Peshkova, V. M.; Savostina, V. M. Analyticheskaya Chimiya Nickelya.; Nauka: Moscow, Russia, 1966; p 5. (Analytical Chemistry of Nickel, in Russian)
12 Kokotov, Y. A.; Pasechnik, V. A. Ravnovesie i Kinetika Ionnogo Obmena; Chimiya: Leningrad, Russia, 1970; p 312. (Equilibria and Kinetics of Ion Exchange, in Russian).
13 Kubelka, P. J. Opt. Soc. Amer. 1948, 38, 448 (cited from [21]).   DOI
14 Saldadze, K. M.; Kopylova-Valova, V. D. Kompleksoobrasuyushchie Ionity; Chimiya: Moscow, 1980; p 516. (Complex-forming Ion Exchangers, in Russian).
15 Gornaya Encyclopediya; Kozlovskiy, E. A., Ed; Sovetskaya Enzyklopediya: Moscow, Russia, 1985; Vol. 2, p 575. (Mining Enzyklopaedia, in Russian)
16 Fomin, R. S. Voda. Kontrol Chimicheskoy, Bakterialnoy i Radiacionnoy Besopasnosty po Meshdunarodnym Standartam; Nauka: Moscow, Russia, 1995; p 135. (Water. Control of Chemical, Bacterial and Radiational Safety by International Standard, in Russian)
17 Nakamoto, K. Infrakrasnye Spectry Neorganicheskikh i Koordinazionnykh Soedineniy; Mir: Moscow, Russia, 1966; p 373. (IR-spectra of Inorganic and Coordinating Compounds, in Russian).
18 Brykina, G. D.; Krysina, L. S.; Ivanov, V. M. J. Anal. Chem. 1988, 43, 1547.
19 Reymers, N. F. Ohrana Prirody i Okrushaushchey Sredy; Prosweshchenie: Moscow, Russia, 1990; p 230. (Nature Concervation and Environmental Control, in Russian)
20 Umland, F.; Janssen, A.; Thierig, D.; Wünsch, G. Theorie und praktische Anwendung von Komplexbildnern; Mir: Moscow, Russia, 1975; p 347.
21 Brykina, G. D.; Marchenko, D. Y., Shpigun, O. A. J. Anal. Chem. 1995, 50, 440.
22 Pollard, J. H. A Handbook of Numerical and Statistical Techniques; Cambridge University Press: Cambridge, U.K., 1977; p 342.
23 Chimicheskaya Enzyklopediya; Knunyanz, I. L., Ed; Bolshaya Rossiyskaya Enzyklopediya: Moscow, Russia, 1998; p 471. (Chemical Encyclopaedia, in Russian)
24 Wilms, H. Sudwest. Wirt. 1990, 46, 9.
25 Yoshimura, K.; Toshimitsu, Y.; Ohashi, S. Talanta 1980, 29, 693.
26 Runov, V. K.; Kachin, S. V. Zavodskaya Laboratoriya 1993, 59, 1.