Browse > Article
http://dx.doi.org/10.5012/bkcs.2003.24.10.1449

Description of Temperature Dependence of Critical Micelle Concentration  

Kim, Hong-Un (Department of Chemical Engineering, Chung-Ang University)
Lim, Kyung-Hee (Department of Chemical Engineering, Chung-Ang University)
Publication Information
Bulletin of the Korean Chemical Society / v.24, no.10, 2003 , pp. 1449-1454 More about this Journal
Abstract
A new equation has been derived on the basis of ${\delta}G^o$ = -RT lnK, linear behavior of the enthalpy of micellization with temperature, and the Gibbs-Helmholtz relation. It describes correctly the dependence of critical micelle concentration $(X_{CMC})$ on temperature and has yielded excellent fitting results for various surfactant systems. The new equation results in the linear behavior of the entropy of micellization with temperature and accounts for the compensation phenomena observed for the micellization in aqueous solutions, along with the linear dependence of the enthalpy of micellization on temperature. These results imply that the new equation of $X_{CMC}(T)$ accounts for the temperature dependence of CMC correctly.
Keywords
Critical micelle concentration; Temperature dependence; Thermodynamic potentials of micellization;
Citations & Related Records

Times Cited By Web Of Science : 9  (Related Records In Web of Science)
Times Cited By SCOPUS : 9
연도 인용수 순위
1 Moroi, Y. Micelles: Theoretical and Applied Aspects; Plenum:New York, 1992.
2 Castedo, A.; Del Castillo, J. L.; Suarez-Filloy, M. J.; Rodriguez, J.R. J. Colloid Interface Sci. 1997, 196, 148.   DOI   ScienceOn
3 Lee, D. J. Colloid Polym. Sci. 1995, 273, 539.   DOI
4 Miller, D. D.; Magid, L. J.; Evans, D. F. J. Phys. Chem. 1990, 94,5921.   DOI
5 Becher, P. In Nonionic Surfactants; Schick, M. J., Ed.; MarcelDekker: New York, 1967; Chapter 5.
6 Blandamer, M. J.; Cullis, P. M.; Soldi, L. G.; Engberts, J. B. F. N.;Kacperrska, A.; Van Os, N. M.; Subha, M. C. S. Adv. ColloidInterface Sci. 1995, 58, 171.   DOI   ScienceOn
7 Madan, B.; Lee, B. Biophys. Chem. 1994, 51, 279.   DOI   ScienceOn
8 Chen, L.-J.; Lin, S.-Y.; Huang, C.-C.; Chen, E.-M. Colloid Surf. A1998, 135, 175.   DOI   ScienceOn
9 Kiraly, A.; Dekany, I. J. Colloid Interface Sci. 2002, 242, 214.   DOI   ScienceOn
10 Gilli, P.; Ferretti, V.; Gilli, G.; Borea, P. A. J. Phys. Chem. 1993,98, 1515.
11 Muller, N. Langmuir 1993, 9, 96.   DOI
12 Singh, H. N.; Saleem, S. M.; Singh, R. P. J. Phys. Chem. 1980, 84,2191.   DOI
13 Sugihara, G.; Arakawa, Y.; Tanaka, K.; Lee, S.; Moroi, Y. J.Colloid Interface Sci. 1995, 170, 399.   DOI   ScienceOn
14 Sugihara, G.; Hisatomi, M. J. Colloid Interface Sci. 1999, 219,31.   DOI   ScienceOn
15 Attwood, D.; Boitard, E.; Dubes, J.-P.; Tachoire, H. J. ColloidInterface Sci. 2000, 227, 356.   DOI   ScienceOn
16 Moroi, Y.; Nishikino, N.; Uehara, H.; Matuura, R. J. ColloidInterface Sci. 1975, 50, 254.   DOI   ScienceOn
17 Kim, H.-U.; Lim, K.-H., manuscript in preparation, 2003.
18 Kim, H. U. Ph. D. Dissertation; Chung-Ang University: Seoul,Korea, 2003.
19 La Mesa, C. J. Phys. Chem. 1990, 94, 323.   DOI
20 Stead, J. A.; Taylor, H. J. J. Colloid Interface Sci. 1969, 30, 482.   DOI   ScienceOn
21 Krishnan, V. C.; Friedman, L. H. J. Solution Chem. 1974, 2, 37.   DOI
22 Kim, H.-U.; Lim, K.-H. manuscript in preparation, 2003.
23 Zielinski, R. J. Colloid Interface Sci. 2001, 235, 201.   DOI   ScienceOn
24 Flockhart, B. D. J. Colloid Interface Sci. 1961, 16, 484.   DOI   ScienceOn
25 Ruso, J. M.; Taboada, P.; Mosquera, V.; Sarmiento, F. J. ColloidInterface Sci. 1999, 214, 292.   DOI   ScienceOn
26 Taboada, P.; Attwood, D.; Garcia, M.; Jones, M. N.; Ruso, J. M.;Mosquera, V.; Sarmiento, F. J. Colloid Interface Sci. 2000, 221,242.   DOI   ScienceOn
27 Muller, N. In Micellization, Solubilization, and Microemulsions;Mittal, K. L., Ed.; Plenum: New York, 1977; Vol. 1, pp 229-239.
28 Yoshida, N.; Matsuoka, K.; Moroi, Y. J. Colloid Interface Sci.1997, 187, 388.   DOI   ScienceOn
29 Lumry, R.; Rajender, S. Biopolymers 1970, 9, 1125.   DOI   ScienceOn
30 Jolicoeur, C.; Philip, R. P. Can. J. Chem. 1974, 52, 1834.   DOI
31 Tanford, C. Hydrophobic Effects: Formation of Micelles andBiological Membranes; John Wiley and Sons. Inc: New York,1980.
32 Phillips, J. N. Trans. Faraday Soc. 1955, 151, 561.
33 Holtzer, A.; Holtzer, M. F. J. Phys. Chem. 1974, 78, 1442.
34 Mosquera, V.; del Rip, J. M.; Attwood, D.; Garcia, M.; Jones, M.N.; Prieto, G.; Suarez, M. J.; Sarmiento, F. J. Colloid Interface Sci.1998, 206, 66.   DOI   ScienceOn
35 Kang, K.-H.; Kim, H.-U.; Lim, K.-H. Colloid Surf. A 2001, 189,113.   DOI   ScienceOn
36 Okawauchi, M.; Gagio, M.; Ikawa, Y.; Sugihara, G.; Murata, Y.;Tanaka, M. Bull. Chem. Soc. Jpn. 1987, 60, 2718.
37 Kresheck, G. C.; Hargraves, W. A. J. Colloid Interface Sci. 1974,48, 481.   DOI   ScienceOn
38 Paula, S.; Sus, W.; Tuchtenhagen, J.; Blume, A. J. Phys. Chem.1995, 99, 11742.   DOI   ScienceOn
39 Kim, H.-U.; Lim, K.-H. submitted to Colloid Surf. A, 2003.
40 Shinoda, K.; Kobayashi, M.; Yamaguchi, N. J. Phys. Chem. 1987, 91, 5292.   DOI
41 Tomasic, V.; Chittofrati, A.; Kallay, N. Colloid Surf. A 1995, 104,95.   DOI   ScienceOn