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http://dx.doi.org/10.5012/bkcs.2002.23.7.953

Volumetric Behaviour of Binary Liquid Mixtures at a Temperature of 303.15 K  

Wahab, Mohammad A.
Ali, M. Azhar
Mottaleb, Mohammad A.
Publication Information
Bulletin of the Korean Chemical Society / v.23, no.7, 2002 , pp. 953-956 More about this Journal
Abstract
Excess molar volumes (Vm E ) of binary liquid mixtures: xC6H5CH3 + (1-x1)CH3CN or + (1-x1)C6H5NO2, or + (1-x1)C2H5NO2 have been determined as a function of mole fraction of C6H5CH3 (x) at a temperature of 303.15 K over a entire range of composition. The densities of the binary liquid mixtures were determined by pycnometrically. The VmE values of the mixtures have been found to be negative over the whole composition in order of C6H5CH3 + C6H5NO2, < C6H5CH3 + CH3CN, and < C6H5CH3 + C2H5NO2. The negative magnitude of VmE suggests the presence of intermolecular interaction in the three binary liquid mixtures.
Keywords
Excess molar volumes; Toluene; Nitrobenzene; Nitroethane; Acetonitrile.;
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1 Tresczanomic, A. J.; Kiyohara, T.; Benson, G. C. Bull. Acad. Poly.Sci. Srr. Sci. Chim. 1981, 29(1-2), 103.
2 Scotchard, G. Chem. Rev. 1949, 44, 7.   DOI
3 Stokes, R. H.; Marsh, K. H. Ann. Rev. Phys. Chem. 1972, 23, 65.   DOI   ScienceOn
4 Rajkumar, X. R.; Raman, K. V.; Arulraj, S. T. Ind. J. Pure Appl. Phys. 1984, 22, 241.
5 Rice, O. K. Chem. Rev. 1949, 44, 69.   DOI
6 Kian, Y. S.; Gerritaan, J. K.; Noore, N. Y. ThermophyisicalProperties Research Literature Retrieval, Guide; Plennum Press:New york, 1967.
7 Ali, M. A.; Mahmud, M. J.; Rahman, M. H.; Rouf, M. A.; Islam,M. S. J. Bangla. Chem. Soc. 1990, 3, 17.
8 Ali, M. A.; Lakhanpal, M. L.; Prashar, R. J. Bangla. Chem. Soc. 1991, 4, 175.
9 Riddick, J. A.; Bunger, W. B.; Sanako, T. R. Organic Solvent,Physical Properties and Methods of Purification, 4th ed; Wiley-Intersci.: N. Y., 1986.
10 Ali, M. A. Ph.D. Thesis; Panjab University: Chandigar, India,1985.
11 Fort, R. T.; Moore, W. R. Trans. Farad. Soc. 1966, 62, 1112.   DOI
12 Dewan, R. K.; Metha, S. K. J. Chem. Thermody. 1985, 18, 176.
13 Emmerich, W.; Egger, W.; Vencour, M.; Roux, A. H.; Polednick,M.; Grolier, J. P. E. J. Chem. Thermody. 1998, 30, 1509.   DOI   ScienceOn
14 Marsh, K. N. J. Chem. Thermody. 1995, 17, 29.
15 Ali, M. A.; Rahman, M. H. J. Bangla. Chem. Soc. 1992, 5, 109.
16 Lakhanpal, M. L.; Ali, M. A. Ind. J. Chem 1987, 26, 648.
17 Rajkumar, X. R.; Raman, K. V.; Arulraj, S. T. Acta Cienc. Indica(Ser) Chem. 1981, 7(1-4), 967.
18 Kumaran, M. K.; Benson, G. C. J. Chem. Thermody. 1983, 15,245.   DOI
19 Weast, R. C. Handbook of Chemistry and Physics, 5th ed; CRCPress Inc.: Boca Raton, Florida, 1975-76.
20 Orgela, J.; Angula, M. C. Chem. Eng. Data 1984, 29, 340.   DOI   ScienceOn
21 Ali, M. A.; Praser, R.; Marhawa, R. K.; Lakhanpal, M. L. Ind. J.Chem. 1990, 29, 177.
22 Ali, M. A.; Praser, R.; Sharma, A.; Lakhanpal, M. L. Ind. J. Chem.1989, 28, 512.
23 Irving, J. B. NEL Report. No. 630 and 631; East Kilbridge:Glasgow, 1967.
24 Cary, F. A.; Sundberg, R. J. Advanced Organic Chemistry Part A:Structure and Mechanism, 3rd ed; Plenum Press: 1990.
25 Hildebrand, J. H. Chem. Rev. 1949, 44, 37.   DOI
26 Nigam, R. K.; Singh, K. C. J. Chem. Soc. Farad. Trans. I 1979,75, 1120.   DOI
27 Tresczanomic, A. J.; Benson, G. C. J. Chem. Thermody. 1978, 10,967.   DOI
28 Redlich, O.; Kister, A. T. Indus. Eng. Chem. 1948, 40, 345.   DOI
29 Prashar, R.; Ali, M. A.; Metha, S. K. J. Chem. Thermody. 2000,32, 711.   DOI   ScienceOn