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http://dx.doi.org/10.5012/bkcs.2002.23.3.404

Copper(II) Oxyanion Complexes Derived from Sparteine Copper(II) Dinitrate: Synthesis and Characterization of 4- and 5-Coordinate Copper(II) Complexes  

Lee, Yong-Min
Kim, Yong-Kyu
Jung, Hee-Cheul
Kim, Young-Inn
Choi, Sung-Nak
Publication Information
Bulletin of the Korean Chemical Society / v.23, no.3, 2002 , pp. 404-412 More about this Journal
Abstract
Nine copper(Ⅱ) oxyanion, and mixed oxyanion complexes that have four- or five-coordinate geometries around copper(Ⅱ) centers were derived from sparteine copper(Ⅱ) dinitrate precursor [Cu($C_{15}$$H_{26}$N2)(NO3)2]. The precursor complex undergoes an anion exchange with various oxyanions, and an interchange reaction with other sparteine copper(Ⅱ) complexes. The [Cu($C_{15}$$H_{26}$N2)(CH3CO2)2] also undergoes "halogen atom abstraction" reaction with CCl4 to produce the mixed anion complex [Cu($C_{15}$$H_{26}$N2)(CH3CO2)Cl]. The whole set of prepared complexes has been used for the comparative electrochemical and spectroscopic studies.
Keywords
(-)-Sparteine; Oxyanion; Copper(II); Interchange reaction;
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