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http://dx.doi.org/10.5012/bkcs.2002.23.2.325

Reaction Condition Dependency of Propagating Behavior in the Polymerization Reaction by Thermal Front  

Huh, Do-Sung (Department of Chemistry, Inje University)
Choe, Sang-Joon (Department of Chemistry, Inje University)
Lee, Burm-Jong (Department of Chemistry, Inje University)
Publication Information
Bulletin of the Korean Chemical Society / v.23, no.2, 2002 , pp. 325-329 More about this Journal
Abstract
In this study, the dependency of the behavior of propagating front on the reaction condition in frontal polymerization reaction has been studied. We have used some multifunctional acrylates as a monomer and ammonium persulfate as an initiator for the polymerization reactions. In frontal polymerization, a method of producing polymeric materials via a thermal front that propagates through the unreacted monomer/initiator solution, the behavior of self propagating front shows various dynamic patterns depending on the reaction condition. We have obtained some spin modes of propagating front in the number of 'hot spots' or 'spin heads' by changing the reaction condition. The effect of the reactor tube diameter on the mode of propagating front has also been studied by using some reactor tubes with different size of tube diameter and it has been examined in some detail by adopting an experimental method of two-tubes system.
Keywords
Propagating front; Frontal polymerization; Spin modes;
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