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http://dx.doi.org/10.5012/bkcs.2002.23.1.112

Tin-Free Three-Component Coupling Reaction of Aryl Halides, Norbornadiene (or Norbornene), and Alkynols Using a Palladium Catalyst  

Choi, Cheol-Kyu (Institute of Photonics and Surface Treatment, Q-sys Co.)
Hong, Jin-Who (Department of Polymer Science and Engineering, Chosun University)
Tomita, Ikuyoshi (Department of Electronic Chemistry, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology)
Endo, Takeshi (Department of Polymer Science and Engineering Faculty of Engineering Yamagata University)
Publication Information
Bulletin of the Korean Chemical Society / v.23, no.1, 2002 , pp. 112-118 More about this Journal
Abstract
Good-to-excellent yields of 2,3-Disubstituted norbornenes (or norbornanes) were obtained using a Pd/Cu catalyzed three-component ternary coupling reaction of aryl halides, norbornadiene (or norbornene), and alkynols in toluene at $100{\circ}C$ in the presence of 5.5 M NaOH as a base and benzyltriethylammonium chloride as a phase transfer catalyst. The results of experiments using various aromatic halides suggest that the ternary coupling reaction is promoted by bromide.
Keywords
Aryl halides; Norbornene; Alkynols; Palladium-catalyst; Three-component reaction;
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