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http://dx.doi.org/10.5012/bkcs.2002.23.11.1585

N-Anthracenylmethyl Calix[4]azacrowns as New Fluorescent Ionophores  

Yang, Seung-H.
Shon, Ok-J.
Park, Ki-M.
Lee, Shim-S.
Park, Ho-J.
Kim, Moon-J.
Lee, Joung-H.
Kim, Jong-S.
Publication Information
Bulletin of the Korean Chemical Society / v.23, no.11, 2002 , pp. 1585-1589 More about this Journal
Abstract
Two novel calixarene-based fluoroionophores were synthesized. Their conformations were confirmed to 1,3-alternate by X-ray crystal structures. From CHEF by blocking the PET mechanism in fluorescence spectra, we observed $In^{3+}$ and $Pb^{2+}$ selectivity over other metal ions. For $In^{3+}$ion, calix[4]-bis-azacrown-5 showed about 20 times more sensitive than calix[4]-mono-azacrown-5 because the source of the binding selectivity comes from the calixarene framework and azacrown ligand by controlling the fluorescence and PET mechanisms as-sociated with the amine moiety.
Keywords
Calixarenes; Complexation; fluorescence; Conformation;
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