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http://dx.doi.org/10.5369/JSST.2006.15.5.317

Determination of quinine in aqueous solution by chemiluminescence method  

Lee, Hyun-Sook (Department of Sensor and Display Engineering, Kyungpook National University)
Kim, Tae-Yeon (Department of Chemistry Education, Graduate School of Education, Kyungpook National University)
Choi, Kyoung-Hye (Department of Chemistry, College of Natural Sciences, Kyungpook National University)
Karim, Mohammad Mainul (Department of Chemistry, College of Natural Sciences, Kyungpook National University)
Bae, Hyun-Sook (Department of Sensor and Display Engineering, Kyungpook National University)
Lee, Sang-Hak (Department of Sensor and Display Engineering, Kyungpook National University)
Publication Information
Journal of Sensor Science and Technology / v.15, no.5, 2006 , pp. 317-322 More about this Journal
Abstract
A method to determine quinine in aqueous solution by chemiluminescence method using a stopped flow system has been studied. The method is based on the increased chemiluminescence intensity with the addition of quinine to a solution of lucigenin and hydrogen peroxide. The effects of KOH concentration, flow rate of reagents, $H_{2}O_{2}$ concentration used for the masking of quinine on the chemiluminescence intensity have been investigated. The calibration curve for quinine was linear over the range from $1.0{\times}10^{-7}$ M to $1.0{\times}10^{-3}$ M, coefficient of correlation was 0.993 and the detection limit was $3.0{\times}10^{-8}$ M under the optimal experimental conditions of 1.0 M, 1.5 M, 3.0 mL/min for the concentration of $H_{2}O_{2}$, KOH and flow rate of reagents, respectively.
Keywords
chemiluminescence; quinine; flow-injection analysis;
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