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Development of Depolymerization Method on the Recycling of Waste Flexible Polyurethane Foam  

엄재열 (단국대학교 공과대학 공업화학과)
이병학 (단국대학교 공과대학 공업화학과)
신판우 (동양공업대학 응용화학과)
김용렬 (대진대학교 화학공학과)
Publication Information
Journal of Environmental Health Sciences / v.28, no.2, 2002 , pp. 41-49 More about this Journal
Abstract
Resource recovery and recycling of materials and products including polyurethanes are viewed as a necessity in today's society. The problems of recycling polyurethane wastes has major technological, economic and ecological significance because polyurethane itself is relatively expensive and its disposal by burning is also costly. In general, the recycling methods for polyurethane could be classified as mechanical, chemical and physical. In the chemical recycling method, there ate hydrolysis, glycolysis, pyrolysis and aminolysis. This study was carried out glycolysis using new method such as sonication and catalyzed reaction. There are kinds of recycled polyols were produced by current method(glycolysis) but, this study were with catalyzed reaction and sonication as decomposers and the chemical properties were analyzed. The reaction results in the formation of polyester urethane diols and then the OH value which is determined by the quantity of diol used for the glycolysis conditions. The glycolysis rates by sonication and catalyzed reaction for the various glycols, increased as: PPG
Keywords
Waste polyurethane; Scrap; Depolymerization; Sonication; Recycled polyol;
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  • Reference
1 리사이클링 백서 : (사)한국자원리싸이클링 협회,1999
2 이중기 : 폐플라스틱의 화학적 리사이클링 기술. 공업화학 전망,3(2), 16-21, 2000
3 Mason, T. J. : Chemistry and ultrasound, Elsevier, New York, 54, 1990
4 Burnett, R. H., Baum, G. A. and Ehig, R. J. : Plastic Recycling. Hanser Publishers, New York, 117, 1992
5 Urbanski, J., Czerwinski, W., Janika, J. and Zowall, H. : Handbook of analysis of synthetic polymers and plastics. Ellis Horwood, U. K., 112, 1977
6 김혜태 : 혼합 폐플라스틱의 발생 실태 및 재활용 기술현황에 대한 연구. 한국 자원 재생공사,1996
7 Mason, T. J. and Lorimer J. : Sonochemistry. John Wiley & Sons, New York, 3, 1988
8 최정욱 : 폐플라스틱 열분해 상업화 공정개발,통상 산업부 연구보고서. 1995-N-WA02 -9-01, 1998
9 옥성현 : 폐플라스틱의 재활용 기술 개발. 환경부 보고서,1997
10 Ramirez, M., Rosa, N. D. and Zarzycki, J. : Sonication method. J. NonCryst. Solids, 120, 40(1990)   DOI   ScienceOn
11 Topac, H., Arastoopour, H., Ivanov, G. and Shutov, F. : Polyurethanes. World Congress, 10, 168, 1993
12 김영빈 : 폐플라스틱의 재자원화 대책. 자원리사이클링 학회,2(1), 27-33, 1993
13 선도원,한재익,손근희 : 일본의 폐플라스틱열분해 기술 동향. 화학공업과 기술,14(4), 371-378, 1996