Browse > Article

A Study on Performance of Protective Gloves to Isocyanate Toxicity  

Lee, Su-Gil (Discipline of Public Health, University of Adelaide, South Australia)
Pisaniello, Dino (Discipline of Public Health, University of Adelaide, South Australia)
Lee, Nae-Woo (Faculty of Safety Engineering, Pukyong National University)
Publication Information
Journal of the Korean Society of Safety / v.23, no.6, 2008 , pp. 62-69 More about this Journal
Abstract
As the concerns of dermal exposure of spray painters to isocyanates in the automobile industry, glove performance was examined like permeation rate and breakthrough time including fatigue test. Methylene chloride was used as the solvent for derivatization of the isocyanates with a 97.5% recovery. Ghost wipe pads were used to wipe the surface of the glove material after chemical penetration through the glove material placed under a disposable test cell. Several solvents were tested, such as thinner(xylene, toluene) and cleaning agent(acetone) by using a standard permeation test cell(AS/NZS standard 2161. part 10.3). Solvents accelerate chemical permeation through the gloves more quickly than pure HDI hardener products. The longest breakthrough times were from Nitrosolve gloves, not detected in 8 hours, compared with others like Latex, Neoprene, TNT and Dermo Plus. Therefore Nitrosolve gloves could be recommended as personal protective equipment in crash repair shops. In addition, revised exposure limit of korean regulation should be suggested for employee to minimize the risk of health symptoms.
Keywords
isocyanate; glove performance; permeation rate; breakthrough time; crash repair shop;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 F.V. Bergerova, T. Pierce, P.O. Droz, "Dermal Absorption Potential of Industrial Chemicals, Criteria for Skin Notation", American Journal of Industrial Medicine, Vol. 17, pp. 617-635, 1990   DOI   ScienceOn
2 J. De Cock, D. Heederick, H. Kromhout, J.S.M. Boleij, "Strategy for Assigning a 'skin notation', A Comment", American Occupational Hygiene, Vol. 40, pp. 611-614, 1996   DOI
3 Lee, "Dermal and Ocular Exposure During The Spray Application of Selected Industrial Chemicals", PhD Thesis, Descipline of Public Health, The University of Adelaide, South Australia, 2005
4 M. Cushmac, D. Difiore, C. Hetfield, "New Chemical Environmental Technology Initiative-Automotive Refinishing Industry Isocyanate Profile", U.S. Environmental Protection Agency(EPA), SAIC Project No. 01-1029-07-8088, 1997
5 Y.C. Liu, J. Sparer, S. R. Woskie, M. R. Cullen, J. S. Chung, C. T. Holm, C. A. Redlich, "Qualitative Assessment of Isocyanate Skin Exposure in Auto Body Shops: A Pilot Study", American Journal of Industrial Medicine, Vol. 37, pp. 265-274, 2000   DOI   ScienceOn
6 C. McCammon, "NIOSH Health Hazard Evaluation, Occupational Safety & Health Administration(OSHA)", U.S Department of Labor, Report No. HETA 95-0405-2600, 1996
7 W. A. Heitbrink, T. C. Cooper, M. A. Edmonds, C. J. Bryant, W. E. Ruch, "In-DEPTH Survey Report- Control Technology for Autobody Repair and Painting Shops, Occupational Safety & Health Administration (OSHA)", U.S Department of Labor, Report No. ECTB 179-14a, 1993
8 노동부 고시 제2008-26호, 화학물질 및 물리적인자의 노출기준, 2008
9 OSHA, "Aliphatic Diisocyanate on Surfaces by Colorimetric Swype Indicators", U.S Department of Labour, Occupational Safety & Health Administration, 2002
10 Ansell, "Ansell Protective Products Chemical Registance Guide - Permeation & Degradation Data", U.S, 1998
11 R.T. Gun, A. Langley, S.J. Dundas, K. McCall, "The Human Cost of Work-Occupational Respiratory Disease", 2ndEdition, ISBN 0 7308 4858 2, SA Health Commission, Adelaide, 1996
12 B. McArthur, "Dermal measurement and wipe sampling methods: A review", Appl. Occup. Environ. Hyg., Vol. 7, No. 9, pp. 599-606, 1992   DOI
13 Y.C. Liu, M. Stowe, F. Walsh, J. Sparer, M.R. Cullen, C.T. Holm, C.A. Redich, "Surface contamination and skin exposure to aliphatic isocyanate skin exposure in auto body shops; A quantative assessment", Am. Ind. Hyg Conf. Exp., New Orleans, Louisiana, June 2-7, 2001
14 HSE, "Methods for the Determination of Hazardous Substances (MDHS) 25/3 Organic isocyanates in air", Health & Safety Executive, January, 1999
15 ACGIH, "Documentation of the Threshold Limit Values and Biological Exposure Indices", 7th Edition, American Conference of Governmental Industrial Hygienists, Cincinnati, OH, 2001
16 S.A. Ness, "Surface and Dermal Monitoring for Toxic Exposures", Van Nostrand Reinhold, New YorkISBN 0-442-01465-1, 1994
17 이수길, 이내우, 디노 피사니엘로, "가구산업에 사용되는 이소시안화물의 폭로에 대한 평가", 한국안전학회지, 제21권, 제2호, pp. 138-142, 2006   과학기술학회마을
18 R.A. Fenske, "Dermal exposure assessment techniques", Ann. Occu. Hyg., Vol. 37, No. 6, pp. 687-706, 1993   DOI   ScienceOn
19 Australian/New Zealand Standard TM, "Occupational Protective Gloves Part 10.3: Protective Gloves Against Chemicals and Micro-Organisms-Determination of Resitance to Permeation by Chemicals", 2002
20 S. Semple, "Dermal exposure to chemicals in the workplace: Just how important is skin absorption?", Occup. Environ. Med., Vol. 61, pp. 376-382, 2004   DOI
21 ATSDR, "Toxicological Profile for. Hexamethylene Diisocyanate(HDI)", CAS# 822-06-0. Agency for Toxic Substances and Disease Registry, August, 1998
22 N. J. Rattray, P.A. Botham, P.M. Hext, D.R. Woodcock, I. Fielding, R.J. Dearman, I. Kimbler, "Induction of respiratory hypersensitivity to diphenolmethane-4,4-diisocyanate(MDI) in guinea pigs", Influence of route of exposure, Toxicol., Vol. 88, pp. 15-30, 1994
23 이수길, 이내우, "분사페인트에 의한 이소시안화물의 노출이 건강에 미치는 영향에 관한 연구", 한국안전학회지, 제23권, 제3호, pp. 79-86, 2008   과학기술학회마을
24 D. Pisaniello, L. Muriale, "The Use of Isocyanate Paints in Auto Refinishing: A Survey of Isocyanate Exposure and Related Work Practices in South Australia", Annals of Occupational Hygiene, Vol. 33, No. 4, pp. 563-572, 1989a   DOI   ScienceOn
25 OSHA HCS, "Title 29 Code of Federal Regulations 1910. 1200", Occupational Safety and Health Administration Hazard Communication Standard (OSHA HCS), Updated July 3, 1998
26 T.C. Cooper, W.A. Heitbrink, M.A. Edmonds, J. Bryant, W. E. Ruch, "In-Depth Survey Report: Control Technology for Autobody Repair and Painting Shops at Jeff Wyler Autobody Shop", Batavia, Ohio, June 16-19, and July 21, 1992. U.S.DHHS, PHS, CDC, NIOSH, NTIS Pub. No. PB-93-216182, 1993