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Magnetic Properties of a $Fe_3B/Nd_2Fe_{14}B$ Magnet due to the Addition fo Co  

Han ,Jong-Soo (Department of Physics, Yeungnam University)
Moon, Soo-Ho (Department of Physics, Yeungnam University)
Woo, Seung-Il (Department of Physics, Yeungnam University)
Kim, Eng-Chan (Department of Physics, Yeungnam University)
Yang, Choong-Jin (Electromagnetic Materials Laboratory, Research Institute of Industrial Science & Technology (RIST))
Park, Eon-Byung (Electromagnetic Materials Laboratory, Research Institute of Industrial Science & Technology (RIST))
Abstract
The addition of Co into $Nd_4Fe_{77.5-x}Co_x(Hfga)_yB_{18.5}(O\;{\le}\;x\;{\le}\;5,\;0\;{\le}\;y\;{\le}\;0.5)$was found to enhance the magnetic properties of $Fe_3B/Nd_2Fe_{14}B$ nanocomposite magnets. The enhancement resulted from the fact that Co retarded the crystallization of {\alpha}-Fe$ or $Fe_3B$ but accelerated that of $ Nd_2Fe_{14}B$. The decreased interval between the onsets of the crystallization temperatures of the $Fe_3B$ and the $ Nd_2Fe_{14}B$phases enabled the grain growth of each phase to be uniform during a post annealing of the melt spun ribbons. the addition of $3{\sim}5$ at.% Co into the ternary composition $Nd_4Fe_{77.5}B_{18.5}$ increased the coercivity ($_iH_c$)from 3.27 to 3.54 kOe with an enhanced remanence value ($4{\pi}M_r$) of around 11.54 kG. From the ribbon magnets of $Nd_4Fe_{71.5}Co_5Hf_0.5}B_{18.5}$made at 26 m/sec and annealed at $680^{\circ}C$ for 10 min, the magnetic properties of $B_r$ = 11.54 kG, $_iH_c$ = 3.54 kOe, and $(BH)_{max}$ = 14.35 MGOe were obtained from a volume production line.
Keywords
$Fe_3B/Nd_2Fe_{14}B$; Co;
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