Browse > Article
http://dx.doi.org/10.5658/WOOD.2015.43.1.76

Furfural Production and Recovery by Two-stage Acid Treatment of Lignocellulosic Biomass  

Shin, Gyeong-Jin (Department of Forest Products and Technology, Chonnam National University)
Jeong, So-Yeon (Department of Forest Products and Technology, Chonnam National University)
Lee, Hong-Joo (Department of Bioenergy and Technology, Chonnam National University)
Lee, Jae-Won (Department of Forest Products and Technology, Chonnam National University)
Publication Information
Journal of the Korean Wood Science and Technology / v.43, no.1, 2015 , pp. 76-85 More about this Journal
Abstract
In this study, we investigated optimal reaction conditions for furfural production from lignocellulosic biomass by two-stage acid treatment. Furfural produced by this method was recovered using XAD-4 resin. Oxalic and sulfuric acid were used as catalysts for the first stage of treatment. The concentration of xylose in the hydrolysate obtained from the first stage was $18.86g/{\ell}$ with oxalic acid and $19.35g/{\ell}$ with sulfuric acid. The concentration of oligosaccharide was relatively high when sulfuric acid was used. Maximum yield of furfural, that is, 55.10% ($6.71g/{\ell}$), was obtained when oxalic acid was used for the first stage and $0.1m{\ell}$ of sulfuric acid was used for the second stage of treatment for 90 min. Furfural production yield increased with increasing the reaction time. Most of the furfural produced by this two-stage treatment method was recovered using XAD-4 resin.
Keywords
two-stage acid treatment; lignocellulosic biomass; sulfuric acid; oxalic acid; furfural;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 Cheng, K.K., Cai, B.Y., Zhang, J.A., Ling, H.Z., Zhou, Y.J., Ge, J.P., Xu, J.M. 2008. Sugarcane bagasse hemicellulose hydrolysate for ethanol production by acid recovery process. Biochemical Engineering Journal 38: 105-109.   DOI
2 Cho, D.H., Kim Y.H., Park J.M., Sim J.H., Kim B.R., Shin S.J. 2012. Characteristics of xylose and glucuronic acid at concentrated sulfuric acid hydrolysis. Journal of Korea TAPPI 44: 9-14.
3 Delgenes, J., Moletta, R., Navarro, J. 1996. Effects of lignocellulose degradation products on ethanol fermentations of glucose and xylose by Saccharomyces cerevisiae, Zymomonas mobilis, Pichia stipitis, and Candida shehatae. Enzyme and Microbial Technology 19: 220-225.   DOI
4 Dias, A.S., Pillinger, M., Valente, A.A. 2005. Dehydration of Xylose into Furfural over Micro-Mesoporous Sulfonic Acid Catalysts. Journal of Catalysis 229: 414-423.   DOI
5 Jeong, S.W., Trinh, L.T.P., Lee, H.J., Lee, J.W. 2014. Improvement of the fermentability of oxalic acid hydrolysates by detoxification using electrodialysis and adsorption. Bioresource Technology 152: 444-449.   DOI
6 Lee, J.W., Rodrigues, R.C.L.B., Jeffries, T.W. 2009. Simultaneous saccharification and ethanol fermentation of oxalic acid pretreated corncob assessed with response surface methodology. Bioresource Technology 100: 6307-6311.   DOI
7 Lee, J.W., Rodrigues, R.C.L.B., Kim, H.Y., Choi, I.G., Jeffries, T.W. 2010. The roles of xylan and lignin in oxalic acid pretreated corncob during separate enzymatic hydrolysis and ethanol fermentation. Bioresource Technology 101: 4379-4385.   DOI
8 Lee, J.W., Jeffries, T.W. 2011. Efficiencies of acid catalysts in the hydrolysis of lignocellulosic biomass over a range of combined severity factors. Bioresource Technology 102: 5884-5890.   DOI   ScienceOn
9 Lee, H.J., Seo, Y.J., Lee, J.W. 2013. Characterization of oxalic acid pretreatment on lignocellulosic biomass using oxalic acid recovered by electrodialysis. Bioresource Technology 133: 87-91.   DOI   ScienceOn
10 Liu, H., Hu, H., Baktash, M.M., Jahan, M.S., Ahsan, L., Ni, Y. 2014. Kinetics of furfurla production from pre-hydrolysis liquor (PHL) of a kraft-based hardwood dissolving pulp production process. Biomass and Bioenergy 66: 320-327.   DOI
11 McKibbins, S.W., Harris, J.F., Saeman, J.F., Neill, W.K. 1962. Kinetics of the acid-catalyzed conversion of glucose to 5-hydroxymethyl-2-furaldehyde and levulinic acid. Forest Products Journal 12: 17-23.
12 Root, D.F., Saeman, J.F., Harris, J.F., Neill, W.K. 1959. Kinetics of the acid catalyzed conversion of xylose to furfural. Forest Products Journal 9: 158-164.
13 Moreau, C., Belgacem, M.N., Gandini, A. 2005. Recent catalytic advances in the chemistry of substituted furans from carbohydrates and in the ensuing polymers. Topics in Catalysis 27: 11-30.
14 Patil, S.K.P., Lund, C.R.F. 2011. Formation and growth of humins via aldol addition and condensation during acid-catalyzed conversion of 5-hydroxymethylfurfural. Energy and Fuels 25: 4745-4755.   DOI
15 Rajeev K., Charles E.W. 2008. The impact of dilute sulfuric acid on the selectivity of xylooligomer depolymerization to monomers. Carbohydrate Research 343: 290-300.   DOI
16 Sangarunlert W., Piumsomboon P., Ngamprasertsith S. 2007. Furfural production by acid hydrolysis and supercritical carbon dioxide extraction from rice husk. Korean Journal of Chemical Engineering 24: 936-941.   DOI
17 Silva, E.A.B., Zabkova, M., Araujo, J.D., Cateto, C.A., Barreiro, M.F., Belgacem M.N., Rodrigues, A.E. 2009. An integrated process to produce vanillin and lignin-based polyurethanes from kraft lignin. Chemical Engineering Research and Design 87: 1276-1292.   DOI   ScienceOn
18 Sluiter, A., Hames, B., Ruiz, R., Scarlata, C., Sluiter, J., Templeton, D., Crocker, D. 2008. In: Laboratory Analytical Procedure No. TP-510-42618. NREL, Golden, CO.
19 Weil, J.R., Dien, B., Bothast, R., Hendrickson, R., Mosier, N.S., Ladisch, M.R., 2002. Removal of fermentation inhibitors formed during pretreatment of biomass by polymeric adsorbents. Industrial and Engineering Chemistry Research 41: 6132-6138.   DOI
20 Wyman, C.E. 1999. Biomass ethanol: technical progress, opportunities, and commercial challenges. Annual Review of Energy and the Environment 24: 189-226.   DOI
21 Yemis, O., Mazza, G. 2011. Acid-catalyzed converison of xylose, xylan and straw into furfural by microwave-assisted reaction. Bioresource Technology 102: 7371-7378.   DOI
22 Yoo, C.G., Kuo, M., Kim, T.H. 2012. Ethanol and furfural production from corn stover using a hybrid fractionation process with zinc chloride and simultaneous saccharification and fermentation (SSF). Process Biochemistry 47: 319-326.   DOI
23 Zakrzewska, M.E., EwaBogel-Lukasik, E., Bogel-Lukasik, R. 2011. Ionic liquid-mediated formation of 5-Hydroxymethylfurfural-A Promising Biomass-Derived Building Block. Chemical Review 111: 397-417.   DOI   ScienceOn
24 Zhu, Y., Kong, Z.N., Stubbs, L.P., Lin, H., Shen, S., Anslyn, E.V., Maguire J.A. 2010. Conversion of cellulose to hexitols catalyzed by ionic liquid- stabilized ruthenium nanoparticles and a reversible Binding Agent. ChemSusChem 3: 67-70.   DOI