Browse > Article
http://dx.doi.org/10.5658/WOOD.2012.40.3.212

Current Research Trends in Wood Preservative for Enhanced Durability : A Literature Review on Copper Based Preservatives  

Kim, Yeong-Suk (Department of Forest Products and Biotechnology, College of Forest Science, Kookmin University)
Publication Information
Journal of the Korean Wood Science and Technology / v.40, no.3, 2012 , pp. 212-227 More about this Journal
Abstract
Current research trends in wood preservatives for enhancing durability was reviewed. Due to leaching of recent Copper-Based Preservatives commonly used as chemicals for pressure treatment; they have been a growing concern, especially in improving the fixation of the copper as alkyl ammonium quat. and azol in wood and preventing the leaching of active ingredients. With the appearance of emulsion type chemicals using micronized and nano-sized wood preservatives, researchs on characteristics of Copper-Based Preservatives regarding penetration and fixation in wood are debatable. Moreover, unlike the case of CCA, the recent alkyl ammonium quat. and azol bear a serious threat in the decrease of antimicrobial effectiveness against wood destroying fungi with copper tolerance. Therefore, development and research of co-biocide is needed.
Keywords
copper based wood preservative; copper tolerent fungi; micronized & nano-sized wood preservative;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Xie, C., J. N. R. Ruddick, S. J. Retting, and F. G. Herring. 1995. Fixation of ammoniacal cpooer preservatives:Reaction of vanillin, a lignin model compound with ammoniacal copper sulfate solution. Holzforschung 49(6): 483-490   DOI
2 Xue, W., P. Kennepohl, and J. N. R. Ruddick. 2010. A comparison of the chemistry of alkaline copper and micronized copper treated wood. The International Research Group on Wood Protection. IRG/WP 10-30528.
3 Xue, W., P. Kennepohl, and J. N. R. Ruddick. 2011. Quantification of mobile copper(II) levels in micronized copper treated wood. The International Research Group on Wood Protection. IRG/WP 11-40550.
4 Yu, L., J. Cao, P. A. Cooper, and T. Ung. 2009. Effect of hot air post-treatments on copper leaching resistance in ACQ-D treated Chinese fir. European J. Wood Products 00: 1-7.
5 Yu, L., J. Cao, W. Gao, and H. Su. 2010. Evaluation of ACQ-D treated Chinese fir and Mongolian Scots pine with different post-treatments after 20 months of exposure. The International Research Group on Wood Protection. IRG/WP 10-30530.
6 Zahora, A. 2010. Influence of Copper Preservative Type on Earlywood and Latewood Distribution of Copper in Treated Wood. The International Research Group on Wood Protection. IRG/WP 10-40507.
7 Zahora, A. 2011. Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Tehnique. The International Research Group on Wood Protection. IRG/WP 11-40549.
8 Zhang, J. and R. Ziobro. 2009. Micronized Copper Preservative Systems: Observations on the Release of Cupric ion ($Cu^{2+}$) from Treated Wood and Performance against Wood Decay Fungi. The International Research Group on Wood Protection. IRG/WP 09-30519.
9 Tang, J. D., A. Perkins, and S. V. Diehl. 2011. Gene expression analysis of a copper-tolerant brown rot fungus on MCQ-treated wood. The International Research Group on Wood Protection. IRG/WP 11-10748.
10 Tang, J. D., T. Sonstegard, S. Burgess, and S. V. Diehl. 2010. A genomic sequencing approach to study wood decay and copper tolerance in the brown rot fungus, Antrodia radiculosa. The International Research Group on Wood Protection. IRG/WP 10-10-10720.
11 Ung, T., M. Negad, and P. Cooper. 2010. Distribution and availability of preservative components in ACQ treated wood - effect of coatings and weathering. The International Research Group on Wood Protection. IRG/WP 10-30537.
12 Woo, C. S. and P. I. Morris. 2010. Sensitivity to Copper of Basidiospores from Copper Tolerant Fungi: Fomitopsis palustris and Oligoporus placentus. The International Research Group on Wood Protection. IRG/WP 10-10707.
13 Ung, Y. T. and P. A. Cooper. 2005. copper stabilization in ACQ-D treated wood: retention, temperature and species effects. Holz als Roh- und Werkstoff 63: 186-191.   DOI
14 Wang, L. and D. P. Kamdem. 2011. Copper Migration from Micronized Copper Preservatives Treated Wood in soil contact: Effect of soil pH. The International Research Group on Wood Protection. IRG/WP 11-50280.
15 Westin, M., J. J. M. Edlund, P. L. Brelid, and I. Johansson. 2010. Field trials of wood preservatives on UC3 retention Part 1. Durability results after 13 years in and above ground. The International Research Group on Wood Protection. IRG/WP 10-30548.
16 Wu, Q., F. Yao, K. Ragon, J. Curole, M. Voitier, and T. shupe. 2010. Extruded wood plastic composites based on ACQ and MCA-treated wood materials. The International Research Group on Wood Protection. IRG/WP 10-40495.
17 Sun, F., L. Yang, A. Chen, B. Bao, and Q. LI. 2009. Mold-resistance Effect of Bamboo Wood Treated with CCC-organic Complexs. The International Research Group on Wood Protection. IRG/WP 09-30514.
18 Mitsuhashi, J., J. J. Morrell, L. Jin, and A. F. Preston. 2007. The effect of additives on copper losses from alkaline copper treated wood, IRG > WP 07-50246, 38th International Research Group on wood protection, Annual Meeting, Jackson, Wyoming, May 20-24, 2007.
19 Pankras, S., P. Cooper, T. Ung, and L. Ayoyemi. 2009. Copper to quat ratio in alkaline copper quat (ACQ) wood preservative-Effercts on fixation and leaching of perservative components in red pine. The International Research Group on Wood Protection. IRG/WP 09-30496.
20 Pasek, E. A. 2003. Minimizing preservative losses: fixation a report of the P4 migration/ fixation/ depletion task force. In: Proc.of the American Wood-preservers' Assoc. 99: 100-124.
21 Ray, M., D. Dickinson, and K. Archer. 2010. A comparison of the Performance of Related Copper Based Preservatives against Soft Rot. The International Research Group on Wood Protection. IRG/WP 10-30540.
22 Ruddick, J. N. R. 2003. Basic copper wood preservatives, preservative depletion: Factors which influence loss. In: Proc. Can. Wood preserv. Assoc. 24: 26-59.
23 Steenkhaer Hastrup, S. C., F. Green III, C. A. Clausen, and B. Jensen, 2005. Tolerance of Serpula lacrymans to copper-based wood preservatives. International Biodeterioration & Biodegradation 56: 173-177.   DOI   ScienceOn
24 Stirling, R. and J. Drummond. 2009. Re-Distribution of Copper in the Cell Walls of Wood Treated with Micronized Copper Quat. The International Research Group on Wood Protection. IRG/WP 09-30506.
25 Stirling, R. and P. I. Morris. 2010. Degradation of Carbon-Based Preservatives by Black-stain Fungi. The International Research Group on Wood Protection. IRG/WP 10-30533.
26 Stirling, R. and P. I. Morris. 2010. Mobility of Copper from MCQ in shell-Treated Wood Exposed Above Ground. The International Research Group on Wood Protection. IRG/WP 10-30534.
27 Kofoed, M. and J. N. R. Ruddick. 2010. A comparison of the corrosion of alkaline copper and micronized copper treated wood. The International Research Group on Wood Protection. IRG/WP 10-40515.
28 Lee, M. J. and P. Cooper. 2010. Adsorption of ACQ components in wood. The International Research Group on Wood Protection. IRG/WP 10-30522.
29 Lesar, B. and M. Humar. 2008. Performance of wood impregnated with N-methylol and copper based aqueous solutions. Holz Roh Werkst 66: 311-312.   DOI
30 Li, Z., X. Li, Y. Zhang, and M. Jiang. 2009. Leaching properties of copper and triazole. The International Research Group on Wood Protection. IRG/WP 09-30509.
31 Lucas, N. and J. N. R. Ruddick. 2002. Determination of the amine to copper ratio remaining in wood after water leaching. Doc. No. 30285. Int. Res. Group on Wood Pres., IRG. Secretariat Stockholm, Sweden.
32 Matsunaga, H., Y. Kataoka, M. Kiguchi, and P. Evans. 2010. Copper nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Can Nanoparticles penetrate the Cell Walls of Tracheids and Ray Parenchyma?. The International Research Group on Wood Protection. IRG/WP 10-30547.
33 Matsunaga, H., Y. Kataoka, M. Kiguchi, and P. Evans. 2011. Copper nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit. The International Research Group on Wood Protection. IRG/WP 11-30566.
34 McIntyre, C. R. 2010. Comparison of Micronized Copper Particle Sizes. The International Research Group on Wood Protection. IRG/WP 10-30538.
35 Mclntyre, C. R., M. H. Freeman, T. F. Shupe, Q. Wu, and D. P. Kamdem. 2009. The Form of Copper: Does It Really Matter?. The International Research Group on Wood Protection. IRG/WP 09-30513.
36 Evans, F. G. 2009. Leaching of the copper component from full scale decking boards during on summer season. The International Research Group on Wood Protection. IRG/WP 09-50260.
37 Feci, E., L. Nunes, S. Palanti, S. Duarte, G. Predieri, and F. Vignali. 2009. Effectiveness of sol-gel treatments coupled with copper and boron against subterranean termites. The International Research Group on Wood Protection. IRG/WP 09-30493.
38 Freeman M. H. and C. R. Mclntyre. 2008. A comprehensive review of copper-based wood preservatives with a focus on new micronized or dispersed copper systems. Forest Prod. J. 58(11): 6-27.
39 Humar, M., F. Pohleven, M. Sentjurc, M. Veber, P. Razpotnik, R. Pogni, and M. Petric. 2003. Performance of waterborne Cu(II) octanoate/ethanol-amine wood preservatives. Holzforschung 57(3): 127-134.
40 Hale, M. D. and R. A. Eaton. 1986. Soft-rot cavity formation in fice preservative-treated hardwood species. Trans. Br. Mycol. Soc. 86: 585-590.   DOI
41 Humar, M., M. Sentjurc, S. A. Amartey, and F. Pohleven. 2005. Influence of acidification of CCB (Cu/Cr/B) impregnated wood on fungal copper tolerance Chemosphere 58(6): 743-749.   DOI   ScienceOn
42 Humar, M., D. Zlindra, and F. Pohleven. 2006. Effect of fixation time on leaching of copper-ethanolamine based wood preservatives. Holz Roh-Werkstoff 65: 329-330.
43 Humar, M., N. Thaler, and B. Lesar. 2011. Influence of wood swelling agents on penetration and copper leaching of copper-ethanolamine based wood preservatives. The International Research Group on Wood Protection. IRG/WP 11-30556.
44 Jiang, X. and J. N. R. Ruddick. 2000. A comparison of the leaching resistance of copper 2 ethanolamine abd ciooer ethlylenediamine treated Scots pine. THE The International Research Group on Wood Protection. IRG/WP 00-30233.
45 Kamdem, D. P. and J. Zhang. 2000. Contribution of wood components on the absorption of copper amine. The International Research Group on Wood Protection. IRG/WP 00-30216.
46 김윤수, 김규혁, 김영숙. 2004. 목재보존과학, 전남대학교출판부.
47 Archer, K. 2007. Cell wall penetration of particulate copper wood Preservative systems in southern pine. Unpublished oral presentation at 38th Annual Meeting. Int. Res. Group in Wood pres., IRG secretatiat, Stockholm.
48 Archer, K. and A. Preston. 2006. An overview of copper based wood preservatives. Wood protection 2006. http://www.forestprod.org/woodprotection06archer.pdf.
49 Choi, S. M., J. N. R. Ruddick, and P. I. Morris. 2002. The copper tolerance of mycelium vs spores for two brown rot fungi. IRG/WP 02-10422. Int. Res. Group on Wood Pres., IRG Secretariat, Stockholm.
50 Chen, G. 2010. Laboratory evaluation of borate: amine: copper derivatives in wood for fungal decay. The International Research Group on Wood Protection. IRG/WP 10-30543.
51 Clausen, C. A. and F. Green. 2003. Oxalic acid overproduction by copper-tolerant brown-rot basidiomycetes on southern yellow pine treated with copper-based preservatives. International Biodeterioration & Biodegradation 51(2): 139-144.   DOI   ScienceOn
52 Clausen, C. A. F. Green III, B. M. Woodward, J. W. Evans, and R. C. DeGroot. 2000. Correlation between oxalic acid production and copper tolerance in Wolfiporia cocos. International Biodeterioration & Biodegradation 46: 69-76.   DOI   ScienceOn
53 Cooper, P. A. and Y. T. Ung. 2009. Component leaching from CCA, ACQ and a micronized copper quat (MCQ) system as affected by leaching protocol. The International Research Group on Wood Protection. IRG/WP 09-50261.
54 Cracium, R., M. Maier, and J. Habicht. 2009. A theoretical- industrial correlation and perspective on copper-based wood preservatives. THE The International Research Group on Wood Protection. IRG/WP 09-30499.
55 Craig, R. M. and M. H. Freeman. 2011. Standardized Field Trials with Micronized Copper. The International Research Group on Wood Protection. IRG/WP 11-30564.
56 김영숙, 이종신, 라종범, 강승모, 이동흡. 2011. 최근 국내 목재보존산업이 당면한 과제와 향후 모색 방향에 대하여, 2011 한국목재공학회 학술발표 요지집.