Browse > Article

Phenolic Compounds from Fallen Needle of Larix kaempferi Carr.  

Kwon, Dong-Joo (Dept. of Wood Science & Engineering, College of Forest Sciences, Kangwon National University)
Kim, Jin-Kyu (Dept. of Wood Science & Engineering, College of Forest Sciences, Kangwon National University)
Bae, Young-Soo (Dept. of Wood Science & Engineering, College of Forest Sciences, Kangwon National University)
Publication Information
Journal of the Korean Wood Science and Technology / v.34, no.6, 2006 , pp. 72-80 More about this Journal
Abstract
Fallen needle (8.5 kg) of Larix kaempferi were collected and extracted with 95% EtOH. The EtOH extracts were evaporated under reduced pressure, concentrated, and successively fractionated with a series of hexane, methylene chloride, ethylacetate and water on a separatory funnel to be freeze dried. A portion of ethylacetate and water soluble powder were chromatographed on a Sephadex LH-20 column eluting with aqueous MeOH and EtOH-hexane mixture. Spectrometric analyses such as NMR and FAB-MS, including TLC, were performed on the seven isolated compounds and were elucidated as (+)-catechin, (-)-epicatechin, 2"-O-rhamnosylvitexin, juglanin, afzelin, laricitrin-3-O-${\beta}$-D-glucopyranoside, isoquercitrin and cedrusin.
Keywords
Larix kaempferi Carr.; ethanol extracts; chromatography; ethyl acetate soluble; water soluble; flavonoids; neolignan;
Citations & Related Records
연도 인용수 순위
  • Reference
1 김태욱. 1996. 한국의 수목, 교학사, pp.21-22
2 함연호. 2000 사시나무屬과 버드나무屬 主要 樹種 樹皮의 抽出成分에 關한 硏究, 깅원대학교 박사학위논문
3 Kang, S. S., J. S. Kim, W. J. Kwak, and K H Kim 1990. Flavonoids from the Leaves of Ginkgo biloba, Kor. J. Pharmacogn, Vol. 21. No.2, pp. 111-120   과학기술학회마을
4 Kazuma, K, N. Noda, and M Suzuki. 2003. Malonylated flavonol glycosides from the petals of Clitoria ternatea, Phytochemistry, Vol. 62, No. 2, pp. 229-237   DOI   ScienceOn
5 Han Y., S. Nishibe, Y. Noguchi, and Z. Jin 2001. Flavonol glycosides from the stems of Trigonella foenumgraecum, Phytochemistry, Vol. 58, No.4, pp. 577-580   DOI   ScienceOn
6 Kim, H. Y., B. H. Moon, H. J. Lee, and D. H. Choi. 2004. Flavonol glyco sides from the leaves of Eucommia ulmoides O. with glycation inhibitory activity, Journal of Ethnopharmacology, Vol. 93, pp. 227-230   DOI   ScienceOn
7 Miki, K and T. sasaya 1980. Lignans from Heartwood of Larix leptolepis Gord, Mokuzai Gakkaisbi, Vol. 26, No.9, pp. 633-636
8 조재명 외 12명, 2003. 원색 약용식용 수목도설, 유성사, pp. 10-11
9 Agrawal, P. K, S. K Agarwal, and R. P. Rastogi. 1980. A new neolignan and other phenolic constituents from Cedrus deodara, phytochemistry, Vol. 19, No. 6, pp. 1260-1261   DOI   ScienceOn
10 Harbone J. B and T. J. J. Mabry. 1982. The flavonoids: advance in research, Chapman and Hall Ltd. pp. 281-292
11 Miki, K and T. sasaya 1979. Dihydrobenzofuran Derivatives in the inner Bark of Larix leptolepis Gord, Mokuzai Gakkaishi, Vol. 25, No. 6, pp. 437-441
12 Miki, K. and T. sasaya 1979. Glycerol Derivatives in the inner Bark of Larix leptolepis Gord, Mokuzai Gakkaishi, Vol. 25, No. 5, pp. 361-366
13 Slimestad, R, Q. M. Andersen, G. W. Francis, A Marston, and K. Hostett manu 1995. Syringetin 3-O-(6''-acetyl)-$\beta$-glucopyranoside and other Flavonols from Needles of Norway spruce, Picea abies, Phytochemistry, Vol. 40, No.5, pp. 1537-1542   DOI   ScienceOn
14 이상극. 2003. 國內産 主要 針葉樹 잎의 抽出成分, 강원 대학교 박사학위논문
15 Miki, K, K. Ito, and T. sasaya. 1979. Lignans from Heartwood of inner Bark of Larix leptolepis Gord, Mokuzai Gakkaishi, Vol. 25, No. 10, pp. 665-670
16 Kim, J. K, W. G. Park, and Y. S. Bae. 1997. Flavonoid Glycosides from Needles of Larix leptolepis (Pinaceae), Mokchaekonghak, vol. 25, No. 2, pp. 81-87
17 Agrawal, P. K. 1989. Carbon-13 NMR of flavonoids, Elsevier. pp. 333-335
18 Takehara, T and T. sasaya 1979a Lignans from Sapwood of Larix leptolepis Gord, Mokuzai Gakkaishi, Vol. 25, No.7, pp. 516-517
19 Takehara, T and T. sasaya 1979b. Dihydrobenzofuran Derivatives from Sapwood of Larix leptolepis Gord, Mokuzai Gakkaisbi, Vol. 25, No. 10, pp. 660-664
20 Agrawal, P. K, S. K. Agarwal, and R. P. Rastogi. 1982. Two lignans from Cedrus deodara, phytochemistry, Vol. 21, No.6, pp. 1459-1461   DOI   ScienceOn
21 Hussein, S. A. M., A. N. M. Hashem, M. A. Seliem, U. Lindequist, and M. A. M. Nawwar. 2003. Polyoxygenated flavonoids from Eugenia edulis, Phytochemistry, Vol. 64, No.4, pp. 883-889   DOI   ScienceOn
22 Yoon, S. Y., H. J. Lee, S. S. Lee, D. H Choi, and K. H. Paik 2000. Studies on Biological Activity of Wood Extractives(V) Identification of Flavonoids from the Heartwood of Larix leptolepis and Their Antioxidative Activities-, Mokchaekonghak, vol. 28, No.3, pp. 78-84