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Constituents from the Roots of Hemerocallis fulva  

Kim, Ju-Sun (Natural Products Research Institute, Seoul National University)
Son, Kun-Ho (Department of Food and Nutrition, Andong National University)
Chang, Hyeun-Wook (College of Pharmacy, Yeongnam University)
Kim, Hyun-Pyo (College of Pharmacy, Kangwon National University)
Bae, Ki-Hwan (College of Pharmacy, Chungnam National University)
Kang, Sam-Sik (Natural Products Research Institute, Seoul National University)
Publication Information
Korean Journal of Pharmacognosy / v.33, no.2, 2002 , pp. 105-109 More about this Journal
Abstract
Besides chrysophanol and friedelin, mixtures of n-hydrocarbons [pentacosane (72.6%), heptacosane (14.6%), tetracosane (5.8%), nonacosane (4.1 %) and hexacosane (2.9%)], n-hydrocarbon alcohols [octacosanol (70.5%) and hexacosanol (29.5%)], l-monoacyl glycerols [acyl part; behenic acid (43.5%), lignoceric acid (32.4%), cerotic acid (9.3%), tricosanoic acid (8.9%), pentacosanoic acid (2.6%), octacosanoic acid (2.3%), heneicosanoic acid (1.0%)], wax esters [behenic acid (56.3%), lignoceric acid (23.0%), cerotic acid (19.8%), tricosanoic acid (4.6%), octacosanoic acid (4.0%), pentacosanoic acid (1.7%), triacontanoic acid (0.6%)/ octacosanol (33.7%), hexacosanol (21.0%), tetracosanol (15.6%), triacontanol (10.5%), docosanol (6.0%), tricosanol (6.0%), heptacosanol (4.2%), nonacosanol (3.0%)] and sterols [${\beta}-sitosterol$ (73.2%), stigmasterol (14.6%), campesterol (12.2%)] were isolated from the roots of Hemerocallis fulva. The acid : alcohol combinations of the major wax esters were $C_{48}$: 22 : 26, 24 : 24, $C_{46}$: 22 : 24, and $C_{44}$: 22 : 22. This is the first report of l-monoacyl glycerols and friedelin from this plant. All isolates were identified on the basis of spectral data and chemical reactions.
Keywords
Hemerocallis fulva; Liliaceae; aliphatic compounds; monoacyl glycerol; triterpenoid; sterol; friedelin; anthraquinone; chrysophanol;
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