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http://dx.doi.org/10.7473/EC.2020.55.3.191

Catalytic Reduction of ortho- and meta-Nitroaniline by Nickel Oxide Nanoparticles  

Jeon, Sugyeong (Department of Convergence Science, Graduate School, Sahmyook University)
Ko, Jeong Won (Nanomaterials Research Institute, Sahmyook University)
Ko, Weon Bae (Department of Convergence Science, Graduate School, Sahmyook University)
Publication Information
Elastomers and Composites / v.55, no.3, 2020 , pp. 191-198 More about this Journal
Abstract
Nickel oxide (NiO) nanoparticles were synthesized by a reaction of nickel nitrate hexahydrate (Ni(NO3)2·6H2O) and sodium hydroxide (NaOH). The synthesized NiO nanoparticles were examined with X-ray diffraction, scanning electron microscopy, Raman spectroscopy, and ultraviolet-visible (UV-vis) spectroscopy. The NiO nanoparticles were used as the catalyst for the reduction of o- and m-nitroaniline to phenylenediamine. The reduction rate of m-nitroaniline was faster than that of o-nitroaniline. The reduction rate for both o- and m-nitroaniline increased as the reaction temperature increased. The rate of reduction for nitroaniline followed a pseudo first-order reaction rate law.
Keywords
Catalytic reduction; Nickel oxide nanoparticles; o-Nitroaniline; m-Nitroaniline;
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