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The Oxidation of Fullerene[$C_{60}$] using Several Oxidants under Microwave Irradiation  

Ko, Weon-Bae (Department of Chemistry, Sahmyook University)
Hwang, Sung-Ho (Department of Chemistry, Sahmyook University)
Ahn, Ju-Hyun (Department of Chemistry, Sahmyook University)
Publication Information
Elastomers and Composites / v.40, no.1, 2005 , pp. 45-52 More about this Journal
Abstract
Synthesis or fullerene oxides[$C_{60}(O)_n$] ($n=1{\sim}4$ or n=1) by fullerene[$C_{60}$] and several oxidants such as 3-chloroperoxy benzoic acid, benzoyl peroxide, trichloroisocyanuric acid, and chromium(VI) oxide took place under microwave irradiation. The reactivity in solid state of fullerene[$C_{60}$] with various oxidants under same microwave rendition increased in order or 3- chloroperoxy benzoic acid > benzoyl peroxide > trichloroisocyanuric acid $\simeq$chromium(VI) oxide. The MALDI-TOF-MS, UV-visible spectra and HPLC analysis confirmed that the products of fullerene oxidation were [$C_{60}(O)_n$] ($n=1{\sim}4$ or n=1).
Keywords
Fullerene Oxides[$C_{60}(O)_n$] ($n=1{\sim}4$ or n=1); Several Oxidants; Microwave Irradiation; MALDI-TOF-MS;
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