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http://dx.doi.org/10.7731/KIFSE.2014.28.6.028

Combustive Properties of Pinus rigida Plates Painted with Alkylenediaminoalkyl-Bis-Phosphonic Acid Salts (Mn+)  

Park, Myung-Ho (Dept. of Mechanical Engineering, Kangwon National University)
Chung, Yeong-Jin (Dept. of Fire Protection Engineering, Kangwon National University)
Publication Information
Fire Science and Engineering / v.28, no.6, 2014 , pp. 28-34 More about this Journal
Abstract
Two kinds of new piperazinomethyl-bis-phosphonic acid $M^{n+}$ ($PIPEABPM^{n+}$) were synthesized and their combustive properties of Pinus rigida plates treated with $PIPEABPM^{n+}$ were tested in comparison with the previously synthesized chemicals. Pinus rigida specimens were painted in three times with 15 wt% $PIPEABPM^{n+}$ solutions at the room temperature. After drying specimen treated with chemicals, combustive properties were examined by the cone calorimeter (ISO 5660-1). As a result, the combustion-retardation properties were partially increased by due to the treated $PIPEABPM^{n+}$ solutions in the virgin Pinus rigida. Especially, the specimens treated with $PIPEABPM^{n+}$ showed both the lower peak heat release rate ($HRR_{peak}$) (173.48~145.36) s and total heat release rate (THRR) (73.0~55.2) $MJ/m^2$ than those of virgin piperazinomethyl-bis-phosphonic acid (PIPEABP)-plate. Compared with virgin PIPEABP-plate, the specimens treated with the $PIPEABPM^{n+}$ showed low combustive properties. However the specimens treated with $PIPEABPM^{n+}$ showed both the shorter time to ignition (TTI) (58~18) s and the time to flameout (Tf) (564~456) s than those of virgin PIPEABP-plate by increasing the thermal conductivity.
Keywords
Alkylenediaminoalkyl-bis-phosphonic acid $M^{n+}$ ($PIPEABPM^{n+}$); Time to ignition (TTI); Total heat released rate (THRR); Peak heat release rate (PHRR);
Citations & Related Records
Times Cited By KSCI : 5  (Citation Analysis)
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