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http://dx.doi.org/10.7731/KIFSE.2013.27.5.57

Combustion Characteristics of Pinus rigida Plates Painted with Alkylenediaminoalkyl-Bis-Phosphonic Acid Derivatives  

Chung, Yeong-Jin (Dept. of Fire Protection Engineering, Kangwon National University)
Publication Information
Fire Science and Engineering / v.27, no.5, 2013 , pp. 57-63 More about this Journal
Abstract
This study was performed to test the combustive properties of Pinus rigida plates treated with piperazinomethyl-bisphosphonic acid (PIPEABP), methylpiperazinomethyl-bis-phosphonic acid (MPIPEABP), and N,N-dimethylethylenediaminomethyl- bis-phosphonic acid (MDEDAP). Pinus rigida specimens were painted in three times with 15 wt% alkylenediaminoalkyl- bis-phosphonic acid solutions at the room temperature. After drying specimen treated with chemicals, combustive properties were examined by the cone calorimeter (ISO 5660-1). As a result, the combustion-retardation properties were increased by due to the treated alkylenediaminoalkyl-bis-phosphonic acid solutios in the virgin Pinus rigida. Especially, the specimens treated with chemicals showed both the later time to ignition (TTI) (148-116 s) and longer time to flameout (Tf) (633-529 s) than those of virgin plate by reducing the burnig rate. Compared with virgin pinus rigida plate, the specimens treated with the alkylenediaminoalkyl-bis-phosphonic acids showed partially low combustive properties. However the specimens treated with PIPEABP showed both the higher peak heat release rate (PHRR) (187.56 $kW/m^2$) and higher total heat release rate (THRR) (75.7 $MJ/m^2$) than those of virgin plate.
Keywords
Alkylenediaminoalkyl-bis-phosphonic acids; Time to ignition (TTI); Total heat released rate (THRR); Peak heat release rate (PHRR);
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Times Cited By KSCI : 3  (Citation Analysis)
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