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A Study on the Characteristics of Pyrolysis of Methyl Ethyl Ketone Peroxide with Addition of Sulfuric Acid  

Jung Doo-Kyun (한국소방안전협회)
Choi Jae-Wook (부경대학교 안전공학과)
Lee In-Sik (부경대학교 안전공학과 대학원)
Publication Information
Fire Science and Engineering / v.18, no.4, 2004 , pp. 52-56 More about this Journal
Abstract
An experiment to examine the characteristics of pyrolysis of Methyl Ethyl Ketone Peroxide was conducted in an air-present environment, using TG-DTA. Decomposition starting temperature was decreased as the increase of 98% concentrated H₂SO₄ to the MEKPO and the maximum decomposition temperature of MEKPO was 116.8℃. The activated energy calculated from differential method of pure MEKPO, MEKPO with 1 wt%, 3wt%, and 5wt% of H₂SO₄ were 0.576㎉/mo1, 0.355㎉/㏖, 0.284㎉/㏖ and 0.258㎉/㏖ respectively.
Keywords
Methyl Ethyl Ketone Peroxide; Air-present environment; Pyrolosis; Decomposition; Activated energy;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
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