Browse > Article

A study on the relations between the color intensity and the antioxidant activity of caramelization products  

신민자 (경희대학교 조리과학과)
윤혜현 (경희대학교 조리과학과)
안명수 (성신여자대학교 식품영양학과)
Publication Information
Korean journal of food and cookery science / v.18, no.6, 2002 , pp. 603-612 More about this Journal
Abstract
The study was carried out to compare the relation between the color intensity and antioxidant activity of caramelization products using xylose(XY), glucose(GL). sucrose(SU), glucose+citric acid(GLCA), glucose+sodium citrate(GLSC), heated at 80, 120 and 140$\^{C}$ for 24hrs, respectively. The color intensity(absorbance at 490nm) of the browning mixtures increased as the browning temperature and time increased. But the degrees of color intensity of SU and GLCA changed very little. The hydrogen donating ability(HDA) of browning reaction products was generally enhanced as the browning temperature and time increased. When browning mixtures were heated at 80$\^{C}$, the HDA of GLGC was the highest, but the HDA of GLSC was the highest when heated at 120 and 140$\^{C}$. The antioxidant activities for the corn oil substrate containing the anhydrous ethanol extracts from the browning mixtures was inferior to that of SU, but was superior to that of GLCA. The relations among the color intensity, the antioxidant activity, and the hydrogen donating ability(HDA, reducing power) of the browning reaction mixtures were as follows: As the color intensity increased, the antioxidant activity decreased. The correlation coefficient of the color intensity and the antioxidant activity by regression equation was -0.73 ∼ -0.82. As the reducing power increased, the antioxidant activity decreased. The correlation coefficient between the reducing power and the antioxidant activity by regression equation was -0.98 ∼ -0.99. Therefore, the antioxidant activity of browning reaction mixtures seemed not correlated with the color intensity and the reducing power.
Keywords
caramel type browning reaction; color intensity; hydrogen donating ability; antioxidant activity;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Griffith, T and Johnson, JA : Relation of the browning reaction to storage stability of sugar cookies, Cereal Chem., 34:159, 1957
2 Ohnishi, S and Shibamoto, T : Volatile compounds from heated beef fat and beef fat with glycine. J. Agr. Food Chem., 32:987, 1984   DOI
3 Zipser, MW and Watts, BM : Lipid oxidation in heat sterilized beef. Food Technol., 15:445, 1961
4 Lee, DI, Heo, TR and Kim, DH : Comparision of the antioxidant effects of ethyl alcohol extracts of a Maillard-type and a caramelization-type browning reaction mixtures. Korean J. Food Sci. Technol., 7(1):43, 1975   DOI   ScienceOn
5 Hashiba, H : The browning reaction of amadori compound derived from various sugars. Agric. Biol. Chem., 46:547, 1982   DOI
6 Hwang, CI and Kim, DH : The antioxidant activity of some extracts from various stages of a Maillard-type browning reaction mixture. Korean J. Food Sci. Technol., 5:84, 1973   DOI
7 Paik, HD and Kim, DH : Antioxidant activity of methylene chloride extracts obtained from glucose-ammonia(1M+8M) browning mixtures. Korean J. Food Sci. Technol., 11:93, 1979
8 Yamaguchi, N and Fujimaki, M: Studies on browning reaction products from reducing sugars and amino acids, part XV. Comparision of antioxidative activity of melanoidin with that of each tocopherol homologue and synergistic effect of melanoidin on tocopherols. J. Food Sci. and Technol. (Japan), 21(1):6, 1974   DOI
9 A.O.C.S. : Official and Tentative Method 3rd ed., Am. Oil Chem. Soc., Chicago, Method cd-25, 1978
10 Choi, ID and Ahn MS : A study on the reaction rate and the antioxidant effects of caramelization reaction mixtures. Korean J. Soc. Food Sci., 11(4), 396, 1995
11 Rhee, C and Kim, DH : Antionxidant activity of acetone extracts obtained from a caramelization-type browning reaction. J. Food Sci., 40:460, 1975   DOI
12 Shin, MJ and Ahn, MS : A study on the antioxidant activity of products of caramel type browning reaction. Korean J. Soc. Food Sci., 16(6):629, 2000
13 Wolfrom, ML and Cavalieri, LF : Chemical interactions of amino compounds and sugars. Ⅲ. The conversion of D-glucose to 5-hydroxymethy 1-2-furfural. J. Am. Chem. Soc., 70:514, 1948   DOI
14 Ahn, MS : Effects of reaction temperature, time, and presence of organic acids or their salts on the antioxidant activity of caramelization mixtures. Thesis for the Degree of Doctor, Korea University, 1984
15 Lewis, VM : Studies on the non-enzymatic browning of food stuffs. Ph. D. Thesis, University of Massachusetts, 1948
16 Kawashima, K, Itoh, H and Chibata, I : Antioxidant effect of peptide in combination with sugar on autoxidation of edible oils. Agric. Biol. Chem., 45(4): 987, 1981   DOI
17 Lingnert, H and Eriksson, CE : Antioxidative Maillard reaction products. Ⅰ. Products from sugars and free amino acids. J. Food Process Pres., 4:161, 1980   DOI
18 Shin, MJ and Ahn, MS : A study on the reaction rate of caramel type browning reaction. Korean J. Soc. Food Sci., 15(4):363, 1999
19 Eskin, NAM, Henderson, HW and Townseand, RH : Biochemistry of food processing in "Biochemistry of food" 2nd academuc press, lnc., San Diego, p93, 1971
20 Kato, H, Yamamoto, M and Fujimaki, M : Mechanisms of browning degradation of D-fructose in special comparison with D-glucose-glycine reaction. Agric. Biol. Chem., 33(6):939, 1969   DOI
21 Park, CK : Effects of the functional groups in the reaction amino acids on the antioxidant activity of Maillard browning reaction mixtures. Thesis for the Degree of Doctor, Korea University, 1985.
22 Kim, HJ : A study on the reaction rate and antioxidant activity of Maillard reaction mixtures of amino acids and dipeptides. Thesis for the Degree of Doctor, Sungshin Women's University, 1995
23 Yi, BH and Kim, DH : Antioxidant activity of maltol, kojic acid, levulinic acid, furfural, 5-hydroxymethyl furfural, and pyrazine. Korean J. Food Sci. Technol., 14(3):265, 1982
24 Yamaguchi, N and Fujimaki. M : Studies on the browning reaction from reducing sugar and amino acid. Part. Fractionation of browning reaction products on sephadex columm and antioxidantive activity of fractionated material(Ⅱ). J. Food Sci. and Technol. (Japan), 17:142, 1970   DOI
25 Hodge, JE : Dehydrated foods, chemistry of browning reaction in model systems, Agr., Food Chem., 1:15, 928, 1953   DOI
26 Kirigaya, N, Kato, H and Fugimaki, M : Studies on antioxidant activity of non-enzymatic browning reaction products(1), Reaction of color intensity and reductones with antioxidant activity of browning reaction products. Agric. Biol. Chem., 32(3):287, 1968   DOI
27 Buera, M, del Pilar, Chirife, J, Resnik, SL and Lozano, RD : Nonenzymatic browning in liquid model systems of high water activity. Kinetics of color changes due to reaction between glucose and glycine peptides. J. Food Sci., 52(4):1068, 1987   DOI
28 Son, JY : Effect of caffeic acid on the antioxidant activity of Maillard reaction products. Thesis for the Degree of Doctor, Korea University, 1992
29 Hashiba, H : A glucose-diglycine condensation product participating oxygen -dependent browning. J. Agric. Food Chem., 23(3):539, 1975   DOI