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http://dx.doi.org/10.9713/kcer.2021.59.2.269

Development of the Highly Dispersed Palladium-Nickel Catalysts for Catalytic Partial Oxidation of Methane  

Lee, Seunghyun (Department of Chemical and Biomolecular Engineering, Sogang University)
Jeon, Jonghyun (Department of Chemical and Biomolecular Engineering, Sogang University)
Kim, Juchan (Department of Chemical and Biomolecular Engineering, Sogang University)
Ha, Kyoung-Su (Department of Chemical and Biomolecular Engineering, Sogang University)
Publication Information
Korean Chemical Engineering Research / v.59, no.2, 2021 , pp. 269-275 More about this Journal
Abstract
In this study, ordered mesoporous silica-supported Ni catalysts were prepared for catalytic partial oxidation of methane (CPOM) by using electroless nickel plating method. Unlike conventionally impregnated catalysts, the electrolessly-plated nickel catalyst showed that nickel was highly dispersed and formed stably on silica-supported surface. It was verified by TEM-EDS analysis. During the activity tests, the electrolessly-plated nickel was barely sintered and the amount of carbon deposition was very small. Consequently, the catalyst was far less deactivated, while the sintering was significantly observed in the cases of the catalysts prepared by the conventional impregnation method. Regarding the palladium-promoted catalysts, the reducibility of nickel was increased, and the reaction performances were enhanced in terms of CH4 conversion and H2/CO ratio of produced syngas.
Keywords
Catalytic partial oxidation of methane; GTL; Nickel plating;
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