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http://dx.doi.org/10.9713/kcer.2021.59.1.21

Fabrication of Chitosan Nanoparticles with Lactococcus lactis for the Removal of Phthalate Endocrine Hormone  

Yoon, Hee-Soo (Department of Chemical & Bio Engineering, Gachon University)
Kang, Ik-Joong (Department of Chemical & Bio Engineering, Gachon University)
Publication Information
Korean Chemical Engineering Research / v.59, no.1, 2021 , pp. 21-34 More about this Journal
Abstract
Chitosan nanoparticles (CNPs) and Lactococcus lactis (L. lac.) were used as adsorbents to evaluate the adsorption performance of endocrine hormones, which are phthalates, in the healthy food packages. CNPs were produced through the cross bond with tripolyphosphate (TPP), and L. lac.-CNPs were prepared through the introduction of L. lac. during the preparation. The various functional groups of all adsorbents were identified using Fourier transform infrared spectroscopy (FTIR). Adsorption isotherm and adsorption kinetic confirmed the adsorption behavior and mechanism of CNPs, L. lac. and L. lac.-CNPs. The adsorption behavior of DBP and DEP for all particles was more suitable for the Freundlich adsorption isotherm model than for the Langmuir adsorption isotherm model, which means that the surface of the particles is heterogeneous. The adsorption mechanism was more suitable for the Pseudo-2nd-order model than for the Pseudo-1st-order model. This means that due to the presence of various functional groups on the particle surface, the adsorption of DBP and DEP is dominated by chemical adsorption such as electrostatic attraction and hydrogen bonding rather than physical adsorption. Finally, it was confirmed that the preparation of CNPs and L. lac.-CNPs can be performed easily and quickly, and it could be used as a cheaper adsorbent that can effectively remove phthalates.
Keywords
Endocrine hormone; Phthalate; Chitosan nanoparticles; Lactococcus lactis;
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