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http://dx.doi.org/10.9713/kcer.2019.57.4.455

The Chemical Aspects on Hydrotreating Catalysis for Residue  

Jeon, Min-Seok (Department of Chemical and Biological Engineering, Hanbat National University)
Lee, Youngjin (Regional Innovation Center for Industrialization of Advanced Chemical Materials, Hanbat National University)
Jung, Hoi-Kyoeng (Department of Chemical and Biological Engineering, Hanbat National University)
Kim, Hyung-Jong (Surface Technology Center, Korea Institute of Industrial Technology (KITECH))
Yoon, Seong-Ho (Institute for Materials Chemistry and Engineering, Kyushu University)
Kim, Taegon (Battery Research Center, R&D Campus Daejeon, LG Chem.)
Park, Joo-Il (Department of Chemical and Biological Engineering, Hanbat National University)
Publication Information
Korean Chemical Engineering Research / v.57, no.4, 2019 , pp. 455-460 More about this Journal
Abstract
Hydrotreating catalysis refers to a various hydrogenation which saturate an unsaturated hydrocarbon, together with removing heteroatoms such as sulfur, nitrogen, oxygen, and trace metals from different petroleum streams in a refinery. Most refineries include at least three hydrotreating units for upgrading naphtha, middle distillates, gas oils, intermediate process streams, and/or residue. Among them, hydrotreating catalysis for residue are the core of the process, because of its complexity. This article reviews recent progress in tackling the issues found in the upgrading residues by hydrotreating, focusing on the chemistry of hydrodemetallization (HDM) and hydrodesulfurization (HDS). We also discuss the composition and functions of hydrotreating catalysts, and we highlight areas for further improvement.
Keywords
Hydrotreating Catalysis; Residue; Hydrodemetallization; Hydrodesulfurization;
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1 Klein, G. C., Kim, S., Rodgers, R. P. and Marshall, A. G., "Mass Spectral Analysis of Asphaltenes. I. Compositional Differences Between Pressure-drop and Solvent-drop Asphaltenes Determined by Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry," Energ. Fuels, 20, 1965-1972(2006).   DOI
2 Shi, Q., Hou, D., Chung, K. H., Xu, C., Zhao, S. and Zhang, Y., "Characterization of Heteroatom Compounds in a Crude oil and its Saturates Aromatics, Resins, and Asphaltenes (SARA) and Non-basic Nitrogen Fractions Analyzed by Negative-ion Electrospray Ionization Fourier Transform ion Cyclotron Resonance Mass Spectrometry," Energ. Fuels, 24, 2545-2553(2010).   DOI
3 Furimsky, E., "Catalysts for Upgrading Heavy Petroleum Feeds: Chapter 2. Properties of Heavy Feeds," Stud. Surf. Sci. Catal., 169, 5-22(2007).   DOI
4 Zeinali, M. and Jamalan, M., "Biocatalytic Activity of Methylmodified Microperoxidase-11 in Transformation of Nickel- and Vanadium-porphyrins," J. Mol. Catal. B: Enzym., 79, 21-26(2012).   DOI
5 (a) Mitchell, P. C. H. and Scott, C. E., "Interaction of Vanadium and Nickel Porphyrins with catalysts, relevance to ca Talytic Demetallization," Catal. Today, 7(4), 467-477(1990).   DOI
6 (b) Premovic, P. I., Tonsa, I. R., Pajovic, M. T., Lopez, L., Monaco, S. L., Dordevic, D. M. and Pavlovic, M. S., "Electron Spin Resonance Study of the Kerogen/asphaltene Vanadyl Porphyrins: Air Oxidation," Fuel, 80, 635-639(2001).   DOI
7 Kim, T., Ryu, J., Kim, M. J., Kim, H. J., Shul, Y. G., Jeon, Y. and Park, J. I., "Characterization and Analysis of Vanadium and Nickel Species in Atmospheric Residues," Fuel, 117(A), 783-791(2014).
8 Ellis, J., Rechsteiner, C., Moir, M. and Wilbur, S., "Determination of Volatile Nickel and Vanadium Species in Crude oil and Crude oil Fractions by Gas Chromatography Coupled to Inductively Coupled Plasma Mass Spectrometry," J. Anal. At. Spectrom., 26, 1674-1678(2011).   DOI
9 Mckenna, A. M., Williams, J. T., Putman, J. C., Aeppli, C., Reddy, C. M., Valentine, D. L., Lemkau, K. L., Kellermann, M. Y., Savory, J. J., Kaiser, N. K., Marshall, A. G. and Rodgers, R. P., "Unprecedented Ultrahigh Resolution FT-ICR Mass Spectrometry and Parts-per-billion Mass Accuracy Enable Direct Characterization of Nickel Vanadyl Porphyrins in Petroleum from Natural Seeps," Energ. Fuels, 28, 2454-2464(2014).   DOI
10 Zhao, X., Liu, Y., Xu, C., Yan, Y., Zhang, Y., Zhang, Q., Zhao, S., Chung, K., Gray, M. R. and Shi, Q., "Separation and Characterization of Vanadyl Porphyrins in Venezuela Orinoco Heavy Crude Oil," Energ. Fuels, 27, 2874-2882(2013).   DOI
11 Wei, J. and Hegedus, L. L., "Catalyst Design-Progress and Perspective," (Ed.), John Wiley & Sons: New York(1987).
12 Kim, T., Al-Mutairi, A., Marafi, A. M. J., Park, J. I., Koyama, H., Yoon, S. H., Miyawaki, J. and Mochida, I., "Hydrotreatment of Two Atmospheric Residues from Kuwait Export and Lower Fars Crude Oils," Fuel, 117(A), 191-197(2014).   DOI
13 Pereira de Oliveira, L., Verstraete, J. J., Trujillo Vazquez, A. and Kolb, M., "Molecular Reconstruction of Petroleum Fractions: Application to Vacuum Residues from Different Origins," Energy Fuels, 27, 3622-3641(2013).   DOI
14 Muller, H., Adam, F. M., Panda, S. K., Al-Jawaad, H. H. and Al-Hajji, A. A., "Evaluation of Quantitive Sulfur Speciation in Gas Oils by Fourier Transform ion Cyclotron Resonance Mass Spectrometry: Validation by Comprehensive Two-dimensional Gas Chromatography," J. Am. Soc. Mass Spectrom., 23, 806-815(2012).   DOI
15 Carbognani, L., Arambarri, J. C., Molero, H. and Pereira-Almao, P., "High Temperature Simulated Distillation of Bitumen Fractions with Open Tubular Capillary Depleted Silicone/siloxane Stationary Phases," Energ. Fuels, 27, 2033-2041(2013).   DOI
16 Onukwuli, O. D., Onyia, I. M., Ekumankama, E. O. and Okeke, S. I., "Solvent Demetallization of Atmospheric and Vacuum Residues," Petro. Sci. Tech., 17, 37-49(1999).   DOI
17 Miller, J. T. and Fisher, R. B., "Structural Determination by XAFS Spectroscopy of Non-porphyrin Nickel and Vanadium in Maya Residuum, Hydrocracking Residuum, and Toluene-insoluble Solid," Energ. Fuels, 13, 719-727(1999).   DOI
18 David Pearson, C. and Green, J. B., "Comparison of Processing Characteristics of Mayan and Wilmington Heavy Residues: 1. Acid-base-neutral Fractionation and Characterization," Fuel, 68, 456-464(1989).   DOI
19 David Pearson, C. and Green, J. B., "Comparison of Processing Characteristics of Mayan and Wilmington Heavy Residues: 2 Characterization of Vanadium and Nickel Complexes in Acidbase-neutral Fractions," Fuel, 68, 465-474(1989).   DOI
20 Gao, Y. Y., Shen, B. X. and Liu, J. C., "Distribution of Nickel and Vanadium in Venezuela Crude Oil," Pet. Sci. Tech., 31, 509-515(2013).   DOI
21 Laredo, G. C., Lopez, C. R., Alvarez, R. E. and Cano, J. L., "Naphthenic Acids, Total Acid Number and Sulfur Content Profile Characterization in Isthmus and Maya Crude Oil," Fuel, 83, 1689-1695(2004).   DOI
22 Marafi, M. and Stanislaus, A., "Spend Catalyst Waste Management: A Review: Part 1-Development in Hydroprocessing Catalyst Waste Reduction and Use," Resour. Conserv. Recy. 52, 859-873(2008).   DOI
23 Huang, B. S., Yin, W. F., Sang, D. H. and Jiang, Z. Y., "Synergy effect of Naphthenic Acid Corrosion and Sulfur Corrosion in Crude Oil Distillation Unit," Appl. Surf. Sci., 259, 664-670(2012).   DOI
24 Avila, B. M. F., Pereira, V. B., Gomes, A. O. and Azevedo, D. A., "Speciation of Organic Sulfur Compounds Using Comprehensive Two-dimensional Gas Chromatography Coupled to Timeof-flight Mass Spectrometry: A Powerful Tool for Petroleum Refining," Fuel, 126, 188-193(2014).   DOI
25 Li, Z., Xia, Z., Lai, W., Zheng, J., Chen, B., Yi, X. and Fang, W., "Hydrodemetallation (HDM) of Nickel-5,10,15,20-tetraphenylporphyrion (Ni-TPP) over NiMo/${\gamma}-Al_2O_3$ Catalyst Prepared by One-pot Method with Controlled Precipitation of the Components," Fuel, 97, 504-511(2012).   DOI
26 Maity, S. K., Blanco, E., Ancheyta, J., Alonso, F. and Fukuyama, H., "Early Stage Deactivation of Heavy Crude Oil Hydroprocessing Catalysts," Fuel, 100, 17-23(2012).   DOI
27 Marafi, M. and Stanislaus, A., "Preparation of Heavy Oil Hydrotreating Catalyst from Spent Residue Hydroprocessing Catalysts," Catal. Today, 130, 421-428(2008).   DOI
28 (b) Verentchikov, A. N., Yavor, M. I., Hasin, Y. I. and Gavrik, M. A., "Multireflection Planar Time-of-flight Mass Analyzer. II: The High-resolution Mode," Tech. Phys, 50, 82-86 (2005).   DOI
29 Boursier, L., Souchon, V., Dartiguelongue, C., Ponthus, J., Courtiade, M. and Thiebaut, D., "Complete Elution of Vacuum Gas Oil Resins by Comprehensive High-temperature Two-dimensional Gas Chromatography," J. Chromatogr. A, 1280, 98-103(2013).   DOI
30 (a) Verentchikov, A. N., Yavor, M. I., Hasin, Y. I. and Gavrik, M. A., "Multireflection Planar Time-of-flight Mass Analyzer. I: An Analyzer for a Parallel Tandem Spectrometer," Tech. Phys, 50, 73-81(2005).   DOI
31 Klitzke, C. F., Corilo, Y. E., Siek, K., Binkley, J., Patrick, J. and Eberlin, M. N., "Petroleomics by Ultrahigh-resolution Time-of-Flight Mass Spectrometry," Energ. Fuels, 26, 5787-5794(2012).   DOI
32 Dickie, J. P. and Yen, T. F., "Macrostructures of the Asphaltic Fractions by Various Instrumental Methods," Anal. Chem, 39, 1847-1852(1967).   DOI
33 Mullins, O. C., "The Modified Yen Model," Energ. Fuels, 24, 2179-2207(2010).   DOI
34 Long, F. X., Gevert, B. S. and Abrahamsson, P., "Mechanistic Studies of Initial Decay of Hydrodemetallization Catalysts Using Model Compounds-effects of Adsorption of Metal Species on Alumina Support," J. Catal., 222, 6-16(2004).   DOI
35 Hauser, A., Marafi, A., Almutairi, A. and Stanislaus, A., "Comparative Study of Hydrodemetallization (HDM) Catalyst Aging by Boscan Feed and Kuwait Atmospheric Residue," Energ. Fuels, 22, 2925-2932(2008).   DOI
36 Al-Mutairi, A., Bahzad, D. and Halabi, M. A., "A Comparation Study on the Performance of a Catalyst System for the Desulfurization of Two Kinds of Atmospheric Residues, Kuwait Export and EOCENE Residual Oils," Catal. Today, 125, 203-210(2007).   DOI
37 Rana, M. S., Ancheyta, J. and Rayo, P., "A Comparative Study for Heavy oil Hydroprocessing Catalysts at Micro-flow and Benchscale Reactors," Catal. Today, 109, 24-32(2005).   DOI
38 Jarullah, A. T., Mujtaba, I. M. and Wood, A. S., "Kinetic Model Development and Simultaneous Hydrodenitrogenation and Hydrodemetallization of Crude oil in Trickle Bed Reactor," Fuel, 90, 2165-2181(2011).   DOI
39 Long, F. X. and Gevert, B. S., "Kinetic Parameter Estimation and Statistical Analysis of Vanadyl Etioporphyrin Hydrodemetallization," Comput. Chem. Eng., 27, 697-700(2003).   DOI
40 Long, F. X. and Gevert, B. S., "Kinetics of Vanadyl Etioporphyrin Hydrodemetallization," J. Catal., 200, 91-98(2001).   DOI