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http://dx.doi.org/10.9713/kcer.2017.55.6.778

Pervaporation Dehydration of Acetic Acid Aqueous Solution using PVA/PAA Membrane with Na-Y Zeolite  

Kwon, YongSung (Department of Industrial Chemistry, Pukyong National University)
Chaudhari, Shivshankar (Department of Industrial Chemistry, Pukyong National University)
Moon, MyungJun (Department of Industrial Chemistry, Pukyong National University)
Shon, MinYoung (Department of Industrial Chemistry, Pukyong National University)
Park, Ahrumi (Center for Membranes, Korea Research Institute of Chemical Technology)
Kim, YoungMi (Center for Membranes, Korea Research Institute of Chemical Technology)
Publication Information
Korean Chemical Engineering Research / v.55, no.6, 2017 , pp. 778-784 More about this Journal
Abstract
Membranes were prepared by incorporating Na-Y zeolite particles into poly(vinyl alcohol) (PVA) cross-linked with poly(acrylic acid) (PAA). The membrane was characterized by FT-IR spectroscopy, contact angle measurement, swelling test, SEM analysis, and XRD analysis. The pervaporation separation of water/acetic acid mixtures was carried out using prepared membranes. From the results, it was shown that the hydrophilic property of prepared membrane increased with increase of zeolite contents and the PVA/PAA membrane with zeolite addition showed higher permeation flux than that of without zeolite membrane. The PVA/PAA membrane containing 8 wt% zeolite showed the highest permeation flux and separation in the feed solution containing 10 wt% acetic acid.
Keywords
Pervaporation; Zeolite; Flux; Separation factor; PVA; PAA;
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Times Cited By KSCI : 2  (Citation Analysis)
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1 Han, B., Li, J., Chen, C. and Wickramasinghe, S. R., "Effect of Degree of Formaldehyde Acetal Treatment and Maleic Acid Crosslinking on Solubility and Diffusivity of Water in PVA Membrane," Inst. of Chem. Eng., 81, 1385-1392(2003).   DOI
2 Rhim, J.-W., Yeom, S.-W., Kim, S.-W. and Lee, K.-H., "Pervaporation Separation and Swelling Measurement of Acetic Acid-water Mixture Using Crosslinked with PVA Membranes," J. Appl. Polym. Sci., 63, 521527(1997).
3 Kusumocahyo, S. P., Sanoh, K. and Kensaka, M., "Water Permselectivity in the Pervaporation of Acetic Acid-water Mixture Using Crosslinked Poly(vinyl alcohol) Membranes," Sep. Sci. Tech., 18, 141-150(2000).
4 Alghezawi, N., Sanli, O., Aras, L. and Asman, G., "Separation of Water-acetic Acid Mixtures Through Acrylonitrile Grafted Poly (vinyl alcohol) Membranes by Pervaporation," Chem. Eng. Process., 44, 51-54(2005).   DOI
5 Yuan, H.-K., Ren, J., Ma, X. H. and Xu, Z.-L., "Dehydration of Ethyl Acetate Aqueous Solution by Pervaporaton Using PVA/PAN Hollow Fiber Composite Membrane," J. Desalination, 280, 252-258(2011).   DOI
6 Aminabhavi, T. M. and Toti, U. S., "Pervaporation Separation-water Acetic Mixtures Using Polymeric Membrane," Des. Monomers Polym., 6, 211-236(2003).   DOI
7 Barber, T. A. and Miller, B. D., "Pervaporation Technology: Fundamentals and Environmental Application," Chem. Eng., 88-90(1994).
8 Jonquieres, A., "Industrial State of the Art of Pervaporation and Vapour Permeation in the Western Countries," J. Membr. Sci., 206, 87-117(2002).   DOI
9 Kalyani, S., Smitha, B., Sridhar, S. and Krishnaiah, A., "Pervaporation Separation of Ethanol Water Mixtures Through Sodium Alginate Membranes," Desalination, 229, 68-81(2008).   DOI
10 Venkata Prasad, C., Yeriswamy, B., Sudhakara, H. and Subha, M. C. S., "Preparation and Characterization of Nanoparticle Filled Mixed Matrix Membranes for the Pervaporation Dehydration of Isopropyl Alcohol," J. Appl. Polym. Sci., 125, 3351-3360(2012).   DOI
11 Asman, G. and Sanli, O., "Characteristics of Permeation and Separation for Acetic Acid-water Mixtures Through Poly(vinyl alcohol) Membrane Modified with Poly(Acrylic acid)," Sep. Sci. Tech., 38, 1963-1980(2003).   DOI
12 Huang, R. Y. and Yeom, C. K., "Pervaporation Separation of Aqueous Mixtures Using Cross-linked Poly(vinyl alcohol), Part II. Permeation of Ethanol-water Mixtures," J. Membr. Sci., 51, 273-292(1990).   DOI
13 Ray, S. and Ray, S. K., "Separation of Organic Mixtures by Pervaporation Using Crosslinked and Filled Rubber Membrane," J. Membr. Sci., 285, 108-119(2006).   DOI
14 Figueiredo, K. C. S., Alves, T. L. M. and Borges, C. P., "Poly(vinyl alcohol) Films Crosslinked by Glutaraldehyde Under Mild Condition," J. Appl. Polym. Sci., 111, 3074-3080(2009).   DOI
15 Asman, G. and Sanli, O., "Separation of Acetic Acid-water Mixtures Through Poly(vinyl alcohol)/poly(acrylic acid) Alloy Membranes Using Evapomeation and Temperature Difference Evapomeation Methods," Sep. Sci. Tech., 41, 11931209(2006).
16 Durmaz-Hilmioglu, N., Yildirim, A. E., Sakaoglu, A. S. and Tulbentci, S., "Acetic Acid Dehydration by Pervaporation," Chem. Eng. Process., 40, 263-267(2001).   DOI
17 Kulkarni, S. S., Tambe, S. M., Kittur, A. A. and Karuduraganavar, M. Y., "Preparation of Novel Composite Membrane for the Pervaporation Separation of Water Acetic Acid Mixture," J. Membr. Sci., 285, 420-431(2006).   DOI
18 Bowen, T., Nobel, R. and Falconer, J., "Fundamentals and Application of Pervaporation Through Zeolite Membranes," Membr. Sci., 245, 1-33(2004).   DOI
19 Kittur, A. A., Kariduraganavar, M. Y., Toti, U. S., Ramesh, K. and Aminabhavi, T. M., "Pervaporation Separation of Water Isopropanol Mixtures Using ZSM-5 Zeolite Incorporated Poly(vinyl alcohol) Membranes," J. Appl. Polym. Sci., 90, 2441-2448(2003).   DOI
20 Li, G., Kilkuchi, E. and Matsukata, M., "Separation of Water Acetic Acid Mixtures by Pervaporation Using a Thin Mordenite Membrane," Sep.Purif.Technol, 32, 199-206(2003).   DOI
21 Flynn, E. J., Keane, D. A., Tabari, P. M. and Morris, M. A., "Pervaporation Performance Enhancement Through the Incorporation of Mesoporous Silica Sphere in to PVA Membranes," Sep. Purif. Technol., 118, 73-80(2013).   DOI
22 Kirk, R. E. and Othmer, D. F., Encyclopedia of Chemical Technology 4th Ed., John Wiley and Sons, Inc., New York, 18, p. 1006 (2000).
23 Khoonsap, S. and Amnuaypanich, S., "Mixed Matrix Membranes Prepared from Poly(vinyl alcohol) (PVA) Incorporated with Zeolite 4A-graft-poly(2-hydroxyethyl methacrylate) (Zeolite-g-PHEMA) for the Pervaporation Dehydration of Water-Acetone Mixtures," J. Membr. Sci., 367, 182-189(2011).   DOI
24 Sun, W., Wang, X., Yang, J., Han, L. H., Zhang, Y. and Wang, J., "Pervaporation Separation of Acetic Acid-water Mixtures Through Sn-substituted ZSM-5 Zeolite Membranes," J. Membr. Sci., 335, 83-88(2009).   DOI
25 Han, I. S. and Cheryan, M., "Downstream Processing of Acetate Fermentation Broth by Nano Filtration," Appl. Biochem. Biotechnol., 19, 57-58(1993).
26 Pietsch, S., BP. Personal communication (2004-2005).
27 Isiklan, N. and Sanli, O., "Separation Characteristics of Acetic Acid-Water Mixtures by Pervaporation using Poly(vinyl alcohol) Membranes Modified with Malic Acid," Chem. Eng. Process, 44, 1019-1027(2005).   DOI
28 Yeom, C.-K. and Lee, K.-H., "Pervaporation Separation of Water Acetic Acid Mixture Through Poly(vinyl alcohol) Membrane Crosslinked with Glutaraldehyde," J. Membr. Sci., 109, 257-265 (1996).   DOI
29 Baheri, B., Shahverdi, M., Rezakazemi, M., Motaee, E. and Mohammadi, T., "Performance of PVA/NaA Mixed Matrix Membrane for Removal of Water from Ethylene Glycol Solution by Pervaporation," Chem. Eng. Commun., 202, 316-321(2015).   DOI
30 Kukulska-Zajac, E., Gora-Marek, K. and Datka, J., "IR and TPD Studies of the Reaction of Acetic Acid in Zeolite NaHY," Micropor Mesopor Mat, 96, 216-221(2006).   DOI
31 Ahn, H. S., Lee, H. R. and Lee, Y. T., "Pervaporation of Water/Ethanol Mixture through NaY Zeolite Membrane," Korean Chem. Eng. Res., 42(5), 558-563(2004).
32 Ahn, H. S., Lee, H. R. and Lee, Y. T., "Pervaporation Characteristics of NaA Zeolite Membrane for Water/Ethanol Mixture," Korean Chem. Eng. Res., 43(2), 243-248(2005).