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http://dx.doi.org/10.9713/kcer.2017.55.5.579

Development and Physical Properties of Acrylic Resin Coatings Containing Tertiary Amine  

Kim, Jin-Wook (Department of Chemical Engineering, Kwangwoon University)
Lee, Dong-Chan (Department of Chemical Engineering, Kwangwoon University)
Choi, Joong-So (Department of Chemical Engineering, Kwangwoon University)
Publication Information
Korean Chemical Engineering Research / v.55, no.5, 2017 , pp. 579-585 More about this Journal
Abstract
Acrylic resins containing tertiary amine were synthesized by a radical polymerization of monomers including n-butyl acrylate (BA), methyl methacrylate (MMA), n-butyl methacrylate (BMA) and dimethylaminoethyl methacrylate (DMAEMA), and diethylaminoethyl methacrylate (DEAEMA) containing tertiary amine. Synthesized acrylic resins were applied to develope coatings of acrylic resins containing tertiary amine. And ${\gamma}$-glycidoxypropyl trimethoxysilane (GPTMS) or ${\gamma}$-glycidoxypropyl triethoxysilane (GPTES) was used as hardener. Developed coatings were white colored ones to use titanium dioxide and were hardened with hardener for measuring their physical properties. Measured physical properties were basic properties, adhesivity and weatherability. As a result, developed acrylic resins coatings containing tertiary amine showed excellent adhesivity on various substrates and also showed the same result on weatherability on dry weather condition.
Keywords
Acrylic resins containing tertiary amine; Radical polymerization; Adhesivity; Weatherability;
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Times Cited By KSCI : 2  (Citation Analysis)
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1 Shi, X., Fernando, B. M. D. and Croll, S. G., "Concurrent Physical Aging and Degradation of Crosslinked Coating Systems in Accelerated Weathering," J. Coat. Technol. Res., 5(3), 299-309(2008).   DOI
2 Orel, B., Orel, Z. C., Jerman, R. and Radoczy, I., "Coil-coating Paints for Solar Collector Panels-II. FT-IR Spectroscopic Investigations," Sol. Wind Tech., 7(6), 713-717(1990).   DOI
3 Bellamy., L. J., The infra-red spectra of complex molecules, John Willey and Sons, New York(1954).
4 Wang, S. J., Fan, X. D., Si, Q. F., Kong, J., Liu, Y. Y., Qiao, W. Q. and Zhang, G. B., "Preparation and Characterization of a Hyperbranched Polyethoxysiloxane Based Anti-fouling Coating," J. Appl. Polym. Sci., 102(6), 5818-5824(2006).   DOI
5 Pouchert, C. J. and Behnke, J., The aldrich library of 13C and 1H FT-NMR spectra, Aldrich Chemical(1993).
6 Fratricova, M., Schwarzer, P. and Kuhn, W., "$^{1}H$-NMR Relaxation Study of Cross-linking and Aging Processes in Polyurethane Coatings," KGK., 59(5), 229-235(2006).
7 Pretsch, P. D., Clerc, T., Siebl, J. and Simon, W., Spectral Data for Structure Determination of Organic Compounds, 2nd ed., Springer-Verlag(1989).
8 Sonpatki, M. M., Ravindranath, K. and Ponrathnam, S., "Segmented Copoly(ether-ester) Elastomers. Influence of Hard Segment Length and Substitution on Mesophase Formation," Polym. J., 26(7), 804-815(1994).   DOI
9 Nippon Shokubai Kagaku Kogyo Co. Ltd., "Curable Composition," JPN. Patent No. 630300521(1988).
10 Rees, S. W., "Non-isocyante Two-pack Coatings," Oil Colour Chem. Assoc., 75(3), 102-104(1992).
11 Ooka, M. and Ozawa, H., "Recent Developments in Crosslinking Technology for Coating Resins," Prog. Org. Coat., 23(4), 325-338 (1994).   DOI
12 Kim, S. K., Choi, Y. H. and Park, H. S., "Synthesis of Silicone/acrylic Resins for Super-weatherable Coatings," J. Korean Oil Chem. Soc., 16(2), 171-177(1999).
13 Lee, H. J., Jang, S. H., Chang, S. M. and Kim, J. M., ",Study on Polymerization Condition of Water-based Acrylic Adhesion" Korean Chem. Eng. Res., 48(5), 609-614(2010).
14 Moon, C. J. and Lee, J. H., "Use of Curdlan as Environmental Friendly Paint Additive," Korean Chem. Eng. Res., 41(5), 675-678 (2003).
15 Park, H. Y., Kim, S. K., Kim S. S., Choi, I. C, Kim, B. W. and Kim, S. J., "Development and Performance Evaluation of Anti-cavitation Paint with Lamella Glass-flake," Korean Chem. Eng. Res., 54(2), 145-151(2016).   DOI
16 Kim, S. R., Park, H. J., Kim, M. S., Park, H. S. and Kim, S. K., "Film Properties of Weather-resistant Silicone/acrylic Coating Resins of Different Compositions," Polym. Korea, 26(5), 615-622 (2002).
17 Kanegafuchi Kagaku Kogyo Co., "Curable Composition at Room Temperature," U.S. Patent No. 4,975,488(1990).
18 Rao, V. L. and Babu, G. N., "Copolymerizations of Methyl ${\alpha}$-bromoacrylate, 2-bromoethyl Methacrylate and 2,3-dibromopropyl Methacrylate with Vinyltriacetoxysilane," Eur. Polym. J., 26(2), 227-231(1990).   DOI
19 Rosen, M. R., "From Treating Solution to Filler Surface and Beyond: the Life History of a Silane Coupling Agent," J. Coat. Technol., 50(644), 70-82(1978).
20 Witucki, G. L., "A Silane Primer: Chemistry and Applications of Alkoxy Silanes," J. Coat. Techol., 65(822), 57-60(1993).
21 Park, H. S., Yang, I. M., Wu, J. P., Kim, M. S., Hahm, H. S., Kim, S. K. and Rhee, H. W., "Synthesis of Silicone-acrylic Resins and Their Applications to Superweatherable Coatings," J. Appl. Polym. Sci., 81(7), 1614-1623(2001).   DOI
22 Ryntz, R. A., Xie, Q. and Ramamurthy, A. C., "Effects of Coating Solvents on the Morphology of Thermoplastic Polyolefins (TPO)," J. Coat. Technol., 67(843), 45-55(1995).
23 Hattori, N., Tanigawa, M. and Okido, M., "Effects of Glass Transition Temperatures of Films on the Corrosion Resistance after Forming of Pre-Coated Aluminum Sheets," Mat. Trans., 49(5), 1180-1185(2008).   DOI
24 Rogers, G., "Test Instruments for Coating Adhesion," Mat. Perform., 42(7), 40-44(2003).
25 Ni, H., Skaja, A. D., Sailer, R. A. and Soucek, M. D., "Moisturecuring Alkoxysilane-functionalized Isocyanurate Coatings," Maromol. chem. phys., 201(6), 722-732(2000).