Browse > Article
http://dx.doi.org/10.9713/kcer.2017.55.1.7

Separation of Sulfuric Acid from Sulfuric Acid/Glucose Solution by Electrodialysis  

Lee, Se-Hoon (Department of Chemical Engineering, Sunchon National University)
Kim, Young-Sook (ETIS Co)
Chu, Cheun-Ho (ETIS Co)
Na, Il-Chai (CNL Energy Co)
Oh, Yong-Hwan (CNL Energy Co)
Park, Kwon-Pil (Department of Chemical Engineering, Sunchon National University)
Publication Information
Korean Chemical Engineering Research / v.55, no.1, 2017 , pp. 7-12 More about this Journal
Abstract
Recovery of sulfuric acid is very important after biomass converted to sugar by acid hydrolysis. In this work, the separation of sulfuric acid from sulfuric acid/glucose solution was studied by electrodiaysis. Three chamber method, which requires both anion membrane and cation membrane, is the most commonly used in the electrodialysis process, but two chamber method using only an anion membrane was the focus of this study. Sulfuric acid was perfectly separated from a mixture of 10~30 wt% glucose and 1~3 M sulfuric acid by electrodialysis using two chamber method. The separation rate of sulfuric acid lineary increased with higher current density when the affect of diffusion and convection of the membrane was small. Without electric energy, 45% of sulfuric acid was separated by diffusion and convection only.
Keywords
Biomass; Sulfuric acid; Separation; Electrodialysis; Glucose; Anion membrane;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Alian Vertes, "Biomass to Biofuels", John Wiley & Sons, New York(2014).
2 Nanguneri, S. R. and Hester, R. D., "Acid/Sugar Separation Using ion Exclusion Resins: Aprocess Analysis and Design," Sep. Sci. Technol., 25, 1829-1842(1990).   DOI
3 Park, J. H. and Kim, J. S., "Two-step Acid Hydrolysis Method for Producing Fermentable Sugar from Lignocellulosic Biomass," Korean Chem. Eng. Res., 54(1), 1-5(2016).   DOI
4 Ladisch, M. R., "Bioseparation Engineering," New York: John Wiley & Sons, Inc(2001).
5 Xie, Y., Phelps, D., Lee, C. H., Sedlak, M., Ho, N. and Wang, N. H. L., "Comparison of Two Adsorbents for Sugar Recovery from Biomass Hydrolyzate," Ind. Eng. Chem. Res, 44, 6816-6823(2005).   DOI
6 Wickramasinghe, S. R. and Grzenia, D. L., "Adsorptive Membranes and Resins for Acetic Acid Removal from Biomass Hydrolysates," Desalination, 234, 144-151(2008).   DOI
7 Nam, H. G., Jo, S. H. and Mun, S., "Comparison of Amberchrom-CG161C and Dowex99 as the Adsorbent of a Four-zone Simulated Moving Bed Process for Removal of Acetic Acid from Biomass Hydrolyzate," Process Biochem., 46, 2044-2053(2011).   DOI
8 Hartmann, B. M., Kaar, W., Yoo, I. K., Lua, L. H. L., Falconer, R. J. and Middelberg, A. P. J., "The Chromatography-free Release, Isolation and Purification of Recombinant Peptide for Fibril Selfassembly," Biotechnol Bioeng, 104, 973-985(2009).   DOI
9 Jeon, K. Y. and Kim, J. H., "Improvement of Fractional Precipitation Process for Prepurification of Paclitaxel," Process Biochem, 44, 736-741(2009).   DOI
10 Han, M. G., Jeon, K. Y., Mun, S. and Kim, J. H., "Development of a Micelle-fractional Precipitation Hybrid Process for the Pre-purification of Paclitaxel From Plant Cell Cultures," Process Biochem, 45, 1368-1374(2010).   DOI
11 Oh, H. J., Jang, H. R., Jung, K. Y. and Kim, J. H., "Evaluation of Adsorbents for Separation and Purification of Paclitaxel from Plant Cell Cultures," Process Biochem, 47, 331-334(2012).   DOI
12 Marti-Calatayud, M. C., Buzzi, D. C., Garcia-Gabaldon, M., Ortega, E., Bernardes, A. M., Tenorio, J. A. S. and Perez-Herranz, V., "Sulfuric Acid Recovery from Acid Mine Drainage by Means of Electrodialysis," Desalination, 343, 120-127(2014).   DOI
13 Wang, X., Wang, Y., Zhang, X., Feng, H. and Xu, T., "In-situ Combination of Fermentation and Electrodialysis with Bipolar Membranes for the Production of Lactic Acid: Continuous Operation," Bioresource Technology, 147, 442-448(2013).   DOI
14 Abla, C. and Rachid, D., "Purification of $H_2SO_4$ of Pickling Bath Contaminated by Fe(II) Ions Using Electrodialysis Process," Energy Procedia, 74, 1418-1433(2015).   DOI
15 Rohman, F. S., Othman, M. R. and Aziz, N., "Modeling of Batch Electrodialysis for Hydrochloric Acid Recovery," Chemical Engineering Journal, 162, 466-479(2010).   DOI
16 Dodgson, K. S., "Determination of Inorganic Sulphate in Studies on the Enzymic and Non-enzymic Hydrolysis of Carbohydrate and Other Sulphate Esters," Biochem. J., 78, 312(1961).   DOI