Browse > Article
http://dx.doi.org/10.9713/kcer.2013.51.4.460

Heat Treatment Effect of Seed on Synthesis of Chemical Manganese Dioxide (CMD) and Electrochemical Properties of LiMn2O4 obtained from the CMD  

Kim, Sung-Wook (Energy Efficient Materials Team, Energy & Environment Division, Korea Institute of Ceramic Engineering and Technology)
Cho, Hae-Ran (Energy Efficient Materials Team, Energy & Environment Division, Korea Institute of Ceramic Engineering and Technology)
Roh, Gwang Chul (Energy Efficient Materials Team, Energy & Environment Division, Korea Institute of Ceramic Engineering and Technology)
Park, Sun-Min (Energy Efficient Materials Team, Energy & Environment Division, Korea Institute of Ceramic Engineering and Technology)
Publication Information
Korean Chemical Engineering Research / v.51, no.4, 2013 , pp. 460-464 More about this Journal
Abstract
A series of Mn compound were prepared by seed-assisted method. The seed used in this reaction was manufactured by calcination of $MnCO_3$ at various temperatures and effects of the calcination temperature on seed-assisted reaction were investigated. With increase of the calcination temperature, CMD (${\gamma}-MnO_2$) was recovered after seed-assisted reactions. LMO used as cathode active material in the Li-ion batteries were synthesized from Mn source obtained in the seed-assisted reaction and the electrochemical properties (rate capability, cycle life performance and specific capacity) of the LMO were investigated. The LMO synthesized from the CMD which is obtained by the reaction with seed prepared by calcination of $MnCO_3$ more than $350^{\circ}C$ shown good electrochemical properties.
Keywords
Li-ion Battery; Chemical Manganese Dioxide; Lithium Manganese Oxide; Electrochemical Properties;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Park, O. K., Cho, Y., Lee, S., Yoo, H. C., Song, H. K. and Cho, J., "Who Will Drive Electric Vehicles, Olivine or Spinel?," Energy Environ. Sci., 4, 1621-1633(2011).   DOI   ScienceOn
2 Shim, J., Kostecki, R., Richardson, T., Song, X. and Striebel, K. A., "Electrochemical Analysis for Cycle Performance and Capacity Fading of a Lithium-ion Battery Cycled at Elevated Temperature," J. Power Sources., 112, 222-230(2002).   DOI   ScienceOn
3 Jiao, F., Shaju, K. M. and Bruce, P. G., "Synthesis of Nanowire and Mesoporous Low-temperature $LiCoO_{2}$ by a Post-templating Reaction," Angew. Chem.-Int. Edit., 44, 6550-6553(2005).   DOI   ScienceOn
4 Li, X. F. and Xu, Y. L., "Enhanced Cycling Performance of Spinel $LiMn_{2}O_{4}$ Coated with $ZnMn_{2}O_{4}$ Shell," J. Solid State Electrochem., 12, 851-855(2008).   DOI
5 Whittingham, M. S., "Lithium Batteries and Cathode Materials," Chem. Rev., 104, 4271-4301(2004).   DOI   ScienceOn
6 Armand, M. and Tarascon, J. M., "Building Better Batteries," Nature., 451, 652-657(2008).   DOI   ScienceOn
7 Gnanaraj, J. S., Pol, V. G., Gedanken, A. and Aurbach, D., "Improving the High-temperature Performance of $LiMn_{2}O_{4}$ Spinel Electrodes by Coating the Active Mass with MgO via a Sonochemical Method," Electrochem. Commun., 5, 940-945(2003).   DOI   ScienceOn
8 Hong, Y. S., Han, C. H., Kim, K., Kwon, C. W., Campet, G. and Choy, J. H., "Structural and Electrochemical Properties of the Spinel $Li(Mn_{2-x}Li_{x/4}Co_{3x/4})O_{4}$, " Solid State Ion., 139, 75-81(2001).   DOI   ScienceOn
9 Komaba, S., Oikawa, K., Myung, S. T., Kumagai, N. and Kamiyama, T., "Neutron Powder Diffraction Studies of $LiMn_{2-y}Al_{y}O_{4}$ Synthesized by the Emission Drying Method," Solid State Ion., 149, 47-52(2002).   DOI   ScienceOn
10 Amine, K., Tukamoto, H., Yasuda, H. and Fujita, Y., "Preparation and Electrochemical Investigation of $LiMn_{2-x}Me_{x}O_{4}$ (Me: Ni, Fe, and x=0.5, 1) Cathode Materials for Secondary Lithium Batteries," J. Power Sources., 68, 604-608(1997).   DOI   ScienceOn
11 He, X. M., Li, J. J., Cai, Y., Jiang, C. Y. and Wan, C. R., "Preparation of Spherical Spinel $LiMn_{2}O_{4}$ Cathode Material for Liion Batteries," Mater. Chem. Phys., 95, 105-108(2006).   DOI   ScienceOn
12 Lu, W., Belharouak, I., Park, S. H., Sun, Y. K. and Amine, K., "Isothermal Calorimetry Investigation of $Li_{1+x}Mn_{2-y}Al_{z}O_{4}$ Spinel," Electrochim. Acta., 52, 5837-5842(2007).   DOI   ScienceOn
13 Eftekhari, A., "Aluminum Oxide as a Multi-function Agent for Improving Battery Performance of $LiMn_{2}O_{4}$ Cathode," Solid State Ion., 167, 237-242(2004).   DOI   ScienceOn
14 Ferracin, L. C., Amaral, F. A., Bocchi, N., "Characterization and Electrochemical Per-formance of the Spinel $LiMn_{2}O_{4}$ Prepared from $\upsilon$-$MnO_{2}$," Solid State Ion., 130, 215-220(2000).   DOI   ScienceOn
15 Chou, S. L., Cheng, F. Y. and Chen, J., "Electrodeposition Synthesis and Electro-chemical Properties of Nanostructured Gamma- $MnO_{2}$ FILms," J. Power Sources., 162, 727-734(2006).   DOI   ScienceOn
16 Hill, L. I., Verbaere, A. and Guyomard, D., "$MnO_{2}$ $(\alpha-, \beta-, \gamma-)$ Compounds Prepared by Hydrothermal-electrochemical Synthesis: Characterization, Morphology, and Lithium Insertion Behavior," J. Power Sources., 119, 226-231(2003).
17 Lee, J. W., Kim, J. I., Roh, K. C., Park, S. M. and Kim, K., "Electrochemical Performances of Li-Mn Spinel Synthesized from Nanosized Chemical Manganese Dioxide," Solid State Sciences., 12, 1687-1691(2003).
18 Zhang, S. S. and Jow, T. R., "Optimization of Synthesis Condition and Electrode Fabri-cation for Spinel $LiMn_{2}O_{4}$ Cathode," J. Power Sources., 109, 172-177(2002).   DOI   ScienceOn
19 Yang, L. X., Zhu, Y. J., Tong, H. and Wang, W. W., "Submicrocubes and Highly Oriented Assemblies of $MnCO_{3}$ Synthesized by Ultrasound Agitation Method and Their Thermal Transformation to Nanoporous $Mn_{2}O_{3}$," Ultrason. Sonochem., 14, 259-265(2007).   DOI   ScienceOn
20 Zhao, J. Z., Tao, Z. L., Liang, J. and Chen, J., "Facile Synthesis of Nanoporous $\gamma$-$MnO_{2}$ Structures and Their Application in Rechargeable Li-ion Batteries," Cryst. Growth. Des., 8, 2799-2805(2008).   DOI   ScienceOn
21 Yang, Z. H., Zhang, W. X., Wang, Q., Song, X. M. and Qian, Y. T., "Synthesis of Porous and Hollow Microspheres of Nanocrystalline $Mn_{2}O_{3}$," Chem. Phys. Lett., 418, 46-49(2006).   DOI   ScienceOn
22 Pistoia, G., Antonini, A., Zane, D. and Pasquali, M., "Synthesis of Mn Spinels From Different Polymorphs of $MnO_{2}$," J. Power Sources., 56, 37-43(1995).   DOI   ScienceOn