Browse > Article
http://dx.doi.org/10.9713/kcer.2013.51.3.388

Plasma Surface Modification of Graphene and Combination with Bacteria Cellulose  

Yim, Eun-Chae (Interdisciplinary program of graduate school for bioenergy and biomaterials, Chonnam National University)
Kim, Seong-Jun (Department of Environmental Engineering, Chonnam National University)
Oh, Il-Kwon (Division of Ocean Systems Engineering, School of Mechanical, Aerospace and Systems Engineering, Korea Advanced Institute of Science and Technology)
Kee, Chang-Doo (School of Mechanical Systems Engineering, Chonnam National University)
Publication Information
Korean Chemical Engineering Research / v.51, no.3, 2013 , pp. 388-393 More about this Journal
Abstract
The study was focused to evaluate the possibility for combination membrane of bacterial cellulose (BC) and graphene with high electrical properties. BC with natural polymer matrix was known to have strong physical strength. For the combination of graphene with BC, the surface of graphene was modified with oxygen plasma by changing strength and time of radio waves in room temperature. Water contact angle of modified graphene grew smaller from $130^{\circ}$ to $12^{\circ}$. XPS analysis showed that oxygen content after treatment increased from 2.99 to 10.98%. Damage degree of graphene was examined from $I_D/I_G$ ratio of Raman analysis. $I_D/I_G$ ratio of non-treated graphene (NTG) was 0.11, and 0.36 to 0.43 in plasma treated graphene (PTG), increasing structural defects of PTG. XRD analysis of PTG membrane with BC was $2{\theta}$ same to BC only, indicating chemically combined membrane. In FT-IR analysis, 1,000 to 1,300 $cm^{-1}$ (C=O) peak indicating oxygen radicals in PTG membrane had formed was larger than NTG membrane. The results suggest that BC as an alternation of plastic material for graphene combination has a possibility in some degree on the part like transparent conductive films.
Keywords
Graphene; Bacterial Cellulose; Plasma; Combination; Modification;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Kim, H. C., Jeon, S. N., Kim, H. I., Choi, H. S., Hong, M. H. and Choi, K. S., "Effects of Oxygen Plasma-treated Graphene Oxide on Mechanical Properties of PMMA/Aluminum Hydroxide Composites," Polymer(Korea), 35, 565-573(2011).   과학기술학회마을
2 Feng, T., Xie, D., Tian, H., Peng, P., Zhang, D., Fu, D., Ren, T., Li, X., Zhu, H. and Jing, Y., "Multi-layer Graphene Treated by O2 Plasma for Transparent Conductive Electrode Applications," Mater. Lett, 73, 187-189(2012).   DOI   ScienceOn
3 Brown, A. J., "An Acetic Acid Ferment Which Forms Cellulose," J. Chem. Soc., 49, 432-439(1886).   DOI
4 Rainer, J. and Luiz, F. F., "Production and Application of Microbial Cellulose," Polym. Degrad Stab. 58, 101-106(1998).
5 Yamanake, S. and Watanabe, K., Applications of Bacterial Cellulose in Cellulosic Polymers, in a Gillbert (ed), Cellulosic Polymers, Blends and Composites, Hanser Inc., Cincinnati, OH, U S A.(1995).
6 Shibazaki, H., Kuga, S. and Onabe, F., "Mechanical Properties of Papersheet Containing Bacterial Cellulose," Japan Tappi 48, 1621-1630(1994).   DOI
7 Reina, A., Jia, X. T., Ho, J., Nezich, D., Son, H., Bulovic, V., Dresselhaus, M. S. and Kong, J., "Large Area, Few Layer Graphene Films on Arbitrary Substrates by Chemical Vapor Deposition," Nano Lett., 9, 30-35(2009).   DOI   ScienceOn
8 Kim, K. S., Zhao, Y., Jang, H., Lee, S. Y., Kim, J. M., Kim, K. S., Ahn, J. H., Kim, P., Choi, J. Y. and Hong, B. H., "Large-scale Pattern Growth of Graphene Films for Stretchable Transparent Electrodes," Nature, 457, 706-710(2009).   DOI   ScienceOn
9 Son, Y. J., Sul, O. J., Chung, D. K., Han, I. S., Choi, Y. J. and Jeong, C. S., "Isolation and Characterization of Trichoderma sp. C-4 Producing Cellulases," Kor. J. Appl. Microbiol. Biotechnol., 25, 346-353(1997).
10 Son, C. J., Chung, S. Y., Lee, J. E. and Kim, S. J., "Isolation and Cultivation Characteristics of Acetobacter xylinum KJ1 Producing Bacterial Cellulose in Shaking and Agitated Culture," J. Appl. Microbiol. Biotechnol. 12, 722-728(2002).
11 Alexander, W. J. and Mitchell, R. L., "Rapid Measurement of Cellulose Viscosity by Nitration Methods," Anal. Chem. 21, 1497-1500(1949).   DOI
12 Andrea, C. F., "Raman Spectroscopy of Grapheme and Graphite: Disorder, Electron-phonon Coupling, Doping and Nonadiabatic Effects," Solid State Commun. 143, 47-57(2007).   DOI   ScienceOn
13 Qi, H. S. Chang, C. Y. and Zhang, L. N., "Effects of Temperature and Molecular Weight on Dissolution of Cellulose in NaOH/urea Aqueous Solution," Cellulose.,15, 779-787(2008).   DOI
14 Egal, M., Budtova, T. and Navard, P. R., "The Dissolution of Microcrystalline Cellulose in Sodiumhydroxide-urea Aqueous Solutions," Cellulose 15, 361-370(2008).   DOI
15 Isogai, A. R., Saito, T. Y. and Fukuzumi, H. K., "TEMPO-oxidized Cellulose Nanofibers," Nanoscale, 3, 71-85(2011).   DOI   ScienceOn
16 Di, C. A., Wei, D. C., Yu, G., Liu, Y. Q., Guo, Y. L. and Zhu, D. B., "Patterned Graphene As Source/drain Electrodes for Bottomcontact Organic Field-effect Transistors," Adv. Mater, 20, 3289-3293(2008).   DOI   ScienceOn
17 Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Zhang, Y., Dubonos, S. V., Grigorieva, I. V. and Firsov, A. A., "Electric Field Effect in Atomically Thin Carbon Films," Science, 306, 666-669(2004).   DOI   ScienceOn
18 Astumian, R. D. and Schelly, Z. A., "Geometric Effects of Reduction of Dimensionality in Interfacial Reactions," J. Am. Chem. Soc., 106, 304-308(1984).   DOI   ScienceOn
19 Dwight, D. W. and Riggs, W. M., "luoropolyrner Surface Studies," J. Colloid Interf. Sci., 47, 650-660(1974).   DOI   ScienceOn
20 Hegemann, D., Brunner, H. and Oehr, C., "Plasma Treatment of Polymers for Surface and Adhesion Improvement," Nucl. Instrum. Methods B 208, 281-286(2003).   DOI   ScienceOn
21 Chen, J. R., Wang, X. Y. and Tomiji, W., "Wettability of Poly (ethylene terephthalate) Film Treated with Low-temperature Plasma and Their Surface Analysis by ESCA," J. Appl. Polym. Sci., 72, 1327-1333(1999).   DOI   ScienceOn
22 Süzer, S., Argun, A., Vatansever, O. and Aral, O., "XPS and Water Contact Angle Measurements on Aged and Corona-treated PP," J. Appl.Polym. Sci., 74, 1846-1850(1999).   DOI   ScienceOn
23 Inagaki, N., Narushim, K., Tuchida, N. and Miyazaki, K., "Surface Characterization of Plasma-modified Poly(ethylene terephthalate) Film Surfaces," J. Polym. Sci. Part B: Polym. Phys., 42, 3727-3740(2004).   DOI   ScienceOn
24 Okuji, S., Sekiya, M., Nakabayashi, M., Endo, H., Sakudo, N. and Nagai, K., "Surface Modification of Polymeric Substrates by Plasma-based Ion Implantation," Nucl. Instrum. Methods Phys. Res. B, 242, 353-356(2006).   DOI   ScienceOn
25 Novák, I., Pollák, V. and Chodák, I., "Study of Surface Properties of Polyolefins Modified by Corona Discharge Plasma," Plasma Process Polym., 3, 355-364(2006).   DOI   ScienceOn
26 Mathieson, I. and Bradley, R. H., "Improved Adhesion to Polymers by UV/ozone Surface Oxidation," Int. J. Adhes. Adhes., 16, 29-31(1996).   DOI   ScienceOn