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http://dx.doi.org/10.9713/kcer.2013.51.2.171

CO2 Adsorption in Metal-organic Frameworks  

Kim, Jun (Department of Chemical Engineering, Inha University)
Kim, Hee-Young (Department of Chemical Engineering, Inha University)
Ahn, Wha-Seung (Department of Chemical Engineering, Inha University)
Publication Information
Korean Chemical Engineering Research / v.51, no.2, 2013 , pp. 171-180 More about this Journal
Abstract
Metal organic frameworks (MOFs) are a class of crystalline organic-inorganic hybrid compounds formed by coordination of metal clusters or ions with organic linkers. MOFs have recently attracted intense research interest due to their permanent porous structures, large surface areas and pore volume, high-dispersed metal species, and potential applications in gas adsorption, separation, and catalysis. $CO_2$ adsorption in MOFs has been investigated in two areas of $CO_2$ storage at high pressures and $CO_2$ adsorption at atmospheric pressure conditions. In this short review, $CO_2$ adsorption/separation results using MOFs conducted in our laboratory was explained in terms of four contributing effects; (1) coordinatively unsaturated open metal sites, (2) functionalization, (3) interpenetration/catenation, and (4) ion-exchange. Zeolitic imidazolate frameworks (ZIFs) and covalent organic frameworks (COFs) were also considered as a candidate material.
Keywords
Metal-organic Frameworks (MOFs); $CO_2$ Adsorption; ZIFs; COFs;
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