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http://dx.doi.org/10.9713/kcer.2011.49.5.657

Synthesis of Aluminophosphate using Structure Directing Agent containing Piperidine Moiety: Effect of SDA on Crystal Structure  

Shin, Hye Sun (School of Applied Chemical Engineering and the Institute of Catalysis Research, Chonnam National University)
Jang, Ik Jun (School of Applied Chemical Engineering and the Institute of Catalysis Research, Chonnam National University)
Shin, Na Ra (School of Applied Chemical Engineering and the Institute of Catalysis Research, Chonnam National University)
Ju, Bit Na (School of Applied Chemical Engineering and the Institute of Catalysis Research, Chonnam National University)
Cho, Sung June (School of Applied Chemical Engineering and the Institute of Catalysis Research, Chonnam National University)
Publication Information
Korean Chemical Engineering Research / v.49, no.5, 2011 , pp. 657-663 More about this Journal
Abstract
Structure directing agent(SDA) containing piperidine moiety such as piperidine(PI), 2-methylpiperidine (MPI), 2,6-dimethylpiperidine(DMPI) and 2,2,6,6,-tetramethylpiperidine(TMPI), respectively has been utilized to synthesize aluminophosphate zeolite using hydrothermal method. The gel composition was $1.0Al_2O_3:1.0P_2O_5:0.76SDA:45H_2O$ and the hydrothermal heating was performed in an oven at 443 K and for 7 days at static mode. The obtained zeolitic material contained a lamellar structure when PI was used as the SDA. With a progressive increase of the SDA size, various structures of aluminophosphate including AlPO-5 of AFI structure were obtained. The aluminophosphate of SAS structure was formed when the largest TMPI was utilized as the SDA, which was confirmed by the Rietveld refinement. The result of $^{27}Al$ and $^{31}P$ MAS NMR of the sample suggested that Al and P were incorporated into the framework of the aluminophosphate.
Keywords
Aluminophosphate; Piperidine; Rietveld Refinement; Crystal Structure; AFI; SAS;
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