Browse > Article

Catalytic Performance of V-KIT-6 for the Oxidation of Styrene  

Kim, Sang-Yun (Division of Chemical Engineering/Research Institute of Industrial Technology(RIIT), Pusan National University)
Jermy, Balasamy R. (Division of Chemical Engineering/Research Institute of Industrial Technology(RIIT), Pusan National University)
Bineesh, Kanattukara V. (Division of Chemical Engineering/Research Institute of Industrial Technology(RIIT), Pusan National University)
Lim, Dong-Ok (Seki Arkema Co., Ltd.)
Kim, Kyung-Hoon (Division of Chemical Engineering/Research Institute of Industrial Technology(RIIT), Pusan National University)
Park, Dae-Won (Division of Chemical Engineering/Research Institute of Industrial Technology(RIIT), Pusan National University)
Publication Information
Korean Chemical Engineering Research / v.47, no.3, 2009 , pp. 275-280 More about this Journal
Abstract
The direct incorporation of vanadium into the three-dimensional(3-D) cubic Ia3d mesostructure designated as V-KIT-6 was carried out hydrothermally using a Pluronic P123 and n-butanol as the structure-directing mixture, tetraethylorthosilicate(TEOS) as the silica source and $NH_4VO_3$ as the vanadium source. The obtained V-KIT-6 showed a very high specific surface area ${\sim}1,000m^2/g$ with tunable pore diameters in narrow distribution of sizes ~6.0 nm. The coordination and nature of V sites in V-KIT-6 are characterized by $^{51}V$-spin-echo NMR analysis. The calcined V-KIT-6 materials showed excellent catalytic activity in the direct oxidation of styrene using tert-butyl hydroperoxide(TBHP) as an oxidant.
Keywords
KIT-6; Hydrothermal; Vanadium; Styrene Oxidation;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Luan, Z., Maes, E. M., Van der Heide, Paul A. W., Zhao, D., Roman, S. Czernuszewicz, and Kevan, L., "Incorporation of Titanium into Mesoporous Silica Molecular Sieve SBA-15," Chem. Mater., 11(12), 3680-3686(1999)   DOI   ScienceOn
2 Fan, J., Yu, C., Wang, L., Tu, B., Zhao, D., Sakamoto, Y. and Terasaki, O., "Mesotunnels on the Silica Wall of Ordered SBA- 15 to Generate Three-Dimensional Large-Pore Mesoporous Networks," J. Am. Chem. Soc., 123(48), 12113-12114(2001)   DOI   ScienceOn
3 Sakamoto, Y., Kaneda, M., Terasaki, O., Zhao, D.Y., Kim, J. M., Stucky, G. D., Shin, H. Y. and Ryoo, R., "Direct Imaging of the Pores and Cages of Three-dimensional Mesoporous Materials," Nature, 408, 449-453(2000)   DOI   ScienceOn
4 Dapurkar, S. E., Sakthivel, A. and Selvam, P., "Mesoporous VMCM-41: Highly Efficient and Remarkable Catalyst for Selective Oxidation of Cyclohexane to Cyclohexanol," J. Mol. Catal. A. Chem., 223(1-2), 241-250(2004)   DOI   ScienceOn
5 Selvam, P. and Dapurkar, S. E., "Catalytic Activity of Highly Ordered Mesoporous V-MCM-48," Appl. Catal. A. Gen., 276(1-2), 257-265(2004)   DOI   ScienceOn
6 Jermy, B. R., Cho, D. R., Bineesh, K. V., Kim, S. Y. and Park, D. W., "Direct Synthesis of Vanadium Incorporated Three-dimensional KIT-6: A Systematic Study in the Oxidation of Cyclohexane," Micro. Meso. Mater., 115(3), 281-292(2008)   DOI   ScienceOn
7 Mathieu, M., Van Der Voort, P., Weckhuysen, B. M., Rao, R. R., Catana, G., Schoonheydt, R. A. and Vansant, E. F., "Vanadium- Incorporated MCM-48 Materials: Optimization of the Synthesis Procedure and an in-situ Spectroscopic Study of the Vanadium Species," J. Phys. Chem. B., 105(17) 3393-3399(2001)   DOI   ScienceOn
8 Luan, Z., Bae, J. Y. and Kevan, L., "Vanadosilicate Mesoporous SBA-15 Molecular Sieves Incorporated with N-Alkylphenothiazines," Chem. Mater., 12, 3202-3207(2000)   DOI   ScienceOn
9 Murugavel, R. and Roesky, H. W., "Titanosilicates: Recent Developments in Synthesis and Use as Oxidation Catalysts," Angew. Chem., Int. ed., 36(5), 477-479(1997)   DOI   ScienceOn
10 Zhang, W., Wang, J., Tanev, P. T. and Pinnavaia, T., 'Catalytic Hydroxylation of Benzene Over Transition-metal Substituted Hexagonal Mesoporous Silicas,' J. Chem. Soc., Chem. Commun., 8, 979-980(1996)   DOI   ScienceOn
11 Chen, Y.-W. and Lu, Y.-H., "Characteristics of V-MCM-41 and Its Catalytic Properties in Oxidation of Benzene, " Ind. Eng. Chem. Res., 38(5), 1893-1903(1999)   DOI   ScienceOn
12 Gao, F., Zhang, Y., Wan, H., Kong, Y., Wu, X., Dong, L., Li, B. and Chen, Y., "The States of Vanadium Species in V-SBA-15 Synthesized Under Different pH Values," Micro. Meso. Mater., 110(2-3), 508-516(2007)   DOI   ScienceOn
13 Tuel, A. and Ben Taarit, Y., "Synthesis, Characterization and Catalytic Properties of Vanadium Silicates with a ZSM-48 Structure," Appl. Catal. A. Gen., 102, 201(1993)   DOI   ScienceOn
14 Gontier, S. and Tuel, A., "Characterization of Vanadium-containing Mesoporous Silicas," Microporous Mater., 5, 161-171(1995)   DOI   ScienceOn
15 Reddy, K. M., Moudrakaski, I. and Sayari, A. J., 'Synthesis of Mesoporous Vanadium Silicate Molecular Sieves,' J. Chem. Soc., Chem. Commun., 9, 1059-1060(1994)   DOI   ScienceOn
16 Centi, G., Perathoner, S., Trifiro, F., Aboukais, A., Aissi, C. F. and Guelton, M., "Physicochemical Characterization of V-Silicalite," J. Phys. Chem., 96(6), 2617-29(1992)   DOI
17 Jermy, B. R., Kim, S. Y., Bineesh, K. V., Selvaraj, M. and Park, D. W., 'Direct Incorporation of High Vanadium Content into Three Dimensional KIT-6 : 1. Optimization of Synthesis Conditions,' Korean J. Chem. Eng., submitted(2008)   DOI
18 Lim, S. and Haller, G. L., "Preparation of Highly Ordered Vanadium- substituted MCM-41. Stability and Acidic Properties," J. Phys. Chem. B., 106(33), 8437-8447(2002)   DOI   ScienceOn
19 Morey, M. S., Davidson, A. and Stukcy, G. D., "Silica-based, Cubic Mesostructures: Synthesis, Characterization and Relevance for Catalysis," J. Porous Mater., 5, 195-204(1998)   DOI   ScienceOn
20 Eckert, H. and Wachs, I. E., "Solid-State Vanadium-51 NMR Structural Studies on Supported Vanadium(V) Oxide Catalysts: Vanadium Oxide Surface Layers on Alumina and Titania Supports," J. Phys. Chem., 93(18), 6796-6805(1989)   DOI   ScienceOn
21 Du, G., Lim, S., Yang, Y., Wang, C., Pfefferle, L. and Haller, G. L., "Catalytic Performance of Vanadium Incorporated MCM-41 Catalysts for the Partial Oxidation of Methane to Formaldehyde," Appl. Catal. A. Gen., 302(1), 48-61(2006)   DOI   ScienceOn
22 Kim, T.W., Kleitz, F., Paul, B. and Ryoo, R., "MCM-48-like Large Mesoporous Silicas with Tailored Pore Structure: Facile Synthesis Domain in a Ternary Triblock Copolymer Butanol Water System," J. Am. Chem. Soc., 127, 7601-7610(2005)   DOI   ScienceOn