Browse > Article

Effects of the Surfactant and the Quaternary Ammonium Functional Groups on the Removal of Perrhenate Anions using Mesoporous Anion-Exchange Resins in Aqueous Solutions  

Lee, Byunghwan (Department of Chemical System Engineering, Keimyung University)
Chung, Yeon-Sung (Department of Chemical System Engineering, Keimyung University)
Park, Chulhwan (Department of Chemical Engineering, Kwangwoon University)
Publication Information
Korean Chemical Engineering Research / v.46, no.2, 2008 , pp. 436-442 More about this Journal
Abstract
Organic-inorganic hybrid mesoporous anion-exchange resins were prepared for the adsorption of anions from aqueous solutions. The prepared samples were characterized using nitrogen adsorption-desorption measurements, Fourier transform infrared (FTIR) spectroscopy, and elemental analyses. Batch and kinetic experiments were performed to examine the anion-exchange performances of the prepared samples. Among the prepared samples, the hybrid mesoporous anion-exchange resins functionalized with tributylammonium groups showed higher adsorption capacities for perrhenate ions than did the resin functionalized with trimethylammonium groups. The surfactant, hexadecylamine, which had hydrophobic alkyl chains, also showed affinity for hydrophobic perrhenate anions.
Keywords
Surfactant; Quaternary Ammonium Groups; Perrhenate; Mesoporous Anion-Exchange Resin; Organic-Inorganic Hybrid Material;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 Bull, R. J., Chang, A. C., Cranor, C. F., Shank, R. C. and Trussell, R., Perchlorate in Drinking Water: A Science and Policy Review, Urban Water Research Center, University of California, Irvine, CA(2004)
2 Ju, Y. H., Webb, O. F., Dai, S., Lin, J. S. and Barnes, C. E., "Synthesis and Characterization of Ordered Mesoporous Anion- Exchange Inorganic/Organic Hybrid Resins for Radionuclide Separation," Ind. Eng. Chem. Res., 39(2), 550-553(2000)   DOI   ScienceOn
3 Kresge, C. T., Leonowicz, M. E., Roth, W. J., Vartuli, J. C. and Beck, J. S., "Ordered Mesoporous Molecular Sieves Synthesized by a Liquid-crystal Template Mechanism," Nature, 359(6397), 710-712(1992)   DOI
4 Lee, B., Kim, Y., Lee, H. and Yi, J., "Synthesis of Functionalized Porous Silicas Via Templating Method as Heavy Metal Ion Adsorbents: the Introduction of Surface Hydrophilicity onto the Surface of Adsorbents," Micropor. Mesopor. Mater., 50(1), 77-90 (2001)   DOI   ScienceOn
5 Kim, Y., Lee, B., Cho, Y. S. and Yi, J., "Effects of the Pore Properties of Mesoporous Silica on the Metal Adsorption Capacities," Korean Chem. Eng. Res., 39(2), 228-236(2001)
6 Choi, H. S., Lee, D. G., Cho, G. J., Lee, C. Y., Chung, J. S., Yoo, I.-K. and Shin, E. W., "Removal of Pb2+ Ions from Water by Surfactant-templated Mesoporous Silicates," Korean Chem. Eng. Res., 44(2), 172-178(2006)
7 Reddad, Z., Gerente, C., Andres, Y. and Cloirec, P. L., "Adsorption of Several Metal Ions onto a Low-Cost Biosorbent: Kinetic and Equilibrium Studies," Environ. Sci. Technol., 36(9), 2067-2073(2002)   DOI   ScienceOn
8 Logan, B. E., "Assessing the Outlook for Perchlorate Remediation," Environ. Sci. Technol., 35(23), 482A-487A(2001)   DOI   ScienceOn
9 Lin, Y., Fryxell, G., Wu, H. and Engelhard, M., "Selective Sorption of Cesium Using Self-Assembled Monolayers on Mesoporous Supports," Environ. Sci. Technol., 35(19), 3962-3966(2001)   DOI   ScienceOn
10 Zhao, H., Nagy, K. L., Waples, J. S. and Vance, G. F., "Surfactant- Templated Mesoporous Silicate Materials as Sorbents for Organic Pollutants in Water," Environ. Sci. Technol., 34(22), 4822-4827(2000)   DOI   ScienceOn
11 Seidel, H., Gorsch, K., Amstatter, K. and Mattusch, J., "Immobilization of Arsenic in a Tailings Material by Ferrous Iron Treatment," Water Res., 39(17), 4073-4082(2005)   DOI   ScienceOn
12 Tanev, P. T. and Pinnavaia, T. J., "A Neutral Templating Route to Mesoporous Molecular Sieves," Science, 267(5199), 865-867 (1995)   DOI   ScienceOn
13 Husing, N., Schubert, U., Mezei, R., Fratzl, P., Riegel, B., Kiefer, W., Kohler, D. and Mader, W., "Formation and Structure of Gel Networks from $Si(OEt)_4/(MeO)_{3}Si(CH_2)_{3}NRMixtures ($NR)," Chem. Mater., 11(2), 451-457(1999)   DOI   ScienceOn
14 Kavallieratos, K. and Moyer, B. A., "Attenuation of Hofmeister Bias in Ion-Pair Extraction by a Disulfonamide Anion Host Used in Strikingly Effective Synergistic Combination with a Calixcrown $Cs^+$ Host," Chem. Commun., (17), 1620-1621(2001)
15 Yoshitake, H., Yokoi, T. and Tatsumi, T., "Adsorption of Chromate and Arsenate by Amino-Functionalized MCM-41 and SBA-1," Chem. Mater., 14(11), 4603-4610(2002)   DOI   ScienceOn
16 Lee, B., Bao, L.-L., Im, H.-J., Dai, S., Hagaman, E. W. and Lin, J. S., "Synthesis and Characterization of Organic-Inorganic Hybrid Mesoporous Anion-Exchange Resins for Perrhenate ($ReO^-_{4}$)Anion Adsorption," Langmuir, 19(10), 4246-4252(2003)   DOI   ScienceOn
17 Kim, Y., Kim, C., Choi, I., Rengaraj, S. and Yi, J., "Arsenic Removal Using Mesoporous Alumina Prepared via a Templating Method," Environ. Sci. Technol., 38(3), 924-931(2004)   DOI   ScienceOn