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Synthesis, Characterization, and Catalytic Applications of Fe-MCM-41  

Yoon, Sang Soon (School of Chemical Engineering, Inha University)
Choi, Jung Sik (School of Chemical Engineering, Inha University)
Choi, Hyeong Jin (School of Polymer Engineering, Inha University)
Ahn, Wha Seung (School of Chemical Engineering, Inha University)
Publication Information
Korean Chemical Engineering Research / v.43, no.2, 2005 , pp. 215-221 More about this Journal
Abstract
A Fe-containing mesoporous silica (Fe-MCM-41) in which part of Si in the framework was replaced by Fe(Si-O-Fe) has been successfully prepared using $Fe^{3+}$ salt by a direct synthesis route. Physical properties of the material were characterized by XRD, $N_2$ adsorption, SEM/TEM, UV-vis and FT-IR spectroscopies. Fe-MCM-41 exhibited high catalytic activity in phenol hydroxylation using $H_2O_2$ as oxidant, giving phenol conversion of ca. 60% at $50^{\circ}C$ [phenol : $H_2O_2$ = 1:1, water solvent]. Fe-MCM-41 was also applied to the growth of CNTs, utilizing a thermal-CVD reactor using acetylene gas, which demonstrated that multi-wall CNTs could be prepared efficiently using the Fe-MCM-41 catalyst.
Keywords
Mesoporous Silica; Fe-MCM-41; Phenol Hydroxylation; CVD; Carbon Nanotube;
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Times Cited By KSCI : 1  (Citation Analysis)
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