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http://dx.doi.org/10.12925/jkocs.2017.34.4.1076

Study on the Applicability Analysis of HPLC for Fuel Marker (Unimark 1494DB) in Petroleum Products  

Hwang, In-ha (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority)
Youn, Ju-min (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority)
Doe, Jin-woo (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority)
Park, Tae-seong (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority)
Kang, Hyung-kyu (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority)
Ha, Jong-han (Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority)
Na, Byung-gi (Department of Chemical Engineering, Chungbuk National University)
Publication Information
Journal of the Korean Applied Science and Technology / v.34, no.4, 2017 , pp. 1076-1084 More about this Journal
Abstract
For analyzing the qualitative and quantitative analysis of fuel marker in petroleum products, the applicability of HPLC was studied. For the qualitative analysis of fuel marker in kerosene and automotive diesel, optimal analytical conditions(ratio of mobile phase solvent, flow rate, etc) in HPLC were selected and calibration curve for quantitative analysis of fuel marker was prepared based on the result of qualitative analysis. In particular, the correlation coefficient of calibration curve in kerosene and automotive diesel was shown to be 0.999 in a certain concentration range and it could be applied to the quantitative analysis. The results of analysis using the UV/Vis spectrometer, which is the current analysis method of fuel marker, were compared with the analysis results using the HPLC. The kerosene showed a low deviation of about 7 % and the automotive diesel showed a somewhat large deviation of about 20 %.
Keywords
HPLC; UV/Vis spectrometer; Unimark 1494DB; Unimark 1494DB developer C-5; Kerosene; Automotive diesel;
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Times Cited By KSCI : 2  (Citation Analysis)
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1 Y. K. Lim, D. K. Kim, E. S. Yim and S. C. Shin, "Determination of Unimark 1494DB in Petroleum using HPLC", Korean Chem. Eng. Res, Vol.47, No.5, pp. 593-598, (2009)
2 R. B. Orelup, "Colored Petroleum Marker", United state patent, patent number 4,735,631.
3 Z. Fingas, M. Wang and D. S. Page, "Oil Spill Identification", J. Chromatogr. A, Vol.843, pp. 369-411, (1999)   DOI
4 M. G. Strachan, R. Alexander and R. I. Kagi, "A Comparison of Selected biological Marker Compounds in Some Natural and Synthetic Liquid Fuels", Fuel, Vol.68, No.5, pp 641-647, (1989)   DOI
5 M. Soler, J. O. Grimalt, J. Albaiges, J. Mendez and M. Marino, "Distribution of Aliphatic, Aromatic and Chlorinated Hydrocarbons in Mussels from the Spanish Atlantic Coast(Galicia). An Assessment of Pollution Oarameters", Chemosphere, Vol.19, No.10, pp 1489-1498, (1989)   DOI
6 M. R. Friswell, Sr. A. Zimin and P. A. Caputo, "Silent Fluorescent Petroleum Marker", United State Patent, Patent number 5,980,593.
7 M. R. Friswell, M. J. Hallisy and M. P. Hinton, "Acid Extractable Petroleum Fuel Marker", United State Patent, Patent number 5,490,872.
8 R. Timkovich, "Analysis Regulatory Dye in Diesel Petroleum", Dye and Pigments, Vol.46, pp. 69-79, (2000)   DOI
9 A. Sr. Zimin, "Stabilized Aqueous Diazo Solution", United State Patent, Patent number 6,080,213.
10 J. Y. Lee, and C. J. Kim, "Absorbance Elevation of Orimax Blue 2N, Orimax Green 151, Quinizarin, Topasol(P-250) and Lubricant(P-8) on the Spectrophotometric Analysis of Unimark 1494DB", Yakhak Hoeji, Vol.50, No.5, pp. 313-321, (2006)
11 Petroleum and Alternative Fuel Business Act, Ministry of Trade, Industry and energy. 14774, (2017).
12 KPETRO internal test method(KPETROSTM-9), Korea Petroleum Quality & Distribution Authority, (2009).
13 C. Y. In, T. J. Kim, S. W. Myung, "Analysis of Caffeine in Aqueous Sample by Hollow Fiber-liquid Microextraction (HFLPME)", Anal. Sci & Tech., Vol.21, No.2, pp. 84-91, (2008).
14 R. E., Majors, "An Overview of Sample Preparation," LC-GC Int. Vol.9, No.1, pp. 16-20, (1991).
15 J. C. Cheong, J. Y. Kim, M. K. In, W. J. Cheong, "Simultaneous Determination of Amphetamine-like Drugs in Human Urine by SPE and GC/MS," Anal. Sci. & Tech., Vol.21, No.1, pp. 41-47, (2008).
16 D. Wang, S. P. Hong, K. H. Row, "Solid Extraction of Caffeine and Theophylline from Green Tea by Molecular Imprinted Polymers," Korean J. Chem. Eng., Vol.21, No.4, pp. 853-857, (2004).   DOI