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http://dx.doi.org/10.12925/jkocs.2014.31.1.7

Synthesis and Properties of Glycolic Acid Ester Type Cationic Surfactant  

Park, Jong-Kwun (Department of Engineering Chemistry, College of Engineering, Chungbuk National University)
Jeong, Noh-Hee (Department of Engineering Chemistry, College of Engineering, Chungbuk National University)
Publication Information
Journal of the Korean Applied Science and Technology / v.31, no.1, 2014 , pp. 7-13 More about this Journal
Abstract
A cationic ester type surfactant, namely N-2-hydroxy-3-(2-hydroxyacetoxy) proply-N,N-dimethyldodecylaminium chloride(HPDA) was synthesized and confirmed by FT-IR and $^1H$-NMR spectroscopy. Surface tensions on the diluted aqueous solutions of the synthetic compounds were measured and evaluated critical micelle concentration. Surface tension was 33~34 dyne/cm in the range of $10^{-3}{\sim}10^{-2}mol/L$ and critical micelle concentration(c.m.c) value was $8.5{\times}10^{-3}mol/L$ by surface tension method. Emulsifying properties of the synthetic surfactant(HPDA) and Sodium lauryl sulfate (SLS), tetradecyl trimethyl ammonium bromide (TTAB) was tested. As a results, synthetic glycolic acid ester type compounds(HPDA) has been confirmed as a good emulsifier. The foaming power and stability of synthesized ester type surfactant was measured by Ross-Miles method.
Keywords
cationic surfactant; surface tension; cmc; emulsifier;
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