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http://dx.doi.org/10.12925/jkocs.2012.29.1.6

Synthesis and Emulsifying Properties for Dipropylene Glycol Succinate  

Jeong, Noh-Hee (Department of Engineering Chemistry, College of Engineering Chungbuk National University)
Kang, Mi-Na (Department of Engineering Chemistry, College of Engineering Chungbuk National University)
Choi, Sung-Ok (Dong Yang Oil & Fat Co., LTD.)
Publication Information
Journal of the Korean Applied Science and Technology / v.29, no.1, 2012 , pp. 47-53 More about this Journal
Abstract
This study is concerned with coemulsifier which is better emulsifiable properties than emulsifier itselves' use only. It's compound was synthesized by esterification of propylene glycol and succinic acid. The structure of them was comfirmed with FT-IR and $^1H$-NMR. Surface active properties with surface tension, cmc, emulsing power were tested respectively at given conditions. Their surface tensions in the aqueous solution was decreased to 33-35 dyne/cm and their cmc was evaluated by surface tension method. And it's emulsifying power was excellent in jojoba oil. As results, the synthesized dipropylene glycol succinate is expected to apply as O/W coemulsifier.
Keywords
surfactant; dicarboxylate; surface tension; coemulsifier;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
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1 H. H. Kang, "Recent studies and applications of surfactants in Cosmetics", Prospectives of Industrial Chemistry, 4(2), 17 (2001).
2 Th.F. Tadros, "Applied Surfactants, Principles and Application", p.309, Wiley-VCH, Weinheim, (2005).
3 D.T, Lee, H, Kim, H. S. Cho, "Gemini surfactants", Journal of the Korean Oil Chemists' Society, 11, 1 (1994).
4 F. M. Menger, J. S. Keiper, "Gemini surfactants", Angewandte Chemie International Edition, (2000).
5 E. J. Choi, Y. S. Jeon, J. D. Lee, N. H. Jeong, "Synthesis and Properties of Gemini Type's Diethylene Glycol Dicarboxylates", Journal of the Korean Oil Chemists' Society, 27(3), 257 (2010).
6 N. H. Jeong, "Synthesis and Properties of Diethoxy Ethylene Glycol Adipate", Journal of Industrial Science and Technology Institute, 25(1), 69 (2011).
7 S. Karaborni, K. Esselink, P.A. J. Hilbers, B. Smit, J.l Karthauser, N. M. van Os, and R. Zana, "Simulating the Self- Assembly of Gemini (Dimeric) Surfactants", Science., 226, 254 (1994).
8 M. J. Rosen and L.D. Song, "Dynamic Surface Tension of Aqueous Surfactant Solutions 8. Effect of Spacer on Dynamic Properties of Gemini Surfactant Solutions", Journal of Colloid and Interface Science, 179, 261 (1996).
9 T. J. Micich and W. M. Linfield, Journal of the American Oil Chemists' Society, 65, 820 (1988).
10 M. Okahara, A. Masuyama, Y. Sumida, and Y. P. Zhu, "Surface active properties of amphiphilic compounds with two hydrophiphilic ionic groups and two lipophilic alkyl chains", Journal of the Japan Oil Chemists' Society, 37(9), 746 (1988).
11 Lifei Chen, Yazhuo Shang, Honglai Liu, Ying Hu, "Middle-phase microemulsion induced by brine in region of low cationic gemini surfactant content", Colloids and Surfaces A : Physicochemical and Engineering Aspects, 305, 29 (2007).
12 T. Zhou, H. Yang, X. Xu, X. Wang, J. Wang, G. Dong, "Synthesis, surface and aggregation properties of nonionic poly (ethylene oxide) gemini surfactants", Colloids and Surfaces A : Physicochemical and Engineering Aspects, 317, 339 (2008).
13 1H-NMR study of micelles formed by mixture of nonionic n-dodecyl-${\beta}$ -D-maltoside and cationic gemini surfactants", Journal of Molecular Liquids, 146, 105 (2009).
14 U. Komorek and K. A. Wilk, "Surface and micellar properties of new nonionic gemini aldonamide-type surfactants", Journal of Colloid and Interface Science, 271, 206 (2004).