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http://dx.doi.org/10.12925/jkocs.2011.28.3.11

Synthesis and Characteristic of Ferric Ferrocyanide Coated Titania/Mica Pearlescent Pigments by Hydrothermal Synthesis Method  

Lee, Kwan-Sik (Department of Engineering Chemistry, Chungbuk National University)
Lee, Dong-Kyu (Department of Engineering Chemistry, Chungbuk National University)
Publication Information
Journal of the Korean Applied Science and Technology / v.28, no.3, 2011 , pp. 335-344 More about this Journal
Abstract
The pearlesent pigment has received attention in a diversity of fields like cosmetics, inks, paints and so on. Ferric Ferrocyanide, one of the nano sized pearlescent pigment, is a kind of surface modification pigment that covers a metal oxidized substance or a coloring agent with uniform thickness. Characteristics of pearlescent pigment are various interference color, intense gloss effect and a three-dimensional effect. We synthesised the pearlesent pigment that ferric ferrocyanide can be deposited on the titania/mica surface by hydrothermal synthesis method. The process parameters are concentration of precursor, controlling pH and reaction temperature. The optimun conditions is that amount of iron(III) chloride hexahydrate is 3.1 wt% and amount of potassim ferrocynide trihydrate is 3.6 wt% in the started pH 4.5 at $70^{\circ}C$. The coating rate and coating efficiency of ferric ferrocyanide was about 1.47 % and 96.7 %, respectively. The synthesised pearlesent pigment was characterized by SEM, XRD, FT-IR and EDS.
Keywords
ferric ferrocyanide; pearlescent pigment; hydrothermal; blue color;
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Times Cited By KSCI : 2  (Citation Analysis)
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