Browse > Article
http://dx.doi.org/10.12925/jkocs.2010.27.1.2

A Study on the Catalytic Activity of Nontoxic Organometallic Compound in Esterification Reaction between Succinic Acid and 1,4-Butanediol  

Park, Keun-Ho (Dept. of Chemical Engineering, Changwon National University)
Publication Information
Journal of the Korean Applied Science and Technology / v.27, no.1, 2010 , pp. 6-13 More about this Journal
Abstract
Esterification reaction between succinic acid and 1,4-butanediol was kinetically investigated in the presence of nontoxic organometallic compound catalyst(ESCAT-100E) at $150-190^{\circ}C$. The reaction rates measured by the amount of distilled water from the reaction vessel. The Esterification reaction was carried out under the first order conditions respect to the concentration of reactants, respectively. The overall reaction order was 2nd. The linear relationship was shown between apparent reaction rate constant and reciprocal absolute temperature. By the Arrhenius plot the activation energy have been calculated as 376.13 kJ/mol under nontoxic organometallic compound catalyst and also apparent reaction rate constant, k' was found to obey first kinetics with respect to the concentration of catalyst.
Keywords
Esterification reaction; succinic acid; l,4-butanediol; nontoxic organometallic compound catalyst (ESCAT-100E); catalytic activity;
Citations & Related Records
Times Cited By KSCI : 2  (Citation Analysis)
연도 인용수 순위
1 H. R. Kricheldorf, Syntheses of Biodegradable and Biocompatible Polymers by Means of Bismuth Catalysts, Chem. Rev., 109, 5579 (2009).   DOI   ScienceOn
2 J. H. Clark, V. Budarin, T. Dugmore, R. Luque, D.J. Macquarrie, and V. Strelko, Catalytic performance of carbonaceous materials in the esterification of succinic acid, Catalysis Communications, 9(8), 1709 (2008).   DOI   ScienceOn
3 K. H. Park, A Study on the Esterification Reaction of Succinic Acid and 1,4-butanediol Using an Organic Metal Catalysts, J. Kor. Oil Chem. Soc., 26(4), (2009).   과학기술학회마을
4 Y. X. Xu, J. Xu, D. Liu, B. Guo, and X. Xie, Synthesis and Characterization of Biodegradable Poly(butylene Succinate-co-Propylene Succinate)s, J. Appl. Polym. Sci., 109(3), 1881 (2008).   DOI   ScienceOn
5 M. Ishii, M. Okazaki, Y. Shibasaki, and M. Ueda, Convenient Synthesis of Aliphatic Polyesters by Distannoxane-Catalyzed Polycondensation, Biomacromolecules, 2, 1267 (2001).   DOI   ScienceOn
6 A. Mahapatro, B. Kalra, A. Kumar, and R. A. Gross, Lipase-Catalyzed Polycondensations: Effect of Substrates and Solvent on Chain Formation, Dispersity, and End-Group Structure, Biomacromolecules, 4, 544 (2003).   DOI   ScienceOn
7 R. Bacaloglu, M. Fisch, K. Biesiada, Kinetics of polyesterification of adipic acid with 1,3-butanediol, Polym. Eng. Sci., 38(6), 1014 (1998).   DOI   ScienceOn
8 R. Nava, T. Halachev, and R. Rodriguez, Immobilized zinc acetate complex on the surface of silica-alumina gel modified by succinic acid: an efficient catalyst for the esterification of DMT, Micropo. Mesopo. Mater. : Offici. J Inter. Zeolite Asso.. 7(2), 91 (2005).
9 A. K. Kolah, N. S. Asthana, D. T. Vu, C. T. Lira, and D. J. Miller, Reaction Kinetics for the Heterogeneously Catalyzed Esterification of Succinic Acid with Ethanol, Ind Eng. Chem. Res., 47, 5313 (2008).   DOI   ScienceOn
10 S. S. Park, H. W. Jun, and S, S, Im, Kinetics of Forming Poly(Butylene Succinate) (PBS) Oligomer in the Presence of METO Catalyst, Polymer Eng. and Sci., 38(6), 905 (1998).   DOI   ScienceOn
11 K. H. Park and D. S. Kim, Effect of Monobutyl Tinoxide Catalyst in Esterification Reaction between Succinic Acid and 1,4-butanediol, J. Kor. Oil Chem. Soc., 26(3), 362 (2009).   과학기술학회마을
12 K. H. Park and B. C. Shon, The Effect of Nitrate Catalyst in Transesterification Reaction between Dimethylphthalate and Ethylene Glycol, J. Kor. Oil Chem. Soc., 10(1), 23 (1993).
13 M. Hunsen, A. Azim, H. Mang, S. R. Wallner, A. Ronkvist, W. Xie, and and R. A. Gross, A Cutinase with Polyester Synthesis Activity, Macromolecules, 40, 148 (2007).   DOI   ScienceOn
14 B. A. J. Noordover, R. Duchateau, R. A. T. M. van Benthem, W. Ming, and C. E. Koning, Enhancing the Functionality of Biobased Polyester Coating Resins through Modification with Citric Acid, Biomacromolecules, 8, 3860 (2007).   DOI   ScienceOn
15 K. H. Park, The Effect of Anion Catalyst in Transesterification Reaction", J. Kor. Oil Chem Soc., 9(2), 141 (1992).