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http://dx.doi.org/10.12925/jkocs.2006.23.4.2

A Statistical-Mechanical Study on Multilayer Adsorptions and the BET Adsorption Equation  

Lim, Kyung-Hee (Department of Chemical Engineering, Chung-Ang University)
Publication Information
Journal of the Korean Applied Science and Technology / v.23, no.4, 2006 , pp. 280-289 More about this Journal
Abstract
Multilayer adsorptions and BET adsorption are analyzed statistical-mechanically. Which ensemble is selected for the analysis is unimportant, because each ensemble yields the same results. However, the amount of mathematical manipulations and the matter of convenience vary from ensemble to ensemble. Hence, multilayer adsorptions and BET adsorption are examined using a canonical and a grand canonical ensembles, and an ensemble of subsystems. Also, the characteristics of multilayer and BET adsorptions are delineated.
Keywords
adsorption; BET adsorption equation; statistical mechanics; multilayer adsorption; ensemble;
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