Browse > Article
http://dx.doi.org/10.5338/KJEA.2015.34.2.15

Establishment of Pre-Harvest Residue Limit(PHRL) of the Fungicide Amisulbrom during Cultivation of Winter-Grown Cabbage  

Ahn, Kyung-Geun (Department of Herbal Medicine Resource, Kangwon National University)
Kim, Gyeong-Ha (Department of Herbal Medicine Resource, Kangwon National University)
Kim, Gi-Ppeum (Department of Herbal Medicine Resource, Kangwon National University)
Kim, Min-Ji (Department of Herbal Medicine Resource, Kangwon National University)
Hong, Seung-Beom (Department of Herbal Medicine Resource, Kangwon National University)
Hwang, Young-Sun (Department of Herbal Medicine Resource, Kangwon National University)
Kwon, Chan-Hyeok (Food Standard Division, Ministry of Food and Drug Safety)
Son, Young Wook (Food Standard Division, Ministry of Food and Drug Safety)
Lee, Young Deuk (Division of Life and Environmental Science, Daegu University)
Choung, Myoung-Gun (Department of Herbal Medicine Resource, Kangwon National University)
Publication Information
Korean Journal of Environmental Agriculture / v.34, no.2, 2015 , pp. 120-127 More about this Journal
Abstract
BACKGROUND: Supervised residue trials were conducted to establish pre-harvest residue limit(PHRL), a criterion to ensure the safety of the pesticide residue in the crop harvest, of amisulbrom for winter-grown cabbage in two fields. Following to application of amisulbrom on the crop, time-course study was carried out to obtain the amisulbrom dissipation of statistical significance which enabled to calculate the predicted values of PHRL. METHOD AND RESULTS: During cultivation under greenhouse condition, samples of winter-grown cabbage were collected at 0, 1, 3, 5, 7 and 10 days after amisulbrom application, and subjected to residue analysis. Analytical method was validated by recoveries ranging 93.7~100.0% as well as limit of quantitation(LOQ) of 0.04 mg/kg. Amisulbrom residues in winter-grown cabbage gradually decreased as time elapsed. The dissipation rate of the residue would be affected by intrinsic degradation along with dilution by the cabbage growth. The decay pattern was well fitted by the simple first-order kinetics. CONCLUSION: Biological half-lives of amisulbrom in winter-grown cabbage ranged 3.7~4.1 days in two field conditions. Based on the regression of amisulbrom dissipation, PHRLs of amisulbrom in winter-grown cabbage were recommended as 8.86~9.47 and 4.21~4.35 mg/kg for 10 and 5 days before harvest, respectively.
Keywords
Amisulbrom; Biological half-life; Pre-harvest residue limit(PHRL); Winter-grown cabbage;
Citations & Related Records
Times Cited By KSCI : 6  (Citation Analysis)
연도 인용수 순위
1 Bentson, K. P. (1990). Fate of xenobiotics in foliar pesticide deposits. In Reviews of Environmental Contamination and Toxicology, pp. 125-161. Springer New York.
2 Chae, Y. A., Lee, Y. M., & Ku, J. O. (1981). Biological Statistics, pp. 82-112, Jeongminsa, Seoul, Korea.
3 Choi, K. I., Seong, K. Y., Jeong, T. K., Lee J. W., Hur, J. H., Ko, K. Y., & Lee, K. S. (2002). Dissipation and removal rate of dichlofluanid and iprodione residue on greenhouse cherry tomato, Korean Journal of Environmental Agriculture, 21(4), 231-236.   DOI
4 Gomez, K. A., & Gomex A. A. (1984), Statistical Procedures for Agricultural Research, 2nd ed., pp. 357-236, John Wiley, New York, USA.
5 Hill, B. D., & Inaba, D. J. (1990). Fate and persistence of residues on wheat used to explain efficacy differences between deltamethrin suspension concentrate and emulsifiable concentrate formulations. Pesticide Science, 29(1), 57-66.   DOI   ScienceOn
6 Jeong, Y. H., Kim, J. U., Kim, J. H., Lee, Y. D., Lim, C. H., Hu, & J. H. (2004). Modern pesticide, pp. 5, 339-342, Sigma-press, Korea.
7 Kim, S. W., Lee, E. M., Yang L., Park, H. W., Lee, H. R., Riu, M. J., Na, Y. R., Noh, J. E., Keum, Y. S., Song, H. H., & Kim, J. H. (2009). Establishment of pre-harvest residue limit (PHRL) of insecticide Bifenthrin during cultivation of grape. The Korean Journal of Pesticide Science, 13(4), 241-248.
8 Kim, Y. S., Park, J. H., Park, J. W., Lee, Y. D., Lee, K. S., & Kim, J. E. (2002). Persistence and dislodgeable residues of chlorpyrifos and procymidone in lettuce leaves under greenhouse condition, Korean Journal of Environmental Agriculture. 21(2), 149-155.   DOI
9 Ko, K. Y., Lee, Y. J., Won, D. J., Park, H. J., & Lee, K. S. (2003). Residual pattern of procymidone and bifenthrin in perilla leaf during the period of cultivation and storage, Korean Journal of Environmental Agriculture, 22(1), 47-52.   DOI
10 Lee, J. H., Park, H. W., Keum, Y. S., Kwon, C. H., Lee, Y. D., & Kim, J. H. (2008). Dissipation pattern of boscalid in cucumber under greenhouse condition. The Korean Journal of Pesticide Science, 12(1), 67-73.
11 Lee, S. J., Kim, Y. H., Song, L. S., Hwang, Y. S., Lim, J. D., Sohn, E. H., Im, M. H., Do, J. A., Oh, J. H., Kwon, K. S., Lee, J. K., Lee, Y. D., & Choung, M. G. (2011). Development of analytical method for Fenoxycarb, Pyriproxyfen and Methoprene residues in agricultural commodities using HPLC-UVD/MS. The Korean Journal of Pesticide Science, 15(3), 254-268.
12 Marín, A., Oliva, J., Garcia, C., Navarro, S., & Barba, A. (2003). Dissipation rates of cyprodinil and fludioxonil in lettuce and table grape in the field and under cold storage conditions. Journal of Agricultural and Food Chemistry, 51(16), 4708-4711.   DOI
13 MacBean, C. (2012). The Pesticide manual; A World Compendium, pp. 38-39, 16th ed., British Crop Protection Council, Hampshire, UK.
14 Seong, K. Y., Choi, K. I., Jeong, M. H., Hur, J. H., Kim, J. G., & Lee, K. S. (2004). Residue and half-lives of bitertanol and tebuconazole in greenhouse-grown pepper, Journal of the Korean Society for Applied Biological Chemistry, 47(1), 113-119.