Browse > Article
http://dx.doi.org/10.5338/KJEA.2005.24.4.341

Adsorption Characteristics of Organophosphorus and Carbamate Pesticides in Four Soils and the Evaluation for Their Leaching Potential Using Two Screening Models  

Kim, Chan-Sub (National Institute of Agriculture Science and Technology)
Park, Byung-Jun (National Institute of Agriculture Science and Technology)
Ihm, Yang-Bin (National Institute of Agriculture Science and Technology)
Ryu, Gab-Hee (National Institute of Agriculture Science and Technology)
Publication Information
Korean Journal of Environmental Agriculture / v.24, no.4, 2005 , pp. 341-349 More about this Journal
Abstract
Soil adsorption study was carried out to define the mobility of pesticides and to evaluate leaching potential in soils. Nine pesticides including metolcarb, molinate, fenobucarb, isazofos, diazinon, fenitrothion, dimepiperate, parathion and chlorpyrifos-methyl were subjected to adsorption experiment for four types of soils, such as upland, paddy, forest and volcanic ash soil. Based on Koc values, metolcarb and molinate were classified as mobile, fenobucarb as mobile or moderately mobile isazofos as moderately mobile, diazinon, fenitrothin, dimepiperate, and parathion as slightly or moderately mobile and chlorpyrifos-methyl as slightly mobile. Two evaluation methods, Groundwater Ubiquity Score (GUS) index and standard indices of soil-chemical adsorption and biodegradation (half-life), were used for the estimation of pesticide leaching potential. Leachabilities of metolcarb, molinate and fenobucarb were evaluated as high, and isazofos, dimepiperate and diazinon as a little potential, while fenitrothion, parthion and chlorpyrifos-methyl showed very low leaching potential. The leaching potential of pesticides was determined on the basis of intrinsic properties of the pesticides and the soil properties. Among the soil properties, organic matter gave a great influence on the leachability in soil. Therefore, leachabilities of the pesticides used were expected less in Sineom soil with relatively higher organic matter than Gangseo, Jungdong and Yesan soil with lower organic matter.
Keywords
pesticide; adsorption; leaching; half-life; Groundwater Ubiquity Score (GUS);
Citations & Related Records
연도 인용수 순위
  • Reference
1 Crepeau, K. L., Walker, G., and Winterlin, W. (1991) Use of coal to retard pesticide movement in soil. J. Environ. Sci. Health B26, 529-545
2 Arienzo, M., Crisanto, T., Sanchez-Martin, M. J., and Sanchez-Camazano, M. (1994) Effect of soil characteristics on adsorption and mobility of (14C) diazinon. J. Agric. Food Chem. 42, 1803-1808   DOI   ScienceOn
3 Sanchez-Martin, M. J. and Sanchez-Camazano, M. (1991) Relationship between the structure of organophosphorus pesticides and adsorption by soil components. Soil Sci. 152, 283-288   DOI
4 McCall, P. J., Swann, R. L., Laskowski, D. A., Unger, S. M., Vrona, S. A., and Dishburger, H. J. (1980) Estimation of chemical mobility in soil from liquid chromatographic retention times. Bull. Environ. Contam. Toxicol. 24, 190-1   DOI   ScienceOn
5 Kim, H. K., Park, I. J., Shim, J. H., and Shu, Y. T. (1996) Soil adsorption of herbicide quizalofop-ethyl. Korean J. Environ. Agric. 15(4), 442-447
6 Gerstl, Z. and Kliger, L. (1990) Fractionation of the organic matter in soils and sediments and their contribution to the sorption of pesticides. J. Environ. Sci. Health B25, 729-741
7 Jury, W. A., Focht, D. D., and Farmer, W. J. (1987) Evaluation of pesticide groundwater pollution potential from standard indices of soil-chemical adsorption and biodegradation. J. Environ. Qual. 16, 422-428   DOI   ScienceOn
8 Boesten, J. J. T. I., and van der Linden, A. M. A. (1991) Modeling the influence of sorption and transformation on pesticide leaching and persistence. J. Environ. Qual. 20, 425-435   DOI
9 Jarvis, N. L., Hollis, J. M., Nicholls, P. H., Mayer, T., and Evans, S. P. (1997) MACRO_DB: a decisionsupport tool for assessing pesticide fate and mobility in soils. Environmental Modelling & Software 12, 251-265   DOI   ScienceOn
10 Weber, J. B. and Miller, C. T. (1989) Organic Chemical Movement over and through soil. 305-334, In Reactions and movement of organic chemicals in soils (ed. Sawhney, B. L. and Brown, K.), SSSA Inc., USA
11 Hamaker, J. W. and Thompson, J. M. (1972) Adsorption. 49-143, In Organic chemicals in the soil environment (ed. Goring, C. A. I. and Hamaker, J. W.), Marcel Dekker, USA
12 Boesten, J. J. T. I. (1990) Influence of solid/liquid ratio on the experimental error of sorption coefficients in pesticide/soil systems. Pes tic. Sci. 30, 31-41   DOI   ScienceOn
13 von Oepen, B., W. Koerdel, and W. Klein (1991) Sorption of nonpolar and polar compounds to soils: Processes, measurements and experience with the applicability of the modified OECD-guideline 106. Chemosphere 22, 285-304   DOI   ScienceOn
14 Pusino, A, Liu, W., and Gessa, C. (1992) Influence of organic matter and its clay complexes on metolachlor adsorption on soil. Pestic. Sci. 36, 283-286   DOI   ScienceOn
15 Gustafson, D. I. (1989) Groundwater ubiquity score: A simple method for assessing pesticide leachability. Environ. Toxicol. Chem. 8, 339-357   DOI
16 Singh, N., P. A. Wahid, M. V. R. Murty, and N. Sethunathan (1990) Sorption-desorption of methyl parathion, fenitrothion and carbofuran in soils. J. Environ. Sci. Health B25, 713-728
17 Page, A. L. (1982) Method of soil analysis. Part 2 - Chemical and microbiological properties. 2nd ed. American Society of Agronomy and Soil Science Society of America. Madison, Wisconsin
18 Klute, A. (1986) Method of soil analysis. Part 1 -Physical and mineralogical methods. 2nd ed. American Society of Agronomy and Soil Science Society of America. Madison, Wisconsin
19 Tomlin, C. (ed.). (1997) The pesticide manual (11th ed.). British Crop Protection Council. UK
20 USA EPA. (1994) Sediment and soil adsorption isotherm. 157-161. In EPA guideline-code of federal regulation 40, part 790 to end
21 Kim, C. S., Lee, B. M., Ihm, Y. B., and Choi, J. H. (2002) Leaching potential of butachlor, ethoprophos, iprobenfos, isoprothiolane and procymidone in soils as affected by adsorption characteristics. Korean J. Pestic. Sci. 6(4), 309-319
22 Bewick, D. W. (1994) The mobility of pesticides in soil-studies to prevent groundwater contamination. 57-86, In H. Boerner (ed.) Pesticides in ground and surface water. Springer-Verlag. Berlin
23 Roberts, T. R. (1996) Assessing the environmental fate of agrochemicals. J. Environ. Sci. Health B31, 325-335   DOI
24 Bottani, P., Keizer, J., and Funari, E. (1996) Leaching indices of some major triazine metabolites. Chemosphere 32, 1401-1411   DOI   ScienceOn
25 Johnson, B. R. (1991) A simple adsorption/dilution model for rice herbicides. Bull. Environ. Contam. Toxicol. 47, 244-250   DOI   ScienceOn
26 Somasundaram, L., Jayachandran, K., Kruger, E.L., Racke, K. D., Moorman, T. B., Dvorak, T., and Coats, J. R. (1993) Degradation of isazofos in the soil environment. J. Agric. Food Chem. 41, 313-318   DOI
27 National Institute of Agricultural Science and Technology (NIAST) (1998) Pesticide database on registration
28 OECD. (1993) 106. Adsorption/Desorption. In OECD guidelines for testing of chemicals
29 Bruecher, J. and Bergstroem, L. (1997) Temperature dependence of linuron sorption to three different agricultural soils. J. Environ. Qual. 26, 1327-1335   DOI   ScienceOn