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http://dx.doi.org/10.14579/MEMBRANE_JOURNAL.2020.30.6.409

Gas Permeation Characteristics of CO2 and N2 through PEBAX/ZIF-8 and PEBAX/amineZIF-8 Composite Membranes  

Hong, Se Ryeong (Kyedang College of General Educations, Sangmyung University)
O, So Young (Department of Chemical Engineering and Materials Science, Sangmyung University)
Lee, Hyun Kyung (Department of Chemical Engineering and Materials Science, Sangmyung University)
Publication Information
Membrane Journal / v.30, no.6, 2020 , pp. 409-419 More about this Journal
Abstract
In this study, PEBAX/ZIF-8 and PEBAX/amineZIF-8 composite membranes were prepared according to the content of zeolitic imidazolate framework-8 (ZIF-8), amine-modified ZIF-8 (amineZIF-8), the gas permeability properties of N2 and CO2 were investigated for each composite membrane. In the case of the PEBAX/ZIF-8 composite membrane, the permeability of N2 and CO2 increased as the ZIF-8 content increased, and in the case of the PEBAX/amineZIF-8 composite membrane, the permeability of N2 and CO2 increased up to 20 wt% of amineZIF-8, but decreased at the higher content. CO2/N2 ideal selectivity increased up to 20 wt% of ZIF-8 and amineZIF-8 contents in both PEBAX/ZIF-8 and PEBAX/ amineZIF-8 composite membranes, and then decreased thereafter, in the case of PEBAX/amineZIF-8 composite membrane was less decreased. The reason for the highest CO2/N2 ideal selectivity at 20 wt% of amineZIF-8 is that amine modification improved the compatibility between PEBAX and amineZIF-8, and thus amineZIF-8 was evenly dispersed in PEBAX, resulting in the greatest effect of the porous ZIF-8 with a 3.4 Å pore size and the amine with affinity for CO2.
Keywords
PEBAX; ZIF-8; $CO_2/N_2$; permeability; selectivity;
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Times Cited By KSCI : 3  (Citation Analysis)
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