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http://dx.doi.org/10.14579/MEMBRANE_JOURNAL.2015.25.1.1

Study for Facilitated Olefin Transport Phenomena Using Silver Oxide  

Ji, Dahye (Department of Chemistry, Sangmyung University)
Kang, Sang Wook (Department of Chemistry, Sangmyung University)
Publication Information
Membrane Journal / v.25, no.1, 2015 , pp. 1-6 More about this Journal
Abstract
It was known that the polarlized surface of silver nanoparticles could be interacted revesibly with olefin molecules for facilitated olefin transport. However, it was thought that it can be regenerated by interaction between oxide surface of AgNPs and olefin molecules because the surface of the silver nanoparticles is easily oxidized in the air. In order to investigate the effect of the silver oxide, 5 wt% AgO or $Ag_2O$ was dispersed in polymer PVP solutions and 0.005~0.02% electron acceptor as TCNQ or p-BQ were added to fabricate the separation membrane. After the addition of the electron acceptor, it was expected to improve the polarity on the surface of the silver oxide and the degree of dispersion. The characteristics of the separation membrane were identified by the gas permeance, XPS and TEM.
Keywords
carrier; facilitated olefin transport; silver nanoparticles; silver oxide; electron acceptor;
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Times Cited By KSCI : 3  (Citation Analysis)
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