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Preparation of PEGDA/PETEDA Dendrimer Membranes for $CO_2$ Separation  

Han, Na (Department of Industrial Chemistry, Sangmyung University)
Lee, Hyunkyung (Department of Industrial Chemistry, Sangmyung University)
Publication Information
Membrane Journal / v.23, no.1, 2013 , pp. 54-60 More about this Journal
Abstract
PEGDA/PETEDA dendrimer composite membranes was prepared by UV photopolymerizing of poly ethylene glycol diacrylate (PEGDA) containing 5~15 wt% pentaerythrityl tetraethylenediamine (PETEDA) dendrimer. The prepared composite membrane was characterized by FT-IR, $^1H$-NMR and DSC. The glass transition temperature ($T_g$) of PEGDA/PETEDA dendrimer composite decreased with the increment of PETEDA dendrimer content. The $CO_2$ separation properties over $CH_4$ were investigated by changing the PETEDA dendrimer content and pressure. The composite membrane containing 10 wt% PETEDA dendrimer exhibited on excellent $CO_2/CH_4$ ideal selectivity of 31.8 and a $CO_2$ permeability of 162.2 barrer.
Keywords
$CO_2$ separation; natural gas purification; carrier; dendrimer; composite membrane; PETEDA dendrimer;
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Times Cited By KSCI : 1  (Citation Analysis)
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