Browse > Article

Advanced Water Treatment of High Turbidity Source by Hybrid Process of Photocatalyst and Ceramic Microfiltration: Effect of Organic Materials in Water-back-flushing  

Park, Jin-Yong (Department of Environmental Sciences & Biotechnology, Hallym University)
Lee, Gwon-Seop (Department of Environmental Sciences & Biotechnology, Hallym University)
Publication Information
Membrane Journal / v.21, no.1, 2011 , pp. 72-83 More about this Journal
Abstract
For advanced drinking water treatment of high turbidity water, we used the hybrid module that was composed of photocatalyst packing between outside of tubular ceramic microfiltration membrane and membrane module inside. Photocatalyst was PP (polypropylene) bead coated $TiO_2$ powder by CVD (chemical vapor deposition) process. Instead of natural organic matters (NOM) and fine inorganic particles in natural water source, modified solution was prepared with humic acid and kaolin. Water-back-flushing of 10 sec was performed per every period of 10 min to minimize membrane fouling. Resistance of membrane fouling ($R_f$) decreased and J increased as concentration of humic acid changed from 10 mg/L to 2 mg/L, and finally the highest total permeate volume ($V_T$) could be obtained at 2 mg/L. Then, treatment efficiencies of turbidity and $UV_{254}$ absorbance were above 98.5% and 85.7%, respectively. As results of treatment portions by membrane filtration, photocatalyst adsorption, and photo-oxidation in MF, MF + $TiO_2$, and MF + $TiO_2$ + UV processes, turbidity was treated little by photocatalyst adsorption, and photo-oxidation. However, treatment portions of humic acid by adsorption and photo-oxidation were above 10.7 and 8.6%, respectively.
Keywords
ceramic membrane; photocatalyst; hybrid process; microfiltration; water-back-flushing;
Citations & Related Records
Times Cited By KSCI : 13  (Citation Analysis)
연도 인용수 순위
1 W. Yuan, A. Kocic, and A. L. Zydney, "Analysis of humic acid fouling during microfiltration using a pore blockage-cake filtration model", J. Membr. Sci., 198, 51 (2002).   DOI   ScienceOn
2 D. B. Mosqueda-Jimenez and P. M. Huck, "Characterization of membrane foulants in drinking water treatment", Desalination, 198, 173 (2006).   DOI
3 M. Heran and S. Elmaleh, "Microfiltration through an inorganic tubular membrane with high frequency retrofiltration", J. Membr. Sci., 188, 181 (2001).   DOI   ScienceOn
4 S. K. Karode, "Unsteady state flux response: a method to determine the nature of the solute and gel layer in membrane filtration", J. Membr. Sci., 188, 9 (2001).   DOI   ScienceOn
5 H. K. Vyas, A. J. Mawson, R. J. Bennett, and A. D. Marshall, "A new method for estimating cake height and porosity during filtration of particulate suspensions", J. Membrane Sci., 176, 113 (2000).   DOI   ScienceOn
6 P. Rai, C. Rai, G. C. Majumdara, S. D. Gupta, and S. De, "Resistance in series model for ultrafiltration of mosambi (Citrus sinensis (L.) Osbeck) juice in a stirred continuous mode", J. Membr. Sci., 283, 116 (2006).   DOI
7 K. Katsoufidou, S. G. Yiantsios, and A. J. Karabelas, "A study of ultrafiltration membrane fouling by humic acids and flux recovery by backwashing: Experiments and modeling", J. Membr. Sci., 266, 40 (2005).   DOI   ScienceOn
8 J. Y. Park, S. J. Choi, and B. R. Park, "Effect of N2-back-flushing in multichannels ceramic microfiltration system for paper wastewater treatment", Desalination, 202, 207 (2007).   DOI   ScienceOn
9 D. Chen, L. K. Weavers, and H. W. Walker, "Ultrasonic control of ceramic membrane fouling: Effect of particle characteristics", Water Research, 40, 840 (2006).   DOI   ScienceOn
10 Y. J. Yuk and K. H. Youm, "Enhancement of ultrafiltration performance using ultrasound", Membrane Journal, 13(4), 283 (2003).
11 W. F. Jones, R. L. Valentine, and V. G. J. Rodgers, "Removal of suspended clay from water using transmembrane pressure pulsed microfiltration", J. Membr. Sci., 157, 199 (1999).   DOI   ScienceOn
12 F. Malek, J. L. Harris, and F. A. Roddick, "Interrelationship of photooxidation and microfiltration in drinking water treatment", J. Membr. Sci., 281, 541 (2006).   DOI   ScienceOn
13 I. R. Bellobono, B. Barni, and F. Gianturco, "Preindustrial experience in advanced oxidation and integral photodegradation of organics in potable waters and waste waters by $PHOTOPERM^{TM}$ membranes immobilizing titanium dioxide and promoting photocatalysts", J. Membr. Sci., 102, 139 (1995).   DOI
14 H. C. Lee and J. Y. Park, "Advanced water treatment of high turbidity source by hybrid process of ceramic microfiltration and activated carbon adsorption: Effect of GAC packing fraction", Membrane Journal, 18(3), 191 (2008).
15 H. C. Lee and J. Y. Park, "Advanced water treatment of high turbidity source by hybrid process of ceramic microfiltration and activated carbon adsorption: Effect of water-back-flushing time and period", Membrane Journal, 19(1), 7 (2009).
16 H. C. Lee, J. Y. Park, and D. Y. Yoon, "Advanced water treatment of high turbidity source by hybrid module of ceramic microfiltration and activated carbon adsorption: Effect of organic/inorganic materials", Korean J. Chem. Eng., 26(3), 697 (2009).   DOI   ScienceOn
17 R. Molinari, C. Grande, E. Driloli, L. Palmisano, and M. Schiavello, "Photocatalytic membrane reactors for degradation of organic pollutants in water", Cata. Today, 37, 273 (2001).
18 R. Molinari, F. Pirillo, M. Falco, V. Loddo, and L. Palmisano, "Photocatalytic degradation of dyes by using a membrane reactor", Chem. Eng. Proc., 43, 1103 (2004).   DOI   ScienceOn
19 S. J. G., K. C. Geun, and H. S. Jin, "Daily variations of water turbidity and particle distribution of high turbid-water in Paldang reservoir, Korea", Korean J. Limnol, 36(3), 257 (2003).
20 J. C. Park, J. W. Park, J. K. Shin, and H. M. Lee, "Dynamics of high turbid water caused by heavy rain of monsoon and typhoon in a large Korean reservoir (Andong reservoir)", Korean J. Limnol, 38(1), 105 (2005).
21 Y. K. Yoon, "Removal characteristics of NOM by particle activated carbon and ozon/PAC in Han-river", Master Dissertation, U. of Seoul, Seoul, Korea (2007).
22 K. Azrague, E. Puech-Costes, P. Aimar, M. T. Maurette, and F. Benoit-Marquie, "Membrane photoreactor (MPR) for the mineralisation of organic pollutants from turbid effluents", J. Membr. Sci., 258, 71 (2005).   DOI   ScienceOn
23 M. Pidou, S. A. Parsons, G. Raymond, P. Jeffery, T. Stephenson, and B. Jefferson, "Fouling control of a membrane coupled photocatalytic process treating greywater", Wat. Res., 43, 3932 (2009).   DOI   ScienceOn
24 D.-J. Kim, J.-Y. Kang, and K.-S. Kim, "Preparation of $TiO_{2}$ thin films on glass beads by a rotating plasma reactor", J. Ind. & Eng. Chem., 16, 997 (2010).   DOI   ScienceOn
25 J. Y. Jung, K. Y. Kang, D. H. Youn, Y. S. Kim, K. H. Suh, and J. H. Lim, "A study on the adsorption of natural organic matter by activated carbon from drinking water", J. Korean Ind. Eng. Chem., 14(8), 1127 (2003).
26 M. H. Cho, C. H. Lee, and S. H. Lee, "Effect of flocculation conditions on membrane permeability in coagulation-microfiltration", Desalination, 191, 386 (2006).   DOI   ScienceOn
27 M. Cheryan, "Ultrafiltration Handbook", pp. 89-93, Technomic Pub. Co., Lancater, PA (1984).
28 J. K. Shin, J. Hur, H. S. Lee, J. C. Park, and S. J. Hwang, "Spatial interpretation of Monsoon turbid- water wnvironment in a reservoir (Yongdam) discharging surface water, Korea", J. Korean Society of Water Quality, 22(5), 933 (2006).
29 J. Y. Park, "Effect of water-back-flushing time on recovery efficiency in ceramic filtration system for paper wastewater treatment", Membrane Journal, 14(4), 329 (2004).
30 J. H. Park, S. Y. Lee, and H. S. Park, "Removal of NOM in a coagulation process enhanced by modified clay", J. Korean Society of Water & Wastewater, 21(1), 37 (2007).
31 Y. Yoon and R. M. Lueptow, "Removal of organic contaminants by RO and NF membranes", J. Membr. Sci., 261, 76 (2005).   DOI   ScienceOn
32 S. Mozia and M. Tomaszewska, "Treatment of surface water using hybrid processes-adsorption on PAC and ultrafiltration", Desalination, 162, 23 (2004).   DOI
33 M. R. Teixeira and M. J. Rosa, "The impact of the water background inorganic matrix on the natural organic matter removal by nanofiltration", J. Membr. Sci., 279, 513 (2006).   DOI   ScienceOn
34 J. H. Chung, K. H. Choo, and H. S. Park, "Low pressure hybrid membrane processes for drinking water treatment", Membrane Journal, 17(3), 161 (2007).
35 H. S. Kim, S. Takizawa, and S. Ohgaki, "Application of microfiltration systems coupled with powdered activated carbon to river treatment", Desalination, 202, 271 (2007).   DOI   ScienceOn
36 R. H. S. Jansen, J. W. de Rijk, A. Zwijnenburg, M. H. V. Mulder, and M. Wessling, "Hollow fiber membrane contactors-A means to study the reaction kinetics of humic substance ozonation", J. Membr. Sci., 257, 48 (2005).   DOI
37 K. W. Park, K. H. Choo, and M. H. Kim, "Use of a combined photocatalysis/ microfiltration system for natural organic matter removal", Membrane Journal, 14(2), 149 (2004).
38 Y. T. Lee and J. K. Oh, "Membrane fouling effect with organic-inorganic materials using the membrane separation in drinking water treatment process", Membrane Journal, 13(4), 219 (2003).